# US 4,399,350 A · Procedure for the thermal treatment of powdered and granulated catalysts and the like

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- Number: US 4,399,350 A
- Document ID: US4399350A
- Status: Granted
- Kind: A
- Application number: 06/273,197
- Filed: 1981-08-21
- Granted: 1983-08-16
- Earliest claimed: 1980-06-13
- Assignees: Sud-Chemie AG
- Inventors: Michael Schneider; Karl Kochloefl; Gerhard Diez; Franz Maier; Josef E. Rauch; Wolfgang Liebelt
- Web page: https://patentgrep.com/patent/US4399350A

## CPC

- B01J 8/16: with particles being subjected to vibrations or pulsations (B01J8/40 takes precedence)
- B01J 37/08: Heat treatment {(B01J37/0009, B01J37/0018 take precedence)}
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

## Abstract

Process for the thermal treatment of powdered and granulated catalysts, catalyst intermediate products, and inorganic substances, which are usable as constituents of catalysts or as auxiliary agents for the production of catalysts. The known process material is placed on a heated vibrating conveyor and there, in the form of a thin layer, in which the particles of the process material are moved with a larger horizontal and a smaller vertical component, heated and allowed to cool either outside the vibrating conveyor or in a separate vibrating conveyor or in the outlet portion of the first vibrating conveyor.

## Claims

### Claim 1

A process for the thermal treatment of powdered or granulated particles of catalytically related material, which comprises the steps of:
A. feeding said material in a thin layer onto a reciprocating and vibrating trough conveyor;
B. imparting a reciprocating and vibratory motion to said conveyor trough and to said powdered material on said trough;
1. said reciprocating motion having a vertical component and a horizontal component and,
2. said vertical component being smaller than said horizontal component so as to move said material along said conveyor,
C. applying heat to the material moving in a harmonic and vibratory fashion along said conveyor trough;
D. thereafter allowing said thermally treated particles to cool.

### Claim 2 (depends on 1)

A process, as defined in claim 1, in which said heat is applied to the material moving in essentially a horizontal plane along said reciprocating and linearly arranged vibrating conveyor.

### Claim 3 (depends on 2)

A process, as defined in claim 2, in which said material moves in a plane at a slight slope from the horizontal.

### Claim 4 (depends on 1)

A process, as defined in claim 1, in which the thickness of said layer of powdered material is in a range of about the diameter of a single particle of said material to about 20 mm.

### Claim 5 (depends on 4)

A process, as defined in claim 4, in which the thickness of said layer is in a range of from about 1-6 mm and preferably between about 2-4 mm.

### Claim 6 (depends on 1)

A process, as defined in claim 1, in which said heat is applied through radiant heaters located above said vibrating conveyor.

### Claim 7 (depends on 1)

A process, as defined in claim 1, the improvement of controlling the movement of the material through the conveyor which comprises the steps of:
A. controlling the duration of time that the materials are on the conveyor;
B. regulating the frequency of the vibration of said conveyor;
C. regulating the vibrational amplitude; and
D. regulating the amplitude direction.

### Claim 8 (depends on 1)

A process, as defined in claim 1, the improvement of controlling the vibratory motion of the conveyor and of controlling the temperature at which said materials are treated on said conveyor which comprises:
A. variably regulating the wattage input to the heating means for the conveyor; and
B. regulating the amount of heat supplied to the material through the use of heating means responsive to a calibrated thermometer located near the material being treated.

### Claim 9 (depends on 1)

A process, as defined in claim 1, the further improvement of introducing gases through the bottom of the vibrating conveyor to absorb the heat evolved through the exothermic reaction of material treated on said conveyor.

### Claim 10 (depends on 1)

A process, as defined in claim 1, the improvement of introducing protective gas atmospheres into contact with the powdered materials.

### Claim 11 (depends on 10)

A process, as defined in claim 10, in which said protective gas atmosphere comprises nitrogen, carbon dioxide, or one of the noble gases.

### Claim 12 (depends on 1)

A process, as defined in claim 1, the improvement of introducing reducing gases into contact with the material moving in a harmonic vibratory motion along said conveyor.

### Claim 13 (depends on 12)

A process, as defined in claim 12, in which said reducing gases comprises hydrogen or carbon monoxide.

### Claim 14 (depends on 12)

A process, as defined in claim 12, which comprises the further steps of:
A. flushing said reducing gases away from the reduced powdered materials;
B. slowly adding a protective gas atmosphere to said treated powdered material;
C. thereafter slowly adding an oxidizing gas to said protective gas atmosphere in gradually increasing concentration; and
D. covering said reduced particles through chemisorption with a thin oxide protective coating.