# US 4,397,712 A · Semi-chemical pulping process > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,397,712 A - Document ID: US4397712A - Status: Granted - Kind: A - Application number: 06/303,944 - Filed: 1981-09-21 - Granted: 1983-08-09 - Earliest claimed: 1975-02-20 - Assignees: New Fibers International - Inventors: John Gordy - Web page: https://patentgrep.com/patent/US4397712A ## CPC - C05C 3/00: Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor - D21C 3/003: {with organic compounds (D21C3/20 and D21C3/222 take precedence)} - D21C 3/06: sulfur dioxide; sulfurous acid; bisulfites {sulfites} - D21C 3/22: Other features of pulping processes - D21C 3/26: Multistage processes - D21C 11/06: Treatment of pulp gases; Recovery of the heat content of the gases; {Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds} - C05C: NITROGENOUS FERTILISERS - D21C: PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR ## Abstract A process for producing corrugating medium pulp, fuel, and other products from a wide variety of woody materials is disclosed. In one embodiment a pulping solution is produced by cooking green chips in a water solution of monoethanolamine and subsequently collecting the liquor produced. Pulp is then produced by digesting chips under a vapor dome of the pulping solution, or cooking the chips in the solution and subsequently digesting under a vapor dome. Digested chips are then refined in pulping solution to produce corrugated medium pulp. In another embodiment, fuel may be produced by digesting woody material under a vapor dome with sulfur dioxide and ammonia. The digested chips then yield a lignin containing liquor which has a good fuel value and may be used as a liquid fuel or impregnate for woody material. In another embodiment the pulping solution is used as a hard wood conversion resin. Wood is impregnated and pressed. The pressed wood may have a density of twice the original wood. Monoethanolamine vapor also can convert soft wood to hard wood. When wood is vapor impregnated under a vapor dome it may be pressed to a more dense configuration. In both hard wood embodiments the pressed wood maintains its pressed configuration so that it may be used in construction or as a fuel. ## Claims ### Claim 1 A process for producing corrugated medium pulp comprising: providing a pulping solution containing a lignin extract from green chips in an aqueous solution of a lignin dissolving mild organic base; providing a heated vessel; admitting a predetermined quantity of chips and solution to said vessel; impregnating said chips with said solution; subsequently lowering the level of solution in said vessel below the chips and circulating solution vapor above, below and on all sides of said chips to digest said chips under a vapor dome, under conditions of temperature and pressure effective to initiate a lignin depolymerization reaction in said chips for a predetermined period of time; refining said chips to produce said pulp; and separating the used solution from the pulp. ### Claim 2 (depends on 1) The process of claim 1, wherein after said chips and solution are admitted to said vessel, said vessel is heated, vented and sealed to remove entrained air therefrom. ### Claim 3 (depends on 2) The process of claim 2, wherein the step of impregnating further comprises heating the chips and lignin solution in said vessel to a pressure of about 60-100 psi for about 5 minutes. ### Claim 4 (depends on 1) The process of claim 1, wherein said chips are maintained under said vapor dome at a pressure of about 60-100 psi for at least about 10-15 minutes to initiate the lignin depolymerization reaction. ### Claim 5 (depends on 1) The process of claim 1, wherein the step of refining further comprises refining said chips in said solution; subsequently, separating said solution from said pulp produced; and collecting said solution for reuse. ### Claim 6 (depends on 1) The process of claim 1, wherein the organic base is monoethanolamine. ### Claim 7 (depends on 1) The process of claim 1, wherein said chips are at least one member selected from the group consisting of alder, cottonwood, aspen or oak. ### Claim 8 (depends on 1) The process of claim 1, wherein said chips are 50% aspen and 50% oak. ### Claim 9 A process for producing corrugating medium pulp comprising: providing a pulping solution containing a lignin extract from green chips in an aqueous solution of a lignin dissolving mild organic base; providing a heating vessel; admitting a predetermined quantity of chips and solution to said vessel; heating said solution; subsequently digesting said chips by lowering the level of solution in said vessel below the chips and circulating solution vapor above, below and on all sides of said chips to digest said chips under a vapor dome under conditions of temperature and pressure effective to initiate a lignin depolymerization reaction in said chips for predetermined period of time; refining said chips to produce said pulp; and separating the used solution from the pulp. ### Claim 10 (depends on 9) The process of claim 9, wherein after said chips are admitted to said vessel, said vessel is heated, vented and sealed to remove entrained air therefrom. ### Claim 11 (depends on 10) The process of claim 10, wherein the step of digesting further comprises heating the chips and vapors in said vessel to a pressure of about 60-100 psi for about 15 minutes. ### Claim 12 (depends on 9) The process of claim 9, wherein said chips are maintained under said vapor dome at a pressure of about 60-100 psi for at least about 10-15 minutes to initiate the lignin depolymerization reaction. ### Claim 13 (depends on 9) The process of claim 9, wherein the step of refining further comprises refining said chips in said solution; subsequently, separating said solution from said pulp produced; and collecting said solution for reuse. ### Claim 14 (depends on 9) The process of claim 9, wherein the organic base is monoethanolamine.