# US 4,397,883 A · Electrographic recording material > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,397,883 A - Document ID: US4397883A - Status: Granted - Kind: A - Application number: 06/218,868 - Filed: 1980-12-22 - Granted: 1983-08-09 - Earliest claimed: 1980-12-22 - Assignees: Monsanto Company - Inventors: Irving Serlin - Web page: https://patentgrep.com/patent/US4397883A ## CPC - G03G 5/0217: {Inorganic components} - C08F 8/44: Preparation of metal salts or ammonium salts - G03G 5/0208: {obtained by reactions only involving carbon-to-carbon unsatured bonds} - Y10T 428/25: Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles - Y10T 428/256: Heavy metal or aluminum or compound thereof - Y10T 428/258: Alkali metal or alkaline earth metal or compound thereof - Y10T 428/277: Cellulosic substrate - Y10T 428/31895: Paper or wood - Y10T 428/31906: Ester, halide or nitrile of addition polymer - Y10T 428/31935: Ester, halide or nitrile of addition polymer - Y10T 428/31993: Of paper - G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY - C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract An electrographic recording material comprising a conductive paper support coated with an electrically insulating layer comprising an intimate blend of a vinyl ester interpolymer latex and up to 500 parts of an inert finely divided pigment per 100 parts by weight of latex interpolymer. The vinyl ester interpolymer comprises about 3 to about 7 weight percent of carboxylic acid groups supplied by an interpolymerized C.sub.4 -C.sub.10 vinylene monobasic carboxylic acid monomer. ## Claims ### Claim 1 An electrographic recording material comprising a conductive paper support coated on at least one side with an electrically insulating layer comprising a dried intimate blend of an aqueous vinyl ester interpolymer latex and up to 500 parts by weight of a finely divided pigment per 100 parts by weight of interpolymer latex, wherein the aqueous interpolymer latex has a pH in the range of about 6.2 to about 7.5 and consists essentially of an acid modified interpolymer of a C.sub.4 -C.sub.6 vinyl ester and a protective colloid, wherein the acid modified vinyl ester interpolymer comprises from about 3 to about 7 weight percent of carboxylic acid groups supplied by an interpolymerized C.sub.14 -C.sub.10 vinylene monobasic carboxylic acid monomer of the formula RCH.dbd.CHCOOH where R is a hydrocarbyl, hydrocarbyloxy or hydrocarbyloxycarbonyl group and wherein the concentration of protective colloid is in the range of about 0.2 to about 0.8 parts by weight per 100 parts by weight of the interpolymer. ### Claim 2 (depends on 1) The electrographic recording material according to claim 1 wherein the protective colloid is a polyvinyl alcohol comprising from about 10 to about 30 weight percent of unhydrolyzed polyvinyl acetate. ### Claim 3 (depends on 2) The electrographic recording material according to claim 2, wherein the polyvinyl alcohol has a weight average molecular weight of at least about 80,000. ### Claim 4 (depends on 1, 2, 3) The electrographic recording material according to claim 1, 2 or 3 wherein the vinyl ester is vinyl acetate. ### Claim 5 (depends on 4) The electrographic recording material according the claim 4 wherein the vinylene monobasic carboxylic acid monomer is selected from the group consisting of crotonic acid, isocrotonic acid and methyl hydrogen maleate. ### Claim 6 (depends on 5) The electrographic recording material of claim 5 wherein the finely divided pigment is selected from the group consisting of silica, calcined clay, zinc sulfide, titanium dioxide, talcum, barium sulfate, calcium carbonate, lithopone, and diatomaceous earth. ### Claim 7 (depends on 5) The electrographic recording material of claim 5 wherein the coating weight of the insulating layer is in the range of about 2 to about 20 grams per square meter of recording material. ### Claim 8 (depends on 5) The electrographic recording material of claim 5 wherein the aqueous interpolymer latex is the product of agitation of an aqueous bead suspension of the interpolymer partly neutralized to a pH in the range of about 6.2 to about 7.5 with a volatile base, the aqueous bead suspension having been prepared by suspension polymerization of the interpolymer monomers in an aqueous sodium containing the protective colloid at a pH adjusted to the range of about 6.0 to about 6.2 by addition of a volatile base throughout the polymerization. ### Claim 9 (depends on 8) The electrographic recording material of claim 8 wherein the volatile base is selected from the group consisting of ammonia and monobasic amines of boiling point less than 100.degree. C. ### Claim 10 (depends on 8) The electrographic recording material of claim 8 wherein the volatile base is ammonia and the pH of the latex is in the range of about 6.2 to about 7.0. ### Claim 11 (depends on 4) The electrographic recording material according to claim 4 wherein the finely divided pigment is selected from the group consisting of silica, calcined clay, zinc sulfide, titanium dioxide, talcum, barium sulfate, calcium carbonate, lithopone, and diatomaceous earth. ### Claim 12 (depends on 4) The electrographic recording material of claim 4 wherein the coating weight of the insulating layer is in the range of about 2 to about 20 grams per square meter of recording material. ### Claim 13 A method of electrographic recording comprising forming an electrostatic charge pattern on an electrically insulting layer of an electrographic recording medium, developing the charge pattern by application of a toner and fixing the toner by heat or pressure, wherein the electrically insulating layer is formed from an intimate blend of an aqueous vinyl ester interpolymer latex and up to 500 parts by weight of a finely divided pigment per 100 parts by weight of interpolymer latex, wherein the interpolymer latex has a pH in the range of about 6.2 to about 7.5 and consists essentially of an acid modified interpolymer of a C.sub.4 -C.sub.6 vinyl ester and a protective colloid, wherein the acid modified vinyl ester interpolymer comprises from about 3 to about 7 weight percent of carboxylic acid groups supplied by an interpolymerized C.sub.4 -C.sub.10 vinylene monobasic carboxylic acid monomer of the formula RCH.dbd.CHCOOH where R is a hydrocarbyl, hydrocarbyloxy or hydrocarbyloxycarbonyl group and wherein the concentration of protective colloid is in the range of about 0.2 to about 0.8 parts by weight per 100 parts by weight of the interpolymer.