# US 4,400,260 A · Shielded, heated electrochemical gas sensor

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- Number: US 4,400,260 A
- Document ID: US4400260A
- Status: Granted
- Kind: A
- Application number: 06/367,276
- Filed: 1982-04-12
- Granted: 1983-08-23
- Earliest claimed: 1981-05-21
- Assignees: Robert Bosch GmbH
- Inventors: Roland Stahl; Hans-Martin Wiedenmann
- Web page: https://patentgrep.com/patent/US4400260A

## CPC

- G01N 27/4071: {using sensor elements of laminated structure}
- G01N 27/4067: {Means for heating or controlling the temperature of the solid electrolyte}
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

To extend temperature range of solid electrolyte ion conductive-type gas sensors, particularly for the exhaust gases from internal combustion engines, and to prevent leakage currents between a heater element and the solid electrolyte body at temperatures just above the response temperature of the sensor, but below its normal operating temperatures, that is, even in the range of between 250.degree. C. to 400.degree. C., a layer-like shielding electrode (18,29) is provided, positioned between the solid electrolyte body (11,25) and the insulating layer (17,31). The shielding electrode is galvanically connected to the return line (21,33) of the heating element. In accordance with one embodiment, the shielding electrode and one of the operating electrodes, for example, the sensing electrode (29), can be the same metallic film or element applied to the sensor, with an additional electrical insulation layer (32) interposed in the region between the film electrode (29) and the solid electrolyte body (25), the heater element (16,30) being positioned with the interposition of the electrical insulating layer over the film electrode in that region. Preferably, the width of the respective insulating layers decreases in a direction away from solid electrolyte body. The system is applicable both to potentiometric, as well as polarographic-type sensors, of, selectively, closed tubular or plate-like construction, with electrodes exposed either to a reference gas or having, respectively, different catalytic activity.

## Claims

### Claim 1

Heated electrochemical sensor with internal shielding, to provide an electrical output representative of a predetermined component in a sample gas to which the sensor is exposed, particularly a combustion exhaust gas, especially from an internal combustion engine, having
an oxygen ion conductive solid electrolyte body (11,25):
two porous electrode layers (13, 15; 27, 29) positioned on the body at spaced surface portions thereof;
a resistance heating element (16, 30) on the body. and an electrical supply connection (22, 35) and an electrical return connection (21, 33) to provide electrical current to the resistance heating element;
and an electrically insulating layer (17, 31) separating the resistance heating element from the solid electrolyte ion conductive body and supporting the resistance heating element thereon
wherein, in accordance with the invention
a layer-like shielding electrode (18, 29) is provided, positioned between the solid electrolyte body (11, 25) and the electrically insulating layer (17, 31) on which the resistance heating element is located and supported, and located beneath the resistance heating element.

### Claim 2 (depends on 1)

Sensor according to claim 1 further including a second electrically insulating layer (32) located between the shielding electrode (18,29) and the solid electrolyte body (11,25).

### Claim 3 (depends on 2)

Sensor according to claim 2 wherein the shielding electrode (29) and one of the porous electrode layers (29) are in electrical connection with each other.

### Claim 4 (depends on 3)

Sensor according to claim 3 wherein the shielding electrode, and one of the porous electrode layers (29) form a continuous electrically conductive layer on the solid electrolyte body, the continuous layer acting as a porous electrode where said layer is in contact with the oxygen ion conductive solid electrolyte body and forming the shielding electrode in that region where said further electrically insulating layer (32) is interposed between said electrically conductive layer (29) and the ion conductive body (25).