# US 4,400,052 A · Method for manufacturing birefringent integrated optics devices > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,400,052 A - Document ID: US4400052A - Status: Granted - Kind: A - Application number: 06/245,628 - Filed: 1981-03-19 - Granted: 1983-08-23 - Earliest claimed: 1981-03-19 - Assignees: Bell Telephone Laboratories, Incorporated - Inventors: Rodney C. Alferness; Janet L. Jackel - Web page: https://patentgrep.com/patent/US4400052A ## CPC - G02B 6/134: by substitution by dopant atoms - G02B 6/126: using polarisation effects {(G02B6/1226 takes precedence)} - G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS ## Abstract Method for adjusting the value of birefringence in predetermined sections of waveguides in integrated optics devices fabricated in optically anisotropic substrates such as monocrystalline LiNbO.sub.3 or LiTaO.sub.3. The inventive method comprises in combination methods for changing both refractive indices in a first volume of the substrate, such as, for instance, ion implantation or metal in-diffusion, thereby creating an optical waveguide for both TE and TM modes of radiation, and methods for further changing one of the indices in a second volume of the substrate, without proportionally changing the other index in the second volume, such as, for instance, Li out-diffusion or ion exchange. In a typical application, the first volume comprises waveguiding regions, including the section in which the birefringence is to be adjusted, and the second volume also includes that waveguide section. The inventive methods are advantageously employed in the manufacture of integrated optics devices whose operating characteristics depend on the value of birefringence of a section of waveguide, for instance, a mode converter/wavelength filter, or a polarization separator. ## Claims ### Claim 1 Method for manufacturing an integrated optics device comprising a substrate of optically anisotropic material, the substrate having a major surface, and a major direction in the surface, an ordinary index of refraction and an extraordinary index of refraction for electromagnetic radiation propagating in the major direction, the method comprising (a) changing both the ordinary and the extraordinary index in a volume of the substrate, thereby producing a waveguide for both TE and TM modes of the radiation, CHARACTERIZED BY the further step of (b) adjusting the value of the difference between the ordinary index and the extraordinary index in at least part of the waveguide. ### Claim 2 (depends on 1) Method of claim 1 wherein the optically anisotropic material comprises material selected from the group consisting of LiNbO.sub.3 and LiTaO.sub.3. ### Claim 3 (depends on 2) Method of claim 2, wherein the changing of both the ordinary and the extraordinary index in step (a) is accomplished by means of ion implantation. ### Claim 4 (depends on 2) Method of claim 2, wherein the changing of both the ordinary and the extraordinary index in step (a) is accomplished by means of metal in-diffusion. ### Claim 5 (depends on 4) Method of claim 4, wherein the metal indiffusion is transition metal in-diffusion. ### Claim 6 (depends on 5) Method of claim 5, wherein the transition metal in-diffusion is Ti in-diffusion. ### Claim 7 (depends on 2) Method of claim 2 wherein the adjusting of the value of the difference between the ordinary index and the extraordinary index is accomplished by means of Li out-diffusion. ### Claim 8 (depends on 2) Method of claim 2 wherein the adjusting of the value of the difference between the ordinary index and the extraordinary index is accomplished by means of ion exchange. ### Claim 9 (depends on 8) Method of claim 8, wherein the ion exchange is Li/Ag exchange or Li/Tl exchange. ### Claim 10 (depends on 9) Method of claim 9, wherein the Li/Ag exchange is accomplished by contacting at least part of the major surface of the substrate with an exchange medium comprising molten AgNO.sub.3 at a temperature below about 370.degree. C. ### Claim 11 (depends on 9) Method of claim 9, wherein the Li/Tl exchange is accomplished by contacting at least part of the major surface of the substrate with an exchange medium comprising TlNO.sub.3 at a temperature below about 370.degree. C. ### Claim 12 (depends on 2) Method of claim 2, wherein the changing of both the ordinary and the extraordinary index is accomplished by means of transition metal in-diffusion, and the adjusting of the value of the difference between the ordinary index and the extraordinary index is accomplished by means of ion exchange. ### Claim 13 (depends on 12) Method of claim 12, wherein the transition metal in-diffusion is Ti in-diffusion, and the ion exchange is Ag/Li or Tl/Li exchange. ### Claim 14 (depends on 13) Method of claim 13, wherein the Ag/Li exchange is accomplished by contacting at least part of the major surface of the substrate with an exchange medium comprising molten AgNO.sub.3 at a temperature below about 370.degree. C. ### Claim 15 (depends on 13) Method of claim 13, wherein the Tl/Li exchange is accomplished by contacting at least part of the major surface of the substrate with an exchange medium comprising molten TlNO.sub.3 at a temperature below about 370.degree. C. ### Claim 16 (depends on 14, 15) Method of claims 14 or 15, wherein the temperature is not more than about 250.degree. C. ### Claim 17 Method for manufacturing an integrated optics device comprising a substrate of monocrystalline material comprising material selected from the group consisting of LiNbO.sub.3 and LiTaO.sub.3, the substrate having a major surface and a major direction in the surface, an ordinary index of refraction and an extraordinary index of refraction for electromagnetic radiation propagating in the major direction, the method comprising (a) increasing both the ordinary and the extraordinary index in a volume of the substrate by means of Ti in-diffusion, thereby producing a waveguide for both TE and TM modes of the radiation, CHARACTERIZED BY the further step of (b) increasing by means of Li out-diffusion, Li/Ag exchange or Li/Tl exchange the value of the extraordinary index in at least part of the waveguide without substantially increasing the ordinary index in the part. ### Claim 18 (depends on 1, 17) A device manufactured according to the method of claims 1 or 17.