# US 4,399,265 A · Process of products UV-stabilized polyester materials > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,399,265 A - Document ID: US4399265A - Status: Granted - Kind: A - Application number: 06/459,050 - Filed: 1983-01-19 - Granted: 1983-08-16 - Earliest claimed: 1983-01-19 - Assignees: Garware Plastics & Polyester Ltd. - Inventors: Shashikant B. Garware; Ramaswamy Ananthanarayanan - Web page: https://patentgrep.com/patent/US4399265A ## CPC - C08J 3/203: {Solid polymers with solid and/or liquid additives} - C08K 5/005: {Stabilisers against oxidation, heat, light, ozone} - C08J 2367/02: Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) - C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29) - C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09) ## Abstract Polyesters are combined with UV-stabilizing substances in order to produce an end product, such as a film, sheet, ribbon or filament, by mixing polyester granules and the UV-stabilizing substance in powdered form at an elevated temperature such that at least the exterior surface of the polyester granules is soft, thereby to cause the powdered UV-stabilizing substance to adhere to the individual polymer granules, the granules with the powder adhering thereto are then dried, and they are then passed through an extruder or otherwise formed into an end product. ## Claims ### Claim 1 The process of producing UV-stabilized polyester materials which comprises: (1) heating polyester granules to a temperature of about 150.degree.-180.degree. C.; (2) mixing a powdered UV-stabilizing substance with said heated granules, thereby producing polyester granules to which said powdered substance is attached; (3) then subjecting said powder-carrying granules to a drying step effective to reduce the moisture content thereof to no more than about 0.005% by weight; and (4) then forming said dried powder-carrying granules into a useful body, such as a film, sheet, ribbon or filament. ### Claim 2 (depends on 1) The process of claim 1, in which said polyester comprises polyethylene terephthalate. ### Claim 3 (depends on 2) The process of claim 2, in which said UV-stabilizing substance is a member of the group consisting of o-hydroxy benzophenones, benzotriazoles, and mixtures thereof. ### Claim 4 (depends on 1) The process of claim 1, in which said UV-stabilizing substance is a member of the group consisting of o-hydroxy benzophenones, benzotriazoles, and mixtures thereof. ### Claim 5 (depends on 1) The process of claim 1, in which, between steps (2) and (3), fines are separated out from the powder-carrying granules. ### Claim 6 (depends on 1) The process of claim 1, in which said forming step (4) is an extrusion step carried out promptly after the drying step (3). ### Claim 7 (depends on 6) The process of claim 6, in which said polyester comprises polyethylene terephthalate and in which said UV-stabilizing substance is a member of the group consisting of o-hydroxy benzophenones, benzotriazoles, and mixtures thereof. ### Claim 8 (depends on 6) The process of claim 6, in which the powder-carrying granules, after being dried in step (3), are directly fed into an extruder and extruded therefrom. ### Claim 9 (depends on 1) The process of claim 1, in which the drying step (3) is carried out at a temperature of about 180.degree.-200.degree. C. ### Claim 10 (depends on 9) The process of claim 9, in which the drying step (3) is carried out while the powder-carrying granules are agitated. ### Claim 11 (depends on 10) The process of claim 10, in which said polyester comprises polyethylene terephthalate and in which said UV-stabilizing substance is a member of the group consisting of o-hydroxy benzophenones, benzotriazoles, and mixtures thereof. ### Claim 12 (depends on 9) The process of claim 9, in which the drying step (3) is carried out while the powder-carrying granules are agitated and fed through a container in which heated gas is provided in flow counter-current to the fed granules. ### Claim 13 (depends on 9) The process of claim 9, in which the drying step (3) is carried out in a heated tumbler including vacuum means to draw off moisture. ### Claim 14 The process of producing UV-stabilized polyester materials which comprises: (1) heating polyester granules to a temperature at which the polymer surface of the granules becomes soft and sticky; (2) agitating said heated polyester granules and mixing them with a powdered UV-stabilizing substance, thereby to cause said powdered substance to adhere to said heated granules; (3) cooling said powder-carrying granules and separating fines therefrom; (4) drying said powder-carrying granules; and (5) then feeding said dried powder-carrying granules into an extruder and extruding the UV-stabilized polyester material therefrom. ### Claim 15 (depends on 14) The process of claim 14, in which said polyester comprises polyethylene phthalate. ### Claim 16 (depends on 15) The process of claim 15, in which said UV-stabilizing substance is a member of the group consisting of o-hydroxy benzophenones, benzotriazoles, and mixtures thereof. ### Claim 17 (depends on 14) The process of claim 14, in which said UV-stabilizing substance is a member of the group consisting of o-hydroxy benzophenones, benzotriazoles, and mixtures thereof. ### Claim 18 (depends on 13) The process of claim 13, in which said drying step (4) is carried out in a hopper dryer, and in which the dried granules are fed directly from said hopper dryer into said extruder.