# US 4,397,942 A · Photographic material, process for the production thereof, process for the production of photographic images and new compounds

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- Number: US 4,397,942 A
- Document ID: US4397942A
- Status: Granted
- Kind: A
- Application number: 06/314,180
- Filed: 1981-10-23
- Granted: 1983-08-09
- Earliest claimed: 1980-10-30
- Assignees: Agfa-Gevaert
- Inventors: Anita von Konig; Franz Moll; Hermann Oediger
- Web page: https://patentgrep.com/patent/US4397942A

## CPC

- G03C 1/346: {Organic derivatives of bivalent sulfur, selenium or tellurium}
- C07D 327/04: Five-membered rings
- G03C: PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES (for photomechanical purposes G03F); PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY (photographic processes characterised by the use or manipulation of apparatus classifiable per se in subclass G03B, see G03B; photomechanical production of textured or patterned surfaces G03F; electrophotography, magnetography G03G)
- C07D: HETEROCYCLIC COMPOUNDS (macromolecular compounds C08)

## Abstract

Compounds of the formula ##STR1## are suitable for the stabilization of the latent image in silver halide photographic materials.

## Claims

### Claim 1

A photosensitive material for the production of photographic images containing at least one photosensitive silver halide emulsion layer and, optionally other layers, and having a soluble compound capable of increasing the stability of latent image nuclei in a quantity of from 10 to 5000 mg per mole of silver halide,
wherein said soluble compound corresponds to the following formula ##STR7## wherein R.sup.1 represents hydrogen, an alkyl group, substituted alkyl group, an acyl group, a substituted acyl group, or a 5- or 6-membered heterocycle.

### Claim 2 (depends on 1)

A material as claimed in claim 1, wherein R.sup.1 represents hydrogen, an alkyl group containing from 1 to 18 carbon atoms substituted by an alkoxy, cycloalkoxy, aralkoxy or aroxy group, an aliphatic acyl group containing at most 20 carbon atoms or an oxygen-containing heterocycle.

### Claim 3 (depends on 1)

A material as claimed in claim 1, wherein R.sup.1 represents hydrogen or an alkyl group substituted by an alkoxy group.

### Claim 4 (depends on 1)

A material as claimed in claim 1, wherein at least 5-hydroxy-2-oxo-1,3-benzoxathiol or 5-acetoxy-2-oxo-1,3-benzoxathiol or 5-(2-tetrahydropyranyloxy)-2-oxo-1,3-benzoxathiol is present.

### Claim 5 (depends on 1)

A material as claimed in claim 1, wherein R.sup.1 represents an acetyl, propionyl, butyryl, pivaloyl, hexanoyl, lauroyl or stearyl group or a substituted acyl radical corresponding to the following general formula: ##STR8## wherein R.sup.2 is alkylene, arylene or aralkylene.

### Claim 6

A process for the production of photosensitive photographic material having at least one layer containing silver halide comprising the steps of
reacting silver and halide salts to precipitate a silver halide,
ripening said silver halide in an emulsion,
incorporating in said emulsion a soluble stabilizing compound in a quantity of from 10 to 5000 mg per mole of silver halide according to the following formula ##STR9## wherein R.sup.1 represents hydrogen, an alkyl group, substituted alkyl group, an acyl group, a substituted acyl group, or a 5- or 6-membered heterocycle and applying the emulsion containing the stabilizer on a layer support.

### Claim 7 (depends on 6)

In the process for the production of photosensitive photographic material as claimed in claim 6, the steps comprising
physical ripening of the emulsion and chemical ripening,
and incorporating said soluble stabilizing compound before chemical ripening.

### Claim 8

A process for the production of photographic images in a photographic material including the steps of
imagewise exposing a photosensitive material containing at least one photosensitive silver halide emulsion layer having a soluble compound capable of increasing the stability of latent image nuclei in a quantity of from 10 to 5000 mg per mol of silver halide and corresponding to the following formula ##STR10## wherein R.sup.1 represents hydrogen, an alkyl group, substituted alkyl group, an acyl group, a substituted acyl group, or a 5- or 6-membered heterocycle
developing the latent image of the exposed material in a photographic developer
and providing a developed image.