# US 4,397,796 A · Method of manufacturing an anisotropic oxidic permanent magnet

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- Number: US 4,397,796 A
- Document ID: US4397796A
- Status: Granted
- Kind: A
- Application number: 06/264,735
- Filed: 1981-05-18
- Granted: 1983-08-09
- Earliest claimed: 1980-05-23
- Assignees: U.S. Philips Corporation
- Inventors: Frederik K. Lotgering; Petrus H. G. M. Vromans
- Web page: https://patentgrep.com/patent/US4397796A

## CPC

- C04B 35/2633: {containing barium, strontium or calcium}
- C04B 35/2608: {Compositions containing one or more ferrites of the group comprising manganese, zinc, nickel, copper or cobalt and one or more ferrites of the group comprising rare earth metals, alkali metals, alkaline earth metals or lead}
- C04B 35/2683: {Other ferrites containing alkaline earth metals or lead}
- Y10S 264/58: Processes of forming magnets
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

In order to obtain a sintered oxidic permanent magnetic material with improved properties, a mixture is prepared which forms a magnet having a composition defined by the formula MeFe.sub.2.sup.2+ Fe.sub.16.sup.3+ O.sub.27, where Me is one or more of the metals barium or strontium, optionally partly replaced by clacium and/or lead. A prefired product having a ferrous iron content which corresponds to the stoichiometric ferrous content of the product composition is sintered at a temperature between 1160.degree. and 1250.degree. C. in an atmopshere having such an oxygen concentration that substantially no oxygen exchange takes place between the product and the atmosphere.

## Claims

### Claim 1

A method of manufacturing an anisotropic oxidic permanent magnet having a hexagonal crystal structure and uniaxial anisotropy, said method comprising the steps of:
providing one or more first compounds from the group consisting of iron oxide and iron compounds which form iron oxide upon heating;
providing one or more second compounds from the group consisting of barium oxide, strontium oxide, lead oxide, and compounds of barium, strontium, and lead which form the respective oxides upon heating and optionally calcium partially replacing, the barium, strontium, and lead
mixing the first and second compounds in proportions which will form a magnet having a W-ferrite phase having a composition defined by the formula MeFe.sub.2.sup.2+ Fe.sub.16.sup.3+ O.sub.27, where Me is a metal from the second compound;
prefiring the mixture at a prefiring temperature in an oxygen-containing atmosphere having a partial oxygen pressure, the partial oxygen pressure and prefiring temperature being chosen to form the desired ferrite phase, said prefiring producing a prefired product having a W-ferrite phase of said formulation;
grinding the prefired product;
shaping the ground product in the presence of a magnetic field; and
sintering the shaped product at a temperature from 1160.degree. to 1250.degree. C. in a gas atmosphere having an oxygen concentration such that substantially no oxygen exchange occurs between the product and the gas atmosphere;
wherein a quantity of iron of from 0.05 to 0.5% by weight is added to the prefired product and the iron containing prefired product is oxidized prior to sintering at a temperature of at most 1150.degree. C. so that the product to be sintered has a ferrous content corresponding to that of said W-ferrite phase.

### Claim 2 (depends on 1)

A method as claimed in claim 1, characterized in that the product is sintered in an atmosphere having a partial oxygen pressure in the range from 1.times.10.sup.-3 to 1.times.10.sup.-2 atmospheres.

### Claim 3 (depends on 1)

A method as claimed in claim 1, characterized in that the iron is added to the prefired product after the grinding step.

### Claim 4 (depends on 1)

A method as claimed in claim 1, characterized in that the shaped product to be sintered has a ferrous content between 6.6 and 7.6% by weight.