# US 4,399,311 A · Process for producing aromatic aldehydes

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- Number: US 4,399,311 A
- Document ID: US4399311A
- Status: Granted
- Kind: A
- Application number: 06/282,733
- Filed: 1981-07-13
- Granted: 1983-08-16
- Earliest claimed: 1980-07-16
- Assignees: Mitsubishi Gas Chemical Company, Inc.
- Inventors: Shigeo Yoshinaka; Tsukasa Toki; Misuzu Wakatsuki; Seiji Uchiyama
- Web page: https://patentgrep.com/patent/US4399311A

## CPC

- C07C 45/27: by oxidation (with ozone C07C45/40)
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS

## Abstract

In a process for producing aromatic aldehydes by reacting chlorinated methylbenzenes with nitric acid, the improvement wherein a lead compound is added to the residue left after separation and recovery of the resulting aromatic aldehydes from the reaction mixture thereby to remove a chlorine ion present in the residue as a precipitate of lead chloride, and the residue left after removal of the lead chloride is recycled to the reaction of the chlorinated methylbenzenes with nitric acid.

## Claims

### Claim 1

In a process for producing aromatic aldehydes by reacting chlorinated methylbenzenes with nitric acid, the improvement wherein a lead compound selected from the group consisting of lead nitrate, lead carbonate or lead hydroxide is added to the residue left after separation and recovery of the resulting aromatic aldehydes from the reaction mixture, thereby to remove a chlorine ion present in the residue as a precipitate of lead chloride, and the residue left after removal of the lead chloride is recycled to the reaction of the chlorinated methylbenzenes with nitric acid.

### Claim 2 (depends on 1)

The process of claim 1 wherein the lead compound is added as a solid to the residue.

### Claim 3 (depends on 1)

The process of claim 1 wherein the lead chloride removed is treated with an aqueous solution of sodium carbonate or sodium hydroxide to convert it to lead carbonate or lead hydroxide which is re-used in forming a precipitate of lead chloride.