# US 4,400,222 A · Method for treating surfaces > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,400,222 A - Document ID: US4400222A - Status: Granted - Kind: A - Application number: 06/274,276 - Filed: 1981-06-16 - Granted: 1983-08-23 - Earliest claimed: 1980-06-17 - Assignees: Hitachi Metals, Ltd. - Inventors: Norimasa Uchida - Web page: https://patentgrep.com/patent/US4400222A ## CPC - C23C 10/26: more than one element being diffused - C23C 10/24: Salt bath containing the element to be diffused - C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04) ## Abstract A method for treating surfaces is provided, in which a material to be treated, such as iron, iron alloys or the like is immersed in a molten bath prepared by adding 5 to 50 weight % of a metal cementing agent consisting of one or more selected from the group consisting of a Group Va element, a substance containing the Group Va element, a Group VIa element and a substance containing the Group VIa element to a salt bath agent consisting of a neutral salt containing 5 to 30 mol % of a borate admixed therewith, to form the carbide of the Group Va element or Group VIa element or the composite carbide of these elements on the surfaces of the material. To the molten bath there may be optionally added 1 to 10 weight % of an adjuvant consisting of one or more selected from the group consisting of the oxysalts of the Groups IVa, Va and VIa elements and/or 1 to 10 weight % of a metal or an alloy thereof selected from the group consisting of a Group IVa metal and an alloy thereof. ## Claims ### Claim 1 A surface-treating method for forming the carbide or composite carbide of a Group Va element and/or Group VIa element on the surface of an iron or iron alloy material to be treated, characterized by immersing said material in a molten bath prepared by adding to (i) a salt bath agent consisting of a mixture of BaCl.sub.2 and 5 to 15 mol % of Na.sub.2 B.sub.4 O.sub.7, (ii) 5 to 50 weight % of a metal cementing agent consisting of one or more substances selected from the group consisting of the Group Va element, a substance containing the Group Va element, the Group VIa element and a substance containing the Group VIa element. ### Claim 2 A surface-treating method for forming the carbide of a Group Va element and/or Group VIa element on the surface of an iron or iron alloy material to be treated, characterized by immersing said material into a molten bath prepared by adding to (i) a salt bath agent consisting of a mixture of BaCl.sub.2 and 5 to 15 mol % of Na.sub.2 B.sub.4 O.sub.7, (ii) 5 to 50 weight % of a metal cementing agent consisting of one or more substances selected from the group consisting of the Group Va element, a substance containing the Group Va element, the Group VIa element and a substance containing the Group VIa element and (iii) an adjuvant consisting of one or more substances selected from the group consisting of the oxysalts of Groups IVa, Va and VIa elements. ### Claim 3 A surface-treating method for forming the composite carbide of a Group Va element or Group VIa element and Group IVa element on the surface of an iron or iron alloy material to be treated, characterized by immersing said material into a molten bath prepared by adding to (i) a salt bath agent consisting of a mixture of BaCl.sub.2 and 5 to 15 mol % of Na.sub.2 B.sub.4 O.sub.7, (ii) 5 to 40 weight % of a metal cementing agent consisting of one or more substances selected from the group consisting of the Group Va element, a substance containing the Group Va element, the Group VIa element and a substance containing the Group VIa element, and (iii) 1 to 10 weight % of one or more substances selected from the Group IVs metal and alloys thereof. ### Claim 4 A surface-treating method for forming either (a) the composite carbide of a Group Va element or Group VIa element and a Group IVa element or (b) a composite carbide of a Group Va element, a Group VIa element and a Group IVa element on the surface of iron or iron alloy material to be treated, characterized by immersing said material into a molten salt bath prepared by adding to (i) a salt bath agent consisting of a mixture of BaCl.sub.2 and 5 to 15 mol % of Na.sub.2 B.sub.4 O.sub.7, (ii) 5 to 40 weight % of a metal cementing agent consisting of one or more substances selected from the group consisting of the Group Va element, a substance containing the Group Va element, the Group VIa element and a substance containing the Group VIa element, (iii) 2 to 10 weight % of an adjuvant consisting of one or more substances selected from the group consisting of the oxysalts of Groups IVa, Va and VIa elements and (iv) 1 to 10 weight % of one or more substances selected from the group consisting of the Group IVa metal and alloys thereof. ### Claim 5 (depends on 3, 4) A surface-treating method according to claim 3 or 4, wherein the metal cementing agent is 5 to 40 weight % of one or more substances selected from the group consisting of the Group Va element, alloys thereof, Group VIa element and alloys thereof, and the molten bath contains 1 to 4 weight % of one or more substances selected from the group consisting of the Group IVa element and alloys thereof. ### Claim 6 (depends on 3, 4) A surface-treating method according to claim 3 or 4, wherein the metal cementing agent contains 5 to 20 weight % of one or more substances selected from the group consisting of the oxides of the Group Va elements and the oxides of the Group VIa elements as well as 4 to 10 weight % of one or more substances consisting of the Group IVa elements and alloys thereof. ### Claim 7 (depends on 4) A surface-treating method according to claim 4, wherein the molten salt bath contains vanadium or its alloy as the metal cementing agent, NaVO.sub.3 as the adjuvant, and titanium or its alloy. ### Claim 8 (depends on 3) A surface-treating method accoridng to claim 3, wherein the molten salt bath contains V.sub.2 O.sub.5 as the metal cementing agent, and titanium or its alloy. ### Claim 9 (depends on 4) A surface-treating method according to claim 4, wherein the molten salt bath contains V.sub.2 O.sub.5 as the metal cementing agent, NaVO.sub.3 as the adjuvant, and titanium or its alloy. ### Claim 10 (depends on 1, 2, 3, 4) A surface-treating method according to claim 1, claim 2, claim 3 or claim 4, wherein said iron or iron alloy material is formed of iron or iron alloy containing more than 0.3 weight % carbon or of iron or iron alloy containing less than 0.3 weight % carbon and having a carbon content at the surface of the material increased by carburization.