# US 4,398,936 A · Process for the preparation of a granular NPK fertilizer and granular NPK fertilizers obtained by this process

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 4,398,936 A
- Document ID: US4398936A
- Status: Granted
- Kind: A
- Application number: 06/213,502
- Filed: 1980-12-05
- Granted: 1983-08-16
- Earliest claimed: 1978-07-04
- Assignees: Unie van Kunstmestfabrieken B.V.
- Inventors: Johan W. Hoogendonk; Servatius J. Lucassen
- Web page: https://patentgrep.com/patent/US4398936A

## CPC

- C05G 1/00: Mixtures of fertilisers belonging individually to different subclasses of C05
- C05B 7/00: Fertilisers based essentially on alkali or ammonium orthophosphates (C05B11/00 takes precedence)
- C05G: MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS (organic fertilisers containing added bacterial cultures, mycelia, or the like C05F11/08; organic fertilisers containing plant vitamins or hormones C05F11/10); FERTILISERS CHARACTERISED BY THEIR FORM
- C05B: PHOSPHATIC FERTILISERS

## Abstract

Storage-stable nitrogen-phosphorous-potassium fertilizer granules and prills are made by adding to a molten or aqueous solution mixture of ammonium nitrate and ammonium phosphate, a particulate potassium salt, typically potassium chloride, in which the particles have an average size no greater than 55 microns and less than 1% by weight of the particles are larger than 150 microns. The potassium salt is added without the need for preheating and at a temperature of between 5.degree. and 40.degree. C. to the mixture where it is simultaneously converted. The resulting mixture is granulated or prilled into NPK fertilizer particles.

## Claims

### Claim 1

In a process for the preparation of granules of NPK fertilizer comprising adding a solid potassium salt to a liquid melt or aqueous solution containing ammonium nitrate and ammonium phosphate and granulating the resulting mixture, the improvement comprising adding said potassium salt to said liquid melt or aqueous solution in the form of particles having a temperature in the range of between 5.degree. C. and 40.degree. C. and an average particle size of at most 55 microns with at most 1 percent by weight of particles over 150 microns, whereupon said resulting mixture is granulated, thereby forming storage-stable granules of NPK fertilizer.

### Claim 2 (depends on 1)

The process according to claim 1 wherein the potassium salt has an average particle size of at most 50 microns.

### Claim 3 (depends on 1, 2)

The process according to claims 1 or 2 wherein the potassium salt is added to said mixture without preheating and at a temperature of about 10.degree. to about 25.degree. C.

### Claim 4 (depends on 1)

The process according to claim 1 wherein the potassium salt is fed to a granulating screw to which also a liquid mixture of ammonium nitrate and ammonium phosphate is fed.

### Claim 5 (depends on 1, 2)

The process according to claims 1 or 2 wherein the potassium salt is potassium chloride.

### Claim 6

In a process for the preparation of granules of NPK fertilizer comprising adding solid potassium salt to a liquid melt or aqueous solution containing ammonium nitrate and thereafter adding ammonium phosphate, and granulating the resulting mixture, the improvement comprising adding said potassium salt to said liquid melt or aqueous solution in the form of particles having a temperature in the range of between 5.degree. C. and 40.degree. C. and an average particle size of at most 55 microns with at most 1 percent by weight of particles over 150 microns, whereupon said resulting mixture is granulated, thereby forming storage-stable granules of NPK fertilizer.

### Claim 7 (depends on 6)

The process according to claim 6 wherein the potassium salt has an average particle size of at most 50 microns.

### Claim 8 (depends on 6, 7)

The process according to claims 6 or 7, wherein the potassium salt particles are added without preheating and at a temperature of between 10.degree. and 25.degree. C.

### Claim 9 (depends on 6, 7)

The process according to claims 6 or 7, wherein the potassium salt is potassium chloride.