# US 4,399,246 A · Filled polyamide compositions with silanes and sulfonamides

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- Number: US 4,399,246 A
- Document ID: US4399246A
- Status: Granted
- Kind: A
- Application number: 06/405,760
- Filed: 1982-08-06
- Granted: 1983-08-16
- Earliest claimed: 1982-08-06
- Assignees: E. I. Du Pont de Nemours and Company
- Inventors: Thomas J. Hyde
- Web page: https://patentgrep.com/patent/US4399246A

## CPC

- C08K 5/43: Compounds containing sulfur bound to nitrogen
- C08K 3/34: Silicon-containing compounds
- C08K 3/346: {Clay}
- C08K 5/435: Sulfonamides
- C08K 5/544: containing nitrogen
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)

## Abstract

This invention is directed to a composition of matter which is derived from 50 to 75 parts of polyamide resin with a number average molecular weight of at least 11,000, plus 25 to 50 parts of a selected mineral filler, 0.2 to 0.9 parts of aminofunctional silane, and 0.2 to 0.9 parts of a selected sulfonamide. The composition provides molded parts with significantly improved falling-weight impact resistance at no sacrifice of rigidity under a wide variety of processing conditions.

## Claims

### Claim 1

A composition consisting essentially of
(a) about 50 to 80 parts by weight of at least one polyamide having a number average molecular weight of at least 11,000,
(b) about 20 to 50 parts by weight of at least one mineral filler that is substantially anhydrous and has a mean average particle size of 2.0 micrometers or less,
(c) about 0.2 to 0.9 parts by weight of at least one aminofunctional silane, and
(d) about 0.2 to 0.9 parts by weight of at least one N-substituted hydrocarbyl sulfonamide.

### Claim 2 (depends on 1)

The composition of claim 1 wherein the polyamide is a condensation product of a saturated aliphatic dicarboxylic acid of 4-12 carbons and a saturated aliphatic diamine of 4-14 carbons.

### Claim 3 (depends on 1)

The composition of claim 1 wherein the polyamide is polyhexamethylene adipamide.

### Claim 4 (depends on 1)

The composition of claim 1 wherein the polyamide is a mixture of poly(caprolactam) and polyhexamethylene adipamide.

### Claim 5 (depends on 1, 2, 3, 4)

The composition of claims 1, 2, 3 or 4 wherein the mineral filler is selected from calcined clay, wollastonite or talc.

### Claim 6

The composition of claims, 1, 2, 3 or 4 wherein the aminofunctional silane is an amino-(lower alkyl)tri(lower alkoxy) silane.

### Claim 7 (depends on 5)

The composition of claim 5 wherein the aminofunctional silane is an amino-(lower alkyl)tri(lower alkoxy) silane.

### Claim 8 (depends on 1)

The composition of claim 1 wherein the N-substituted hydrocarbyl sulfonamide has the formula ##STR2## wherein R.sub.1 is aryl of 6-10 carbons and R.sub.2 is alkyl of 1-6 carbons.

### Claim 9 (depends on 5)

The composition of claim 5 wherein the N-substituted hydrocarbyl sulfonamide has the formula ##STR3## wherein R.sub.1 is aryl of 6-10 carbons and R.sub.2 is alkyl of 1-6 carbons.

### Claim 10 (depends on 6)

The composition of claim 6 wherein the N-substituted hydrocarbyl sulfonamide has the formula ##STR4## wherein R.sub.1 is aryl of 6-10 carbons and R.sub.2 is alkyl of 1-6 carbons.

### Claim 11 (depends on 7)

The composition of claim 7 wherein the N-substituted hydrocarbyl sulfonamide has the formula ##STR5## wherein R.sub.1 is aryl of 6-10 carbons and R.sub.2 is alkyl of 1-6 carbons.