# US 4,398,769 A · Method for fragmenting underground formations by hydraulic pressure > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,398,769 A - Document ID: US4398769A - Status: Granted - Kind: A - Application number: 06/206,088 - Filed: 1980-11-12 - Granted: 1983-08-16 - Earliest claimed: 1980-11-12 - Assignees: Occidental Research Corporation - Inventors: Charles H. Jacoby - Web page: https://patentgrep.com/patent/US4398769A ## CPC - E21B 43/26: by forming crevices or fractures - E21B 43/263: using explosives - E21B 43/283: {in association with a fracturing process} - E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS ## Abstract An in situ leaching or solution mining process is conducted in a subterranean cavity in communication with a well bore. The subterranean cavity is gradually enlarged by inducing spallation of formation particles and/or collapse of the roof into the cavity by repeatedly cycling the hydraulic pressure in the subterranean cavity. The hydraulic pressure is preferably increased during a period of at least about two hours. The hydraulic pressure can be gradually decreased during a period of at least about two hours or can be suddenly decreased. Rapid pressure pulses can be applied to liquid in the subterranean cavity by detonation of shaped charges of explosive with the axis of force of the charge being directed along the axis of the well. ## Claims ### Claim 1 A method for enhancing exposure of leachable mineral values adjacent a solution mining cavity having a substantially unsupported roof in a subterranean formation comprising the steps of: substantially filling such a subterranean cavity with a liquid; and repeatedly increasing hydraulic pressure of the liquid in the subterranean cavity from a minimum pressure of about the hydraulic head between the subterranean cavity and the ground surface or less, to a maximum pressure sufficient to lift the roof of the cavity and less than sufficient for lifting the overburden above the top of the stress arch which forms over the subterranean cavity, and then decreasing hydraulic pressure to such minimum pressure, the time interval of increasing hydraulic pressure to the maximum pressure being at least about two hours. ### Claim 2 (depends on 1) A method as recited in claim 1 wherein hydraulic pressure in the subterranean cavity is suddenly decreased from about the maximum pressure to about the minimum pressure. ### Claim 3 (depends on 1) A method as recited in claim 1 wherein the hydraulic pressure in the subterranean cavity is gradually decreased from about the maximum pressure to about the minimum pressure during a period of at least about two hours. ### Claim 4 (depends on 1) A method as recited in claim 1 wherein the liquid comprises a solvent for a mineral constituent of the subterranean formation. ### Claim 5 (depends on 4) A method as recited in claim 4 comprising continually introducing a liquid comprising a solvent and withdrawing a pregnant solution containing dissolved mineral constituents from the subterranean cavity. ### Claim 6 (depends on 1) A method as recited in claim 1 wherein the maximum hydraulic pressure is in the order of about 1.6 to 2.7 times the hydraulic head between the subterranean cavity and the ground surface. ### Claim 7 (depends on 1) A method as recited in claim 1 wherein the minimum pressure is less than the hydrostatic head between the cavity and the ground surface. ### Claim 8 (depends on 1) A method as recited in claim 1 practiced in a formation containing clay further comprising the preliminary steps of: fracturing such formation for establishing fluid communication between an inlet well and an outlet well; maintaining sufficient hydraulic pressure in such formation for propping open fractures; and circulating solvent liquid through such fractures for dissolving mineral constituents of the formation. ### Claim 9 (depends on 1) A method as recited in claim 1 practiced in a formation containing swellable clay comprising including sufficient ionic salt in such liquid for inhibiting swelling of the clay. ### Claim 10 (depends on 9) A method as recited in claim 9 wherein the ionic salt comprises sodium chloride. ### Claim 11 A method for promoting fragmentation adjacent a subterranean cavity having a substantially unsupported roof in a subterranean formation, and including a stress arch over the cavity transferring load from overburden above the cavity to locations spaced laterally from the cavity, comprising the steps of: substantially filling such a cavity with a liquid; and repeatedly cycling hydraulic pressure of liquid in the subterranean cavity between a minimum pressure and a maximum pressure sufficient to reverse stress in formation underlying the stress arch over the cavity from tension to compression and less than sufficient for lifting overburden between the top of the stress arch and the ground surface. ### Claim 12 (depends on 11) A method as recited in claim 11 wherein the hydraulic pressure in the subterranean cavity is increased from the minimum pressure to the maximum pressure for a period of at least about two hours. ### Claim 13 (depends on 11) A method as recited in claim 11 wherein the hydraulic pressure in the subterranean cavity is gradually decreased from about the maximum pressure to about the minimum pressure during a period of at least about two hours. ### Claim 