# US 4,398,924 A · Sulfur oxide reduction in a coal gasification process

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- Number: US 4,398,924 A
- Document ID: US4398924A
- Status: Granted
- Kind: A
- Application number: 06/327,009
- Filed: 1981-12-03
- Granted: 1983-08-16
- Earliest claimed: 1981-12-03
- Assignees: Chevron Research Company
- Inventors: C. Richard Hsieh; Paul T. Roberts
- Web page: https://patentgrep.com/patent/US4398924A

## CPC

- C10J 3/54: Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
- C10J 3/12: using solid heat-carriers
- C10J 3/526: {for entrained flow gasifiers}
- C10J 3/82: Gas withdrawal means
- C10J 2300/093: Coal
- C10J 2300/0956: Air or oxygen enriched air
- C10J 2300/0976: as steam
- C10J 2300/0996: Calcium-containing inorganic materials, e.g. lime
- C10J 2300/1606: Combustion processes
- C10J 2300/1807: Recycle loops, e.g. gas, solids, heating medium, water
- C10J: PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES (synthesis gas from liquid or gaseous hydrocarbons C01B; underground gasification of minerals E21B43/295); CARBURETTING AIR OR OTHER GASES

## Abstract

A method for reduction of sulfur oxides generated by a coal gasification process is disclosed wherein a regenerable sorbent absorbs the sulfur oxide in an oxidizing atmosphere and releases the sulfur oxides in the form of hydrogen sulfide in a reducing atmosphere.

## Claims

### Claim 1

In the coal gasification process comprising:
(a) introducing a coal containing sulfur and a heat transfer material into a reaction vessel;
(b) passing steam through said vessel to react with said coal to form a hot char and a gaseous product, whereby hydrogen sulfide is released from the coal and wherein the heat necessary for said reaction is supplied by the heat-transfer material;
(c) removing the heat-transfer material from said vessel;
(d) introducing at least a portion of the heat-transfer material into a combustion zone;
(e) removing the hot char, the gaseous product and the hydrogen sulfide from the vessel, separating the hot char from the gaseous product and the hydrogen sulfide, and introducing at least a portion of the hot char into the combustion zone;
(f) heating the heat-transfer material to an elevated temperature in said combustion zone by combusting the char with air, thereby releasing sulfur oxides, and contacting the heat-transfer material with the combusted char; and
(g) recycling at least a portion of said heat-transfer material to said reaction vessel as a source of heat-transfer material;
the improvement comprising a method of reducing said sulfur oxides comprising
(1) absorbing onto a regenerable sorbent the sulfur oxides released in the combustion zone;
(2) transferring said regenerable sorbent to the reaction vessel;
(3) releasing the sulfur oxides from the regenerable sorbent in the reaction vessel in the form of hydrogen sulfide; and
(4) recycling the regenerable sorbent to the combustion zone to absorb further sulfur oxides in step (2).

### Claim 2 (depends on 1)

A method according to claim 1 wherein said regenerable sorbent is selected from the group consisting of limestone, dolomites, limes, calcium aluminate cements, calcium oxide, magnesium oxide, barium oxide and barium titanate.

### Claim 3 (depends on 2)

A method according to claim 2 wherein said regenerable sorbent contains calcium.

### Claim 4 (depends on 3)

A method according to claim 3 wherein the operating temperatures of both the combustion zone and the reaction vessel are in excess of 1600.degree. F.

### Claim 5

In the coal gasification process comprising:
(a) introducing a solid heat-transfer material into an upper portion of a vertically elongated reaction vessel, the vessel having a means for substantially impeding vertical backmixing of vertically moving solids in the vessel;
(b) introducing a coal containing sulfur into a lower portion of said vessel, the physical characteristics of the heat-transfer material and the coal differing such that a superficial velocity of a fluid flowing upwardly through the vessel is greater than the minimum fluidizing velocity of the heat-transfer material and the terminal velocity of the coal, but is less than the terminal velocity of the heat-transfer material;
(c) passing steam upwardly through said vessel at a rate sufficient to fluidize the heat-transfer material and entrain the coal to maintain substantially countercurrent vertical flow of the heat-transfer material and coal in the vessel without substantial top-to-bottom backmixing of the heat-transfer material and the coal in the vessel, whereby the heat-transfer material substantially flows downwardly in a fluidized state through the vessel and the coal substantially flows upwardly in an entrained state through the vessel, whereby the steam reacts with the coal to form a hot char and a gaseous product and whereby hydrogen sulfide is released from said coal;
(d) removing the heat-transfer material from a lower end of said vessel at a temperature substantially lower than the temperature at which the heat-transfer material was introduced into the vessel;
(e) introducing at least a portion of the heat-transfer material into an upper portion of a vertically elongated combustion zone having means for substantially impeding vertical backmixing of vertically moving solids substantially throughout the combustion zone;
(f) removing the hot char, the gaseous product and the hydrogen sulfide from an upper end of said vessel, separating the hot char from the gaseous product and the hydrogen sulfide, and introducing at least a portion of the hot char into a lower portion of the combustion zone;
(g) heating the heat-transfer material to an elevated temperature in said combustion zone by contacting the heat-transfer material with the hot char while maintaining substantially countercurrent plug flow of the heat-transfer material and the char by passing air upwardly through the combustion zone at a rate sufficient to fluidize the heat-transfer material and entrain the char, whereby the heat-transfer material substantially flows downwardly through the combustion zone in a fluidized state and is heated to an elevated temperature while the char substantially flows upwardly through the combustion zone in an entrained state and is combusted, thereby releasing sulfur oxides; and
(h) recycling at least a portion of said heat-transfer material to said reaction vessel as a source of heat-transfer material;
the improvement comprising a method of reducing said sulfur oxides comprising:
(1) incorporating a regenerable sorbent into said heat-transfer material;
(2) absorbing onto the regenerable sorbent the sulfur oxides released in the combustion zone;
(3) transferring said regenerable sorbent with the heat-transfer material to the reaction vessel;
(4) releasing the sulfur oxides from the regenerable sorbent in the reaction vessel in the form of hydrogen sulfides; and
(5) recycling the regenerable sorbent to the combustion zone to absorb further sulfur oxides in Step (2).

### Claim 6 (depends on 5)

A method according to claim 5 wherein said regenerable sorbent is selected from the group consisting of limestone, dolomites, limes, calcium aluminate cements, calcium oxide, magnesium oxide, barium oxide and barium titanate.

### Claim 7 (depends on 6)

A method according to claim 6 wherein said regenerable sorbent contains calcium.

### Claim 8 (depends on 7)

A method according to claim 7 wherein the operating temperatures of both the combustion zone and the reaction vessel are in excess of 1600.degree. F.