# US 4,397,653 A · Method of producing a colloidal fuel from coal and a heavy petroleum fraction

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- Number: US 4,397,653 A
- Document ID: US4397653A
- Status: Granted
- Kind: A
- Application number: 06/321,346
- Filed: 1981-11-13
- Granted: 1983-08-09
- Earliest claimed: 1981-11-13
- Inventors: James R. Longanbach
- Web page: https://patentgrep.com/patent/US4397653A

## CPC

- C10L 1/322: {Coal-oil suspensions}
- C10L: FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS

## Abstract

A method is provided for combining coal as a colloidal suspension within a heavy petroleum fraction. The coal is broken to a medium particle size and is formed into a slurry with a heavy petroleum fraction such as a decanted oil having a boiling point of about 300.degree.-550.degree. C. The slurry is heated to a temperature of 400.degree.-500.degree. C. for a limited time of only about 1-5 minutes before cooling to a temperature of less than 300.degree. C. During this limited contact time at elevated temperature the slurry can be contacted with hydrogen gas to promote conversion. The liquid phase containing dispersed coal solids is filtered from the residual solids and recovered for use as a fuel or feed stock for other processes. The residual solids containing some carbonaceous material are further processed to provide hydrogen gas and heat for use as required in this process.

## Claims

### Claim 1

A method of producing a liquid fuel or feed stock containing colloidal coal particles suspended in a petroleum fraction comprising:
comminuting coal to particles;
contacting said comminuted coal with a petroleum fraction having an atmospheric boiling point range of 300.degree.-800.degree. C. to form a slurry;
heating said slurry to a temperature of 400.degree.-500.degree. C. at a pressure of about 10-200 atmospheres and maintaining said slurry at this temperature for no more than 1 to 5 minutes;
cooling said slurry to a temperature of less than 300.degree. C. after only 1 to 5 minutes contact time at 400.degree.-500.degree. C.;
filtering the liquid phase from the residual solids of said slurry;
processing said residual solids to provide hydrogen gas and heat;
recovering said liquid phase with suspended coal particles for use.

### Claim 2 (depends on 1)

The method of claim 1 wherein said comminuted coal is contacted with said petroleum fraction and with hydrogen gas at a temperature of 400.degree.-500.degree. C. for a period of no more than about 1 to 5 minutes prior to filtering the liquid phase from the residual solids.

### Claim 3 (depends on 1)

The method of claim 1 wherein said petroleum fraction is a decanted oil having a boiling point of about 300.degree. to 550.degree. C.

### Claim 4 (depends on 1)

The method of claim 1 wherein said liquid phase filtered from said residual solids contains 40-80 weight percent MAF of the comminuted coal solids suspended as colloidal particles or as liquefied coal material.

### Claim 5 (depends on 1)

The method of claim 1 wherein said residual solids are gasified and combusted to provide hydrogen gas and heat for said contacting step.

### Claim 6 (depends on 1)

The method of claim 1 wherein said contact time at said 400.degree.-500.degree. C. in the presence of hydrogen gas is limited to only about 2 minutes prior to cooling to less than 300.degree. C.

### Claim 7 (depends on 1)

The method of claim 1 wherein said slurry is cooled to a temperature of 200.degree.-300.degree. C. prior to said filtration step.