# US 4,397,924 A · High temperature solid state storage cell

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- Number: US 4,397,924 A
- Document ID: US4397924A
- Status: Granted
- Kind: A
- Application number: 06/273,797
- Filed: 1981-06-15
- Granted: 1983-08-09
- Earliest claimed: 1981-06-15
- Assignees: Duracell Inc.
- Inventors: Jesse R. Rea; Milton Kallianidis; G. Stephen Kelsey
- Web page: https://patentgrep.com/patent/US4397924A

## CPC

- H01M 4/40: Alloys based on alkali metals
- H01M 10/39: working at high temperature
- Y02E 60/10: Energy storage using batteries
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- Y10T 29/49108: Electric battery cell making
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

A completely solid state high temperature storage cell comprised of a solid rechargeable cathode such as TiS.sub.2, a solid electrolyte which remains solid at the high temperature operating conditions of the cell and which exhibits high ionic conductivity at such elevated temperatures such as an electrolyte comprised of lithium iodide, and a solid lithium or other alkali metal alloy anode (such as a lithium-silicon alloy) with 5-50% by weight of said anode being comprised of said solid electrolyte.

## Claims

### Claim 1

A rechargeable solid state cell, operating at temperatures above about 300.degree. C., comprising a solid rechargeable cathode, a solid alkali metal alloy anode, and a solid electrolyte comprised of an ionically conductive material comprised of said alkali metal characterized in that said anode contains 5-50% by weight thereof of said solid electrolyte material homogeneously dispersed therein and wherein all of said cathode, electrolyte and anode remain in the solid state during cell operation.

### Claim 2 (depends on 1)

The cell of claim 1 wherein said alkali metal is lithium.

### Claim 3 (depends on 2)

The cell of claim 2 wherein said solid electrolyte is comprised of LiI.

### Claim 4 (depends on 3)

The cell of claim 3 wherein said solid electrolyte further comprises Al.sub.2 O.sub.3.

### Claim 5 (depends on 4)

The cell of claim 4 wherein said Al.sub.2 O.sub.3 was treated with an organo-metallic lithium compound prior to its use as part of said electrolyte.

### Claim 6 (depends on 5)

The cell of claim 5 wherein said solid electrolyte comprises 20% by weight of said anode.

### Claim 7 (depends on 1, 2, 3, 4, 5, 6)

The cell of claims 1, 2, 3, 4, 5 or 6 wherein said rechargeable solid cathode is comprised of a metal chalcogenide.

### Claim 8 (depends on 7)

The cell of claim 7 wherein said metal chalcogenide is TiS.sub.2.

### Claim 9 (depends on 2)

The cell of claim 2 wherein said lithium is alloyed with one or more members of the group consisting of silicon, aluminum and boron.

### Claim 10 (depends on 8, 9)

The cell of claims 8 or 9 wherein said alkali metal alloy anode is comprised of a lithium silicon alloy.

### Claim 11

A method of making a solid state cell with improved recharging characteristics, said cell comprising a solid lithium anode, and solid lithium salt electrolyte and a solid cathode capable of being recharged, with said cell being operated at temperatures above about 300.degree. C. and wherein all of said anode, cathode and electrolyte remain in the solid state during cell operation, said method comprising the steps of forming a lithium alloy, then homogeneously dispersing the same material as in said electrolyte into said lithium alloy in a range of 5-50% by weight thereof and forming said anode, with said anode, electrolyte and cathode being compressed together to form said cell.

### Claim 12 (depends on 11)

The method of claim 11 wherein said electrolyte is comprised of LiI.