# US 4,396,486 A · Ion selective electrode element

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- Number: US 4,396,486 A
- Document ID: US4396486A
- Status: Granted
- Kind: A
- Application number: 06/410,699
- Filed: 1982-08-23
- Granted: 1983-08-02
- Earliest claimed: 1982-08-23
- Assignees: Graphic Controls Corporation
- Inventors: Norbert J. Mruk; Robert A. Falls
- Web page: https://patentgrep.com/patent/US4396486A

## CPC

- G01N 27/333: Ion-selective electrodes or membranes (glass electrodes G01N27/36)
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

An ion selective potentiometric electrode component consisting essentially of a solid, plate-like interface element prepared by simultaneously co-precipitating Ag.sub.2 S, Ag.sub.2 Se, CdS and CdSe followed by compressing the precipitated material at an elevated temperature to provide a substantially impervious agglomerate having an X-ray diffraction pattern distinct from a composite pattern of the individual four components and characterized by improved response properties and enhanced sensitivity to cadmium ion concentration in solution.

## Claims

### Claim 1

A solid membrane for use as a component of an ion-selective potentiometric electrode,
said membrane being sensitive to selective ions to facilitate a determination of the concentration thereof in solution,
said membrane comprising pressed and intimately bonded particles derived from four-component co-precipitate of Ag.sub.2 S, Ag.sub.2 Se, CdS and CdSe, and
said membrane being characterized in having a crystalline structure distinct from that derived from intermixing the individual compounds Ag.sub.2 S, Ag.sub.2 Se, CdS and CdSe and also distinct from that derived from intermixing a co-precipitate of Ag.sub.2 S and Ag.sub.2 Se with a co-precipitate of CdS and CdSe.

### Claim 2 (depends on 1)

The composition as set forth in claim 1 wherein said four-component co-precipitate includes four components present in essentially equal molar concentrations.

### Claim 3 (depends on 1)

The composition as set forth in claim 1 wherein said four-component co-precipitate comprises a unitary pellet-like aggregate of particles compressed at a pressure of about 100,000 psi and at a temperature of about 350.degree. F.

### Claim 4 (depends on 1)

The structure as set forth in claim 1 wherein an ion selective electrode incorporating said membrane exhibits an essentially logarithmically linear proportional voltage response curve over at least an eight-fold cadmium ion concentrational range including over a range of from about 0.1 molar to about 10.sup.-8 molar.

### Claim 5 (depends on 1)

The structure as set forth in claim 1 wherein disposition of said membrane as an interface medium between a reference solution containing a fixed concentration of Cd.sup.++ ion and exhibiting a fixed constant potential and a sample solution containing Cd.sup.++ ion