# US 4,396,700 A · Process for forming an image > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,396,700 A - Document ID: US4396700A - Status: Granted - Kind: A - Application number: 06/331,742 - Filed: 1981-12-17 - Granted: 1983-08-02 - Earliest claimed: 1977-12-06 - Assignees: Fuji Photo Film Co., Ltd. - Inventors: Masao Kitajima; Hiromichi Tachikawa; Fumiaki Shinozaki; Tomoaki Ikeda - Web page: https://patentgrep.com/patent/US4396700A ## CPC - G03F 7/346: {using photosensitive materials other than non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds} - G03F: PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR; (phototypographic composing devices B41B; photosensitive materials or processes for photographic purposes G03C; electrophotography, sensitive layers or processes therefor G03G) ## Abstract A process for forming an image is disclosed wherein a photosensitive image-forming material comprising a diazonium compound or an azide compound is exposed and developed by a peeling development method wherein a development carrier sheet having thereon a layer of an adhesive composition is adhered to the image-forming material, before or after exposure, and, after exposure, peeled from the image-forming material whereby the exposed areas of the photosensitive layer are adhered to the carrier sheet thereby forming a relief image, and the unexposed areas remaining adhered to the support also forming a relief image. ## Claims ### Claim 1 A process for forming an image, which comprises imagewise exposing a photosensitive image-forming material consisting of a non-transparent support or support colored with dyes or pigments, said support having formed thereon a layer of a photosensitive composition, said photosensitive composition layer being in intimate contact with an original image transparency during said imagewise exposing and said composition containing a diazonium compound or an aromatic azide compound and a binder which imparts heat-softenability to the photosensitive composition layer wherein said layer is a solid layer not tacky at temperature ranges between about 5.degree. C. to 40.degree. C. and then adhering the photosensitive composition layer closely to a development carrier sheet having thereon a layer of adhesive composition comprising a polymeric material and a tackifier; and peeling said image-forming material and said carrier sheet from each other at a temperature which is lower than the softening temperature of the photosensitive composition layer and lower than the softening temperature of the layer of adhesive on said carrier sheet to imagewise separate said photosensitive composition layer and to transfer and adhere the entire exposed area of the photosensitive layer to the carrier sheet and thereby form a relief image on the carrier sheet, and the non-transferred unexposed area of the photosensitive composition remains on the support also forming a relief image simultaneously with the relief image on the carrier sheet. ### Claim 2 A process for forming an image, which comprises imagewise exposing a photosensitive image-forming material composed of a non-transparent support or support colored with dyes or pigments, said support having formed thereon as the uppermost layer a layer of a photosensitive composition, said photosensitive composition layer being in intimate contact with an original image transparency during said imagewise exposing and said composition containing a diazonium compound or an aromatic azide compound and a binder which imparts heat-softenability to the photosensitive composition layer wherein said layer is a solid layer not tacky at temperature ranges between about 5.degree. C. to 40.degree. C. and then adhering the photosensitive composition layer closely to a development carrier sheet having thereon a layer of an adhesive composition comprising a polymeric material and a tackifier and peeling said image-forming material and said carrier sheet from each other at a temperature which is lower than the softening temperature of the photosensitive composition layer and lower than the softening temperature of the layer of adhesive on said carrier sheet to imagewise separate said photosensitive composition layer and to transfer and adhere the entire exposed area of the photosensitive layer to the carrier sheet and thereby form a relief image on the carrier sheet, and the non-transferred unexposed area of the photosensitive composition remains on the support also forming a relief image simultaneously with the relief image on the carrier sheet. ### Claim 3 (depends on 1, 2) The process of claim 1 or claim 2 wherein said photosensitive composition layer is adhered to said development carrier sheet at a temperature from ordinary temperature up to 150.degree. C. ### Claim 4 (depends on 1, 2) The process of claim 1 or claim 2, wherein said photosensitive image-forming material is exposed prior to application of said carrier sheet with the photosensitive composition layer of said image-forming material being in intimate contact with the original image transparency. ### Claim 5 (depends on 1, 2) The process of claim 1 or claim 2, wherein said diazonium compound is rendered less hydrophilic. ### Claim 6 (depends on 1, 2) The process of claim 1 or claim 2, wherein said diazonium compound is represented by the formula ArN.dbd.N.sup.+ X.sup.- wherein Ar represents an aromatic ring substituted at the 4-position with an alkylamino group, a phenylamino group, an N-heterocyclic group, or a mercapto group and X is an anion. ### Claim 7 (depends on 1, 2) The process of claim 1 or claim 2, wherein said azide compound is represented by the formula N.sub.3 --R.sub.5 --CH.dbd.CH--R.sub.6 wherein R.sub.5 is phenylene and R.sub.6 is an acyl group or an azide aryl group. ### Claim 8 (depends on 1, 2) The process of claim 1 or claim 2, wherein said adhesive composition contains a rubber, a cellulosic polymeric material or a vinyl polymer. ### Claim 9 (depends on 1, 2) The process of claim 1 or claim 2, wherein said peeling development is carried out at room temperature to 100.degree. C. ### Claim 10 (depends on 1, 2) The process of claim 1 or claim 2, wherein said layer of said photosensitive composition is from 0.5 .mu.m to 500 .mu.m thick. ### Claim 11 (depends on 1, 2) The process the claim 1 or claim 2, wherein said peeling temperature is from room temperature to about 60.degree. C. ### Claim 12 (depends on 1, 2) The process of claim 1 or claim 2, wherein said diazonium compound is selected from the group consisting of 4-morpholino-benzene diazonium/boron tetrafluoride double salt, the condensation product of 4-N-phenylamino-benzenediazonium and formaldehyde, 4-N,N-dimethylaminobenzenediazonium/tetraphenylboron double salt, 2,6-di(4'-azidobenzal)-4-methylcyclohexane, 1-diazo-2,5-di-methoxy-1-p-tolylmercaptobenzene phosphorous hexafluoride double salt, 2-diazo-1-naphthol-5-sulfonic acid ethyl ether, and 4-morpholino-2,5-dibutoxybenzene diazonium/boron tetrafluoride double salt; and wherein said binder is selected from the group consisting of vinylidene chloride/acrylonitrile copolymer, m-cresol-type novolak resin, and polyvinyl butyral; and wherein said support is selected from the group consisting of grained and anodized aluminum, polyethylene terephthalate having aluminum vacuum-deposited thereon in a thickness of about 1,000 A, polyethylene terephthalate having a subbing layer of gelatin, aluminum having a 1.mu. thick layer of polyvinyl alcohol, aluminum which has been grained, anodized and treated with sodium silicate. ### Claim 13 (depends on 1, 2) The process of claim 1 or claim 2, wherein said diazonium compound has an oleophilic moiety. ### Claim 14 (depends on 13) The process of claim 13, wherein said oleophilic moiety is alkoxy substituted on an aromatic ring of said diazonium compound. ### Claim 15 (depends on 13) The process of claim 13, wherein said oleophilic moiety is an anion of said diazonium compound selected from the group consisting of tetraphenylborate, tetrafluoroborate, hexafluorophosphate, hexafluoroarsenate, p-toluenesulfonic acid and hexafluoroantimonate.