# US 4,399,168 A · Method of preparing coated cemented carbide product

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- Number: US 4,399,168 A
- Document ID: US4399168A
- Status: Granted
- Kind: A
- Application number: 06/278,473
- Filed: 1981-06-29
- Granted: 1983-08-16
- Earliest claimed: 1980-01-21
- Assignees: Santrade Ltd.
- Inventors: Gregor H. Kullander; Christopher G. Chatfield; Marian Mikus; Bo K. Westergren
- Web page: https://patentgrep.com/patent/US4399168A

## CPC

- C23C 16/403: {of aluminium, magnesium or beryllium}
- C23C 16/30: Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C 16/32: Carbides
- C23C 16/34: Nitrides {(C23C16/303 takes precedence)}
- C23C 16/36: Carbonitrides
- C23C 30/005: {on hard metal substrates}
- C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04)

## Abstract

An improved process for the production of coated cemented carbide products is disclosed. A cemented carbide substrate is treated to form a metal carbide, nitride or carbonitride coating. The coated substrate is heat treated at a temperature close to or near the melting point of the binder metal of the cemented carbide to diffuse elements from the substrate into the coating. An intermediate (second) metal carbide, nitride or carbonitride coating is thereafter applied and the portion of the second is oxidized, nitrided or sulfided without detrimentally affecting the adherence of the second coating. Thereafter, a wear-resistant oxide (e.g., aluminum oxide) coating is applied to form the improved coated carbide product.

## Claims

### Claim 1

Method of treating a cemented carbide substrate containing at least one carbide together with binder metal in order to improve its wear resistance and utility, which method consists essentially of the sequential steps of:
(a) treating the substrate in an atmosphere selected from carbide, nitride and carbonitride forming atmospheres to form or apply a coating essentially comprising at least one coat of at least one member selected from the group consisting of carbides, nitrides and carbonitrides of the elements Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Si and B;
(b) heat treating the coated substrate at a temperature close to or greater than the melting point of the binder phase in order to diffuse elements away from the substrate into said coating and from the coating into the substrate and to form a microrough surface on the substrate;
(c) treating the substrate from step (b) in an atmosphere selected from carbide, nitride and carbonitride forming atmospheres to form or apply a second coating essentially comprising at least one member selected from the group consisting of carbides, nitrides and carbonitrides of the elements Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Si and B;
(d) treating the resulting substrate with a nitrogen-containing gas to nitride a portion of the second coating without detrimentally effecting the adherence of the second coating to the said substrate; and
(e) applying a wear resistant oxide coating on the thus pretreated cemented carbide substrate.

### Claim 2

Method of treating a cemented carbide substrate containing at least one carbide together with binder metal in order to improve its wear resistance and utility, which method consists essentially of the sequential steps of:
(a) treating the substrate in an atmosphere selected from carbide, nitride and carbonitride forming atmospheres to form or apply a coating essentially comprising at least one coat of at least one member selected from the group consisting of carbides, nitrides and carbonitrides of the elements Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Si and B;
(b) heat treating the coated substrate at a temperature close to or greater than the melting point of the binder phase in order to diffuse elements from the substrate into said coating and from the coating into the substrate and to form a microrough surface on the substrate, the treatment of the substrate according to steps (a) and (b) above being performed as one operation, in which the member of the metals of the substrate forming the carbide, nitride and carbonitride is brought to diffuse from the interior of the substrate out to the surface;
(c) treating the substrate from step (b) in an atmosphere selected from carbide, nitride and carbonitride forming atmospheres to form or apply a second coating essentially comprising at least one member selected from the group consisting of carbides, nitrides and carbonitrides of the elements Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Si and B;
(d) treating the resulting substrate with a nitrogen-containing gas to nitride a portion of the second coating without detrimentally effecting the adherence of the second coating to the said substrate; and
(e) applying a wear resistant oxide coating on the thus pretreated cemented carbide substrate.