# US 4,397,969 A · Aqueous dispersions of polyvinylbutyral having low content of hydrosolubles > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,397,969 A - Document ID: US4397969A - Status: Granted - Kind: A - Application number: 06/070,648 - Filed: 1979-08-28 - Granted: 1983-08-09 - Earliest claimed: 1977-04-22 - Assignees: Rhone-Poulenc Industries - Inventors: Jean-Marie Pouchol - Web page: https://patentgrep.com/patent/US4397969A ## CPC - C09D 129/14: Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols - C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D) ## Abstract Aqueous dispersions of particulate polyvinylbutyral are disclosed, said dispersions comprising an amount of hydrosolubles dissolved in the aqueous phase thereof, the content in the dispersions of said dissolved hydrosolubles being less than about 2.5% by weight, based upon the weight of the polyvinylbutyral. Said dispersions are useful in the formulation of certain coating compositions, e.g., paints and varnishes. ## Claims ### Claim 1 A process for preparing an aqueous dispersion of polyvinylbutyral having a particle size of from about 0.01.mu. to 5.mu. and containing, dissolved therein, less than about 2.5% by weight of hydrosoluble compounds relative to the weight of polyvinylbutyral, comprising the steps of (a) bringing an aqueous dispersion of the polyvinylbutyral, formed by reacting polyvinyl alcohol with butyraldehyde in an aqueous medium, in an aqueous solution containing, dissolved therein, an amount of no more than 2.5% by weight of hydrosoluble compounds relative to the weight of polyvinylbutyral, into contact with a semipermeable ultrafiltration membrane in such a manner that a portion of the aqueous dispersion comprising the polyvinylbutyral particles is retained and a sufficient portion of the aqueous solution is filtrated through the membrane in order to remove such an amount of hydrosoluble compounds that the amount of hydrosoluble compounds within the retained portion of the dispersion is reduced to less than about 2.5% by weight relative to the weight of the polyvinylbutyral and (b) in the course of the ultrafiltration, adding to the retained portion of the dispersion a sufficient amount of deionized water in order to replace at least a major part of the filtrated off portion of the aqueous solution. ### Claim 2 (depends on 1) The process as defined in claim 1, wherein the aqueous solution is continuously filtrated through the semipermeable ultrafiltration membrane and deionized water is simultaneously added to the retained portion of the dispersion. ### Claim 3 (depends on 1) The process as defined in claim 1, wherein the semipermeable membrane has a high cut-off threshold, which is generally between 5,000 and 100,000, expressed as the value of the molecular weight of standard proteins in a neutral buffered medium. ### Claim 4 (depends on 1) The process as defined in claim 1, wherein the aqueous solution passes through the semipermeable ultrafiltration membrane at a rate of more than 0.5 m/second. ### Claim 5 (depends on 4) The process as defined in claim 4, wherein the rate is between 1 and 2 m/second. ### Claim 6 (depends on 1) The process as defined in claim 1, wherein the difference in pressure of between 0.1 and 6 bars exists between the pressure prevailing on each side of the membrane. ### Claim 7 (depends on 6) The process as defined in claim 6, wherein the difference in pressure is between 1.5 and 3 bars. ### Claim 8 (depends on 1) The process as defined in claim 1, wherein the temperature of the dispersion is between 0.degree. and 100.degree. C. ### Claim 9 (depends on 8) The process as defined in claim 8, wherein the temperature is between 0.degree. and 50.degree. C. ### Claim 10 (depends on 1) In a composition of matter comprising an aqueous dispersion of particles of polyvinylbutyral and an amount of hydrosolubles dissolved in the aqueous phase thereof, the improvement which comprises the amount of such dissolved hydrosolubles in the dispersion being less than about 2.5% by weight, based upon the weight of the polyvinylbutyral and the polyvinylbutyral particles having a particle size of between 0.01.mu. and 5.mu., and the dispersion being obtained by the process as defined in claim 1.