# US 4,398,642 A · Multi-ply vessel and method for production thereof

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 4,398,642 A
- Document ID: US4398642A
- Status: Granted
- Kind: A
- Application number: 06/269,056
- Filed: 1981-06-02
- Granted: 1983-08-16
- Earliest claimed: 1979-11-02
- Assignees: Toyo Boseki Kabushiki Kaisha
- Inventors: Tadashi Okudaira; Akio Tsuboi; Shigeharu Sugihara; Yoshihisa Hama
- Web page: https://patentgrep.com/patent/US4398642A

## CPC

- B32B 27/08: of synthetic resin
- B32B 27/36: comprising polyesters
- B32B 2307/412: Transparent
- B32B 2307/724: Permeability to gases, adsorption
- B32B 2367/00: Polyesters, e.g. PET, i.e. polyethylene terephthalate
- Y10S 428/91: Product with molecular orientation
- Y10T 428/1352: Polymer or resin containing [i.e., natural or synthetic]
- Y10T 428/31736: Next to polyester
- Y10T 428/31786: Of polyester [e.g., alkyd, etc.]
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

A multi-ply vessel which comprises an inner layer (A) composed of a thermoplastic polyester resin, a middle layer (B) composed of a metaxylylene group-containing polyamide resin and an outer layer (C) composed of a synthetic resin having impermeability to moisture, said inner layer (A) and middle layer (B) being oriented in at least one direction at the thin part of the vessel wall. This vessel is produced by orienting a parison having a multi-ply structure of the inner layer (A), the middle layer (B) and the outer layer (C) in a draw ratio of 1 to 4 times in longitudinal direction and of 2 to 7 times in crosswise direction at a temperature of from Tg+15.degree. C. to 2(Tg)+15.degree. C. (wherein Tg is the glass transition temperature of the thermoplastic polyester resin). This vessel has high transparency as well as excellent chemical resistance, impact resistance and the like because a thermoplastic polyester resin is used as the inner layer (A) and also has excellent gas barrier properties against oxygen because the metaxylylene group-containing polyamide resin is used as the middle layer (B).

## Claims

### Claim 1

A biaxially oriented blow-molded transparent multi-ply vessel having dimensional stability and form retention characteristics having a multi-ply structure composed of at least two kinds of synthetic resins which comprises an inner layer composed of a thermoplastic polyester resin having an intrinsic viscosity of 0.55 or more, an intermediate layer composed of metaxylylene group-containing polyamide resin and an outer layer composed of a synthetic resin having impermeability to moisture, said layers of the thermoplastic polyester resin and the metaxylylene group-containing polyamide resin being oriented in at least one direction at the thin part of the vessel wall.

### Claim 2 (depends on 1)

A multi-ply vessel according to claim 1 wherein the thermoplastic polyester resin is that having repeating units consisting predominantly of ethylene terephthalate.

### Claim 3 (depends on 1)

A multi-ply vessel according to claim 1 wherein the synthetic resin having impermeability to moisture of the outer layer is a thermoplastic polyester resin.

### Claim 4 (depends on 3)

A multi-ply vessel according to claim 3 wherein the thermoplastic polyester resin is that having repeating units consisting predominantly of ethylene terephthalate.

### Claim 5 (depends on 1)

The vessel as in claim 1 wherein said layers of polyester resin and polyamide resin are oriented to such a degree that the birefringence at the thin part of the vessel wall is 0.03 or more.

### Claim 6 (depends on 1)

The vessel as in claim 1 which consists of said layers.