# US 4,396,495 A · Reduction of foaming in a slurry catalyst hydrocarbon conversion process

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- Number: US 4,396,495 A
- Document ID: US4396495A
- Status: Granted
- Kind: A
- Application number: 06/342,523
- Filed: 1982-01-25
- Granted: 1983-08-02
- Earliest claimed: 1982-01-25
- Assignees: Uop LLC
- Inventors: Richard Braun; Russell W. Johnson
- Web page: https://patentgrep.com/patent/US4396495A

## CPC

- C10G 49/00: Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- B01J 8/22: gas being introduced into the liquid
- B01J 2219/0025: Foam formation
- C10G 2300/107: Atmospheric residues having a boiling point of at least about 538 °C
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

## Abstract

A catalytic slurry process for effecting the conversion of a hydrocarbonaceous black oil charge stock is disclosed and which process possesses improved efficiency by the addition of antifoamant.

## Claims

### Claim 1

In a process for the conversion of a hydrocarbonaceous black oil comprising asphaltenes and indigenous trace metals wherein a slurry of said black oil and a finely divided, unsupported metal catalyst is subjected to hydrocarbon conversion conditions in the presence of hydrogen in a hydrocarbon conversion zone, thereby causing the formation within said conversion zone of foam which impairs the efficiency of the conversion process, the method of reducing or eliminating said foam formation in the conversion zone which comprises introducing to said zone containing the black oil-catalyst slurry-from about 0.001 to about 1 weight percent, based on the weight of said black oil, of a silicone antifoaming agent to mitigate foaming in the conversion zone.

### Claim 2 (depends on 1)

The process of claim 1 wherein said indigenous trace metal comprises nickel, vanadium, iron or a mixture thereof.

### Claim 3 (depends on 1)

The process of claim 1 wherein said finely divided, unsupported metal catalyst comprises vanadium, molybdenum, nickel or compounds thereof.

### Claim 4 (depends on 1)

The process of claim 1 wherein hydrocarbon conversion conditions include a pressure from about 1000 psig to about 3000 psig, a temperature from about 500.degree. F. to about 950.degree. F., a liquid hourly space velocity from about 0.05 to about 10, a hydrogen circulation rate from about 3,000 to about 30,000 SCFB, and a catalyst concentration from about 0.01 to about 10 weight percent based on the weight of the elemental metal and fresh feedstock.

### Claim 5 (depends on 1)

The process of claim 1 wherein said finely divided, unsupported metal catalyst has a nominal diameter or particle size from about 0.1 micron to about 100 microns.

### Claim 6 (depends on 1)

The process of claim 1 wherein said hydrocarbonaceous black oil comprises atmospheric tower bottoms, vacuum column bottoms, crude oil residuals, coal oil extracts, tar sand oil, shale oil, or deasphalter pitch.