# US 4,396,646 A · Method of making patterned polarizers

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- Number: US 4,396,646 A
- Document ID: US4396646A
- Status: Granted
- Kind: A
- Application number: 06/285,273
- Filed: 1981-07-20
- Granted: 1983-08-02
- Earliest claimed: 1981-07-20
- Assignees: Polaroid Corporation
- Inventors: Norman W. Schuler; Gary T. Scupp
- Web page: https://patentgrep.com/patent/US4396646A

## CPC

- G02B 5/3033: {in the form of a thin sheet or foil, e.g. Polaroid}
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS

## Abstract

A method of making patterned polarizer elements having areas exhibiting different optical properties comprising removing the dichroic dye from selected areas of a linear, dichroic, light polarizer and restaining these selected areas with a different dichroic dye.

## Claims

### Claim 1

A method for making linear, dichroic polarizers having areas with different optical properties comprising:
uniaxially stretching a film of polymeric material;
staining the stretched film with a first dichroic dye solution;
selectively masking the stained polymeric film;
bleaching the masked polymeric film to remove the first dichroic dye from the unmasked areas thereof;
applying a second dichroic dye solution to the bleached areas of said polymeric film to restain said areas;
removing the mask from the stained polymeric film; and
treating the stained film with a borating solution.

### Claim 2 (depends on 1)

The method of claim 1 wherein said polymeric material is a hydroxyl-containing vinyl polymer.

### Claim 3 (depends on 2)

The method of claim 2 wherein said polymeric material is polyvinyl alcohol.

### Claim 4 (depends on 3)

The method of claim 3 wherein the stained polyvinyl alcohol film is selectively masked with a polyester adhesive tape.

### Claim 5 (depends on 3)

The method of claim 3 wherein the first dichroic dye solution comprises an iodine solution.

### Claim 6 (depends on 5)

The method of claim 5 wherein a caustic solution is used to bleach the iodine stain from the polyvinyl alcohol film.

### Claim 7 (depends on 6)

The method of claim 6 wherein said caustic solution is an aqueous solution containing about 1 to about 50 percent by weight sodium hydroxide applied at a temperature from about 25.degree. C. to about 70.degree. C. with a contact time of about 1 to about 30 seconds.

### Claim 8 (depends on 7)

The method of claim 7 wherein said caustic solution comprises about 20 percent by weight sodium hydroxide applied at a temperature of about 40.degree. C. with a contact time of about 10 second.

### Claim 9 (depends on 3)

The method of claim 3 wherein said second dichroic dye is applied in an aqueous solution containing about 1 to about 10 percent by weight of the dye at a temperature ranging from about 25.degree. C. to about 70.degree. C. with a contact time from about about 5 to about 30 seconds.

### Claim 10 (depends on 3)

The method of claim 3 including pretreating the uniaxially stretched polyvinyl alcohol film, prior to staining with the first dichroic dye, with an aqueous solution of sodium hydroxide and methanol in order to enhance the dye-receptivity of the polyvinyl alcohol film.

### Claim 11 (depends on 10)

The method of claim 10 wherein the pretreatment solution comprises about 5 to about 25 percent by weight sodium hydroxide and about 10 to about 50 percent by weight methanol.

### Claim 12 (depends on 11)

The method of claim 11 wherein said pretreatment solution comprises an aqueous solution containing about 16 percent sodium hydroxide and about 28 percent methanol and is applied at a temperature of about 51.degree. C. with a contact time of about 15 seconds.

### Claim 13 (depends on 3)

The method of claim 3 wherein said film of polyvinyl alcohol comprises a mordant-containing polyvinyl alcohol material.

### Claim 14 (depends on 3)

The method of claim 3 comprising:
uniaxially stretching a film of polyvinyl alcohol;
treating the stretched film with an aqueous solution containing about 16 percent by weight sodium hydroxide and about 20 percent sodium hydroxide at a temperature of about 51.degree. C. with a contact time of about 15 second;
staining the pretreated polyvinyl alcohol film with an iodine solution;
selectively masking the stained polyvinyl alcohol film with a polyester adhesive material;
bleaching the masked film with an aqueous solution containing about 20 percent by weight sodium hydroxide at a temperature of about 40.degree. C. with a contact time of about 10 seconds;
applying a second staining solution to the bleached areas of the polyvinyl alcohol film;
removing the polyester mask from the stained film;
treating the unmasked film with a borating solution.