# US 4,396,669 A · Composite carbonaceous articles and process for making same

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- Number: US 4,396,669 A
- Document ID: US4396669A
- Status: Granted
- Kind: A
- Application number: 06/180,170
- Filed: 1980-08-22
- Granted: 1983-08-02
- Earliest claimed: 1980-08-22
- Assignees: Carbone USA Corporation
- Inventors: Yvon P. Cariou
- Web page: https://patentgrep.com/patent/US4396669A

## CPC

- C04B 35/83: Carbon fibres in a carbon matrix
- C04B 35/524: obtained from polymer precursors, e.g. glass-like carbon material
- H01M 4/96: Carbon-based electrodes
- H01M 8/0213: Gas-impermeable carbon-containing materials
- Y02E 60/50: Fuel cells
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- Y10T 428/30: Self-sustaining carbon mass or layer with impregnant or other layer
- Y10T 442/59: At least three layers
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

Disclosed is a composite carbonaceous article formed of carbon felt fabric intimately linked to vitreous carbon. A carbonizable high carbon resin is cast or centrifuged onto a carbon or precursor felt fabric to form shapes which can then be baked to carbonizing or graphitizing temperatures.

## Claims

### Claim 1

A composite multi-layered carbonaceous article comprising:
a felted fabric member having at least two surfaces and being composed of carbon fibers, a layer of vitreous carbon being bonded to at least one of said surfaces to be completely located only at that surface to form two distinct layers which are bonded together;
said vitreous carbon having been produced by polymerizing on said fabric a carbonizable, polymerizable resin having a carbon content in the range of 40 to 90 percent,
said layer having a closed microporosity and being gas impervious;
only some of said carbon fibers penetrating into said layer of vitreous carbon.

### Claim 2 (depends on 1)

The article of claim 1, wherein alternate layers of fabric members and layers of vitreous carbon are integrally united to form a sandwich-like structure.

### Claim 3 (depends on 1)

The article of claim 1, wherein said carbon fibers have a diameter of about four to eight microns.

### Claim 4 (depends on 1)

The article of claim 1, wherein said vitreous carbon has a thermal conductivity ranging from 0.01 to 0.02 cal/cm/s/C and a transverse breaking strength of 600 to 1000 kg/cm.sup.2, and said fibers have a carbon content in the range of 94 to 100%.

### Claim 5 (depends on 1)

The article of claim 1, wherein said vitreous carbon and said fibers are graphitized.

### Claim 6

A process for making a shaped composite multi-layered carbonaceous article comprising providing a felted fabric composed of carbon fibers, said fabric having at least two surfaces, bonding a carbonizable, polymerizable resin having a carbon content in the range of 40 to 90% and a polymerization catalyst to at least one of said surfaces under ambient temperature and pressure by polymerizing said resin to carbonizing or graphitizing temperatures so that said carbon is completely located only at the one surface to form two distinct layers which are bonded together.

### Claim 7 (depends on 6)

The process of claim 6, wherein said resin is a furfural-based resin, a phenolic resin or a polyimide resin.

### Claim 8 (depends on 6)

The process of claim 6, wherein the amount of resin applied to said fabric ranges from 0.1 to 2.0 gram per cm.sup.2 of fabric.

### Claim 9 (depends on 6)

The process of claim 6, wherein a thickness of resin of 2/10 to 2.5 mm is used and the temperature is increased at a rate of 3.degree. to 5.degree. C./hr.

### Claim 10 (depends on 6)

The process of claim 6, wherein the thickness of resin used is over 2.5 mm and the rate of heating is increased by about 1.degree. C./hr.

### Claim 11 (depends on 6)

The process of claim 6, conducted by stacking a plurality of composite articles in a furnace, separating said articles by rigid, flat, separating means and heating to the desired temperature.

### Claim 12 (depends on 6)

The process of claim 6, wherein contacting of said resin is effected by casting said resin on a substantially flat, rigid surface and placing said fabric thereon.

### Claim 13 (depends on 6)

The process of claim 6, wherein contacting is conducted by centrifuging a roll of said fabric with said resin, heating to the polymerization temperature of said resin, unrolling the thus treated roll and baking same.

### Claim 14 (depends on 6)

The process of claim 6, wherein said fabric is precarbonized prior to being applied to said resin.