14 (depends on 11) A method as recited in claim 11 wherein hydraulic pressure in the subterranean cavity is suddenly decreased from about the maximum pressure to about the minimum pressure. ### Claim 15 (depends on 11) A method as recited in claim 11 wherein the minimum pressure is less than the hydrostatic head between the cavity and the ground surface. ### Claim 16 (depends on 11) A method as recited in claim 11 wherein the liquid comprises a solvent for a mineral constituent of the subterranean formation. ### Claim 17 (depends on 16) A method as recited in claim 16 comprising continually introducing a liquid comprising a solvent and withdrawing a pregnant solution containing dissolved mineral constituents from the subterranean cavity. ### Claim 18 (depends on 17) A method as recited in claim 17 further comprising the step of withdrawing liquid from a portion of a well between the cavity and the ground surface for reducing hydraulic head above the cavity. ### Claim 19 (depends on 11) A method as recited in claim 11 practiced in a formation containing clay further comprising the preliminary steps of: fracturing such formation for establishing fluid communication between an inlet well and an outlet well; maintaining sufficient hydraulic pressure in such formation for propping open fractures; and circulating solvent liquid through such fractures for dissolving mineral constituents of the formation. ### Claim 20 A method for enlarging a cavity having a substantially unsupported roof in a subterranean formation comprising the steps of: substantially filling the subterranean cavity with liquid; increasing hydraulic pressure in the subterranean cavity during a period of at least about two hours, the maximum hydraulic pressure in the subterranean cavity being less than sufficient for lifting overburden above the top of a stress arch over the subterranean cavity; decreasing hydraulic pressure in the subterranean cavity during a subsequent period of at least about two hours; and alternately repeating the increasing and decreasing steps for cyclic flexing of the roof of the subterranean cavity. ### Claim 21 (depends on 20) A method as recited in claim 20 wherein the minimum pressure is less than the hydrostatic head between the cavity and the ground surface. ### Claim 22 (depends on 20) A method as recited in claim 20 wherein hydraulic pressure is gradually increased during a period of at least about two hours from a minimum pressure of about the hydraulic head between the subterranean cavity and the ground surface to a selected maximum pressure. ### Claim 23 (depends on 20) A method as recited in claim 20 practiced in a formation containing clay further comprising the preliminary steps of: fracturing such formation for establishing fluid communication between an inlet well and an outlet well; maintaining sufficient hydraulic pressure in such formation for propping open fractures; and circulating solvent liquid through such fractures for dissolving mineral constituents of the formation. ### Claim 24 (depends on 20) A method as recited in claim 20 practiced in a formation containing swellable clay comprising including sufficient ionic salt in such liquid for inhibiting swelling of the clay. ### Claim 25 (depends on 24) A method as recited in claim 24 wherein the ionic salt comprises sodium chloride. ### Claim 26 (depends on 20) A method as recited in claim 20 wherein the liquid comprises a solvent for a mineral constituent of the subterranean formation. ### Claim 27 A method for enlarging a subterranean cavity having a substantially unsupported roof in a subterranean formation and for exposing a leachable mineral constituent of the subterranean formation comprising the steps of: substantially filling the subterranean cavity with a liquid; increasing hydraulic pressure in the subterranean cavity during the period of at least about two hours, the maximum hydraulic pressure in the subterranean cavity being less than sufficient for lifting overburden above the top of a stress arch over the subterranean cavity; and thereafter suddenly decreasing the hydraulic pressure in the subterranean cavity. ### Claim 28 (depends on 27) A method as recited in claim 27 wherein the maximum hydraulic pressure in the cavity is about 1.6 to 2.7 times the hydraulic head between the subterranean cavity and the ground surface. ### Claim 29 (depends on 27) A method as recited in claim 27 wherein the minimum pressure is less than the hydrostatic head between the cavity and the ground surface. ### Claim 30 (depends on 27) A method as recited in claim 27 practiced in a formation containing clay further comprising the preliminary steps of: fracturing such formation for establishing fluid communication between an inlet well and an outlet well; maintaining sufficient hydraulic pressure in such formation for propping open fractures; and circulating solvent liquid through such fractures for dissolving mineral constituents of the formation. ### Claim 31 (depends on 27) A method as recited in claim 27 wherein the liquid comprises a solvent for a mineral constituent of the subterranean formation. ### Claim 32 (depends on 31) A method as recited in claim 31 comprising continually introducing a liquid comprising a solvent and withdrawing a pregnant solution containing dissolved mineral constituents from the subterranean cavity. ### Claim 33 (depends on 32) A method as recited in claim 32 further comprising the step of withdrawing liquid from a portion of a well between the cavity and the ground surface for reducing hydraulic head above the cavity. ### Claim 34 A method for in situ leaching of at least one mineral constituent in a subterranean formation comprising the steps of: drilling at least one well from the ground surface to a subterranean formation selected for leaching; forming a cavity in the subterranean formation adjacent such a well; substantially filling the subterranean cavity with a solvent liquid for leaching mineral constituents of the subterranean formation; withdrawing a pregnant solution containing at least one dissolved mineral constituent from the subterranean cavity; repeatedly cyling hydraulic pressure of liquid in the subterranean cavity between a minimum pressure and a maximum pressure less than sufficient for lifting the overburden between the subterranean cavity and the ground surface, for promoting spallation of formation particles and enlarging the subterranean cavity; and withdrawing at least a portion of such formation particles with the pregnant solution. ### Claim 35 (depends on 34) A method as recited in claim 34 further comprising the step of withdrawing liquid from a portion of such a well between the cavity and the ground surface for reducing hydraulic head above the cavity. ### Claim 36 (depends on 34) A method as recited in claim 34 wherein the hydraulic pressure in the subterranean cavity is gradually increased from about the minimum pressure to about the maximum pressure during a period of at least about two hours. ### Claim 37 (depends on 34) A method as recited in claim 34 wherein hydraulic pressure in the subterranean cavity is suddenly decreased from about the maximum pressure to about the minimum pressure. ### Claim 38 (depends on 34) A method as recited in claim 34 wherein the hydraulic pressure in the subterranean cavity is gradually decreased from about the maximum pressure to the minimum pressure during a period of at least about two hours. ### Claim 39 (depends on 34) A method as recited in claim 34 practiced in a formation containing swellable clay comprising including sufficient ionic salt in such liquid for inhibiting swelling of the clay. ### Claim 40 (depends on 39) A method as recited in claim 39 wherein the ionic salt comprises sodium chloride. ### Claim 41 (depends on 34) A method as recited in claim 34 wherein hydraulic pressure in the subterranean cavity is gradually increased by introducing a quantity of solvent liquid into the subterranean cavity during a period of at least about two hours which is greater than the quantity of pregnant solution withdrawn from the cavity during such period. ### Claim 42 (depends on 41) A method as recited in claim 41 wherein the quantity of pregnant solution withdrawn from the subterranean cavity during a period of at least about two hours is greater than the quantity of solvent liquid introduced during such period for gradually reducing hydraulic pressure in the subterranean cavity. ### Claim 43 (depends on 41) A method as recited in claim 41 wherein the hydraulic pressure in the subterranean cavity is reduced suddenly. ### Claim 44 A method for in situ leaching of mineral constituents from a subterranean formation comprising the steps of: drilling at least one well from the ground surface to a subterranean formation to be leached; forming an initial cavity in the subterranean formation in communication with such a well; substantially filling the initial subterranean cavity with a solvent liquid for dissolving mineral constituents from the subterranean formation; withdrawing a pregnant solution containing dissolved mineral constituents from the subterranean cavity; increasing hydraulic pressure in the subterranean cavity during a period of at least about two hours wherein the maximum hydraulic pressure in the subterranean cavity is less than sufficient for lifting overburden above the top of the stress arch formed over the cavity; and thereafter decreasing hydraulic pressure in the subterranean cavity for promoting spallation of formation particles into the cavity; and withdrawing at least a portion of such formation particles from the subterranean cavity. ### Claim 45 (depends on 44) A method as recited in claim 44 wherein hydraulic pressure in the subterranean cavity is gradually increased during a period of at least about two hours from a minimum pressure of about the hydraulic head between the subterranean cavity and the ground surface, and a selected maximum pressure. ### Claim 46 (depends on 45) A method as recited in claim 45 wherein the hydraulic pressure in the subterranean cavity is suddenly decreased from about the maximum pressure to about the minimum pressure. ### Claim 47 (depends on 45) A method as recited in claim 45 wherein the hydraulic pressure in the subterranean cavity is gradually decreased from about the maximum pressure to about the minimum pressure during a period of at least about two hours. ### Claim 48 (depends on 43) A method as recited in claim 43 wherein hydraulic pressure in the subterranean cavity is gradually increased during a period of at least about two hours from a minimum pressure less than the hydraulic head between the subterranean cavity and the ground surface, and a selected maximum pressure.