# US 4,399,269 A · Poly-(-2-aminoalkyl)polyamines

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- Number: US 4,399,269 A
- Document ID: US4399269A
- Status: Granted
- Kind: A
- Application number: 06/395,435
- Filed: 1982-07-06
- Granted: 1983-08-16
- Earliest claimed: 1981-05-04
- Assignees: Milliken Research Corporation
- Inventors: Edward W. Kluger
- Web page: https://patentgrep.com/patent/US4399269A

## CPC

- C08G 59/5006: {aliphatic}
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

## Abstract

Poly-(-2-aminoalkyl)polyamine compounds are provided having the following formula: ##STR1## wherein: n is an integer of from 3 to about 12; R.sub.1 is selected from H and an alkyl group containing from 1 to about 10 carbon atoms; R.sub.2 and R.sub.3 are each independently selected from H and a lower alkyl group containing from 1 to about 6 carbon atoms; R.sub.4 is selected from H and ##STR2## R.sub.5 is selected from an alkyl group containing from about 6 to about 25 carbon atoms.

## Claims

### Claim 1

An epoxy resin composition comprising an epoxy resin and at least one epoxy resin curing agent of the formula: ##STR14## wherein: n is an integer of from 3 to about 12;
R.sub.1 is selected from H and an alkyl group containing from 1 to about 10 carbon atoms;
R.sub.2 and R.sub.3 are each independently selected from H and a lower alkyl group containing from 1 to about 6 carbon atoms;
R.sub.4 is selected from H and ##STR15## R.sub.5 is selected from an alkyl group containing from about 6 to about 25 carbon atoms.

### Claim 2 (depends on 1)

The curable epoxy resin composition of claim 1, wherein said epoxy resin is selected from the polyepoxides having at least two ##STR16## groups.

### Claim 3 (depends on 2)

The epoxy resin composition of claim 2, wherein said ##STR17## groups are terminal groups.

### Claim 4 (depends on 3)

The epoxy resin composition of claim 3, wherein said epoxy resin is a diglycidyl ether of bis-phenol.

### Claim 5 (depends on 1, 4)

The epoxy resin composition of claim 1, wherein said epoxy resin curing agent is represented by the formula set forth in claim 4 and wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are H.

### Claim 6 (depends on 5)

The epoxy resin composition of claim 5, wherein said alkyl group is derived from an amine compound of the formula: ##STR18## where x and y are independently selected from integers of from 1 to about 6, wherein the functionality of said compounds is provided by the reaction of at least one of the primary amine groups thereof.

### Claim 7

In a method for curing an epoxy resin composition comprising incorporating an epoxy resin curing agent into an epoxy resin and heating the combination of the epoxy resin and the epoxy curing agent, the improvement which comprises said epoxy resin curing agent being represented by the formula: ##STR19## wherein: n is an integer of from 3 to about 12;
R.sub.1 is selected from H and an alkyl group containing from 1 to about 10 carbon atoms;
R.sub.2 and R.sub.3 are each independently selected from H and a lower alkyl group containing from 1 to about 6 carbon atoms;
R.sub.4 is selected from H and ##STR20## R.sub.5 is selected from an alkyl group containing from about 6 to about 25 carbon atoms.