# US 4,396,739 A · Easy-clean vinyl acetate adhesive composition

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- Number: US 4,396,739 A
- Document ID: US4396739A
- Status: Granted
- Kind: A
- Application number: 06/336,752
- Filed: 1982-01-04
- Granted: 1983-08-02
- Earliest claimed: 1980-10-06
- Assignees: National Starch and Chemical Corporation
- Inventors: Julius Sirota; Vincent A. Lauria
- Web page: https://patentgrep.com/patent/US4396739A

## CPC

- C09J 131/04: Homopolymers or copolymers of vinyl acetate
- C08L 2666/54: Inorganic substances
- C09J: ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES (preparation of glue or gelatine C09H)
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)

## Abstract

Improved "easy-clean" vinyl acetate homo- and copolymer-based emulsion adhesives are provided by the addition thereto of specific water soluble, ionic salts. Those particular vinyl acetate based adhesives which are formulated for use in remoistening applications are further improved with respect to their "lay-flat" performance.

## Claims

### Claim 1

An aqueous adhesive composition, characterized by "easy-clean" properties consisting essentially of per 100 parts by weight total composition:
(a) 50-99.5 parts of an aqueous vinyl acetate homo- or copolymer emulsion;
(b) 0.5 to 15 parts of a salt selected from the group consisting of calcium chloride, calcium nitrate, magnesium chloride, magnesium nitrate, aluminum chloride, aluminum nitrate, ammonium chloride, ammonium acetate, potassium acetate and blends thereof;
(c) 0 to 35 parts humectant;
(d) 0 to 35 parts plasticizer;
(e) 0 to 35 parts solvent;
(f) 0 to 20 parts water soluble protective colloid; wherein the total of components c, d, e and f comprises 0-49.5 parts by weight per 100 parts of the total formulation; and wherein the adhesive contains no carboxyl or related functional groups nor any externally added cross-linking components which can react with the salt.

### Claim 2 (depends on 1)

The adhesive composition of claim 1 wherein the emulsion of part (a) is a vinyl acetate homopolymer emulsion.

### Claim 3 (depends on 1)

The adhesive composition of claim 1 wherein the emulsion of part (a) is a vinyl acetate - ethylene copolymer emulsion.

### Claim 4 (depends on 1)

The adhesive composition of claim 1 wherein the salt of part (b) is calcium chloride or magnesium chloride.

### Claim 5

An easy-clean aqueous adhesive composition consisting essentially of per 100 parts by weight of the total composition:
(a) 50-89.5 parts of an aqueous vinyl acetate copolymer emulsion,
(b) 0.5-15 parts of a salt selected from the group consisting of calcium chloride, calcium nitrate, magnesium chloride, magnesium nitrate, aluminum chloride, aluminum nitrate, ammonium chloride, ammonium acetate, potassium acetate and blends thereof;
(c) 5-20 parts plasticizer;
(d) 5-35 parts humectant;
(e) 0-10 parts solvent; and
(f) 0-10 parts water soluble polymer or thickener; and wherein the adhesive contains no carboxyl or related functional groups nor any externally added cross-linking components which can react with the salt.

### Claim 6

A remoistenable adhesive composition characterized by improved "lay-flat" properties consisting essentially of per 100 parts by weight of the total composition:
(a) 50-89.5 parts of an aqueous vinyl acetate homo- or copolymer emulsion;
(b) 0.5-15 parts of a salt selected from the group consisting of calcium chloride, calcium nitrate, magnesium chloride, magnesium nitrate, aluminum chloride, aluminum nitrate, ammonium chloride, ammonium acetate, potassium acetate and blends thereof;
(c) 5-15 parts partially hydrolyzed polyvinyl alcohol;
(d) 5-30 parts humectant, and
(e) 0-5 parts plasticizer; and wherein the adhesive contains no carboxyl or related functional groups nor any externally added cross-linking components which can react with the salt.

### Claim 7

A method for imparting "easy-clean" properties to an aqueous vinyl acetate based emulsion adhesive containing no carboxyl or related functional groups nor any externally added cross-linking components characterized by the step of adding to each 100 parts of the total adhesive base 0.5 to 15 parts of a salt selected from the group consisting of calcium chloride, calcium nitrate, magnesium chloride, magnesium nitrate, aluminum chloride, aluminum nitrate, ammonium chloride, ammonium acetate, potassium acetate and blends thereof.