Photographic recording material with metal complexable, heterocyclic azo dye
AssigneeAfga-Gevaert Aktiengesellschaft
InventorsPeter Bergthaller, Gunther Schenk, Gerhard Wolfrum, Hans-Volker Runzheimer
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AssigneeAfga-Gevaert Aktiengesellschaft
InventorsPeter Bergthaller, Gunther Schenk, Gerhard Wolfrum, Hans-Volker Runzheimer
Estimating the term…
Cyan images may be prepared by the dye diffusion transfer process, using dye-releasers which on development release diffusible dyes capable of forming light-fast cyan metal-dye-complexes particularly with copper or nickel ions. As also the dye-releasers are capable of complexation, cyan images can be prepared not only from the released dyes but also from the dye-releasers ("retained image"). Released dyes and dye-releasers of the present invention contain a chromophor of the following formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which may be the same or different, each represents --H, --F, --Cl, --Br, --CN, --NO.sub.2, --CF.sub.3, --OCF.sub.3, --SCF.sub.3, alkyl, alkoxy, alkylthio, acylamino, alkylsulfonyl, arylsulfonyl, --CO--X or --SO.sub.2 --Y or two adjacent groups R.sup.1 -R.sup.4 together constitute a condensed benzene ring which may contain further substituents; R.sup.5 represents hydrogen or a substituent having an electron donor character; R.sup.6 represents hydrogen, halogen or alkyl; G represents a group capable of chelate formation; X represents --OH, alkoxy, an amino group optionally substituted by alkyl or aryl, or a cyclic amino group; Y represents --H, --OH, an amino group optionally substituted by alkyl or aryl, a cyclic amino group or a group corresponding to the following general formula: --NH--So.sub.2 --R.sup.7 ; R.sup.7 represents alkyl, aryl, an amino group optionally disubstituted by alkyl or a cyclic amino group; and n represents 0 or 1.
A color photographic recording material for the production of color images by the dye diffusion transfer process, containing at least one light-sensitive silver halide emulsion layer and a non-diffusing color-providing compound associated thereto, from which color-providing compound a diffusible azo dye capable of forming a complex with metal ions is released under the conditions of alkaline development as a function of the development of the silver halide emulsion layer, wherein the improvement comprises the azo dye corresponds to the following general formula II:
Dependencies are inferred from the claim text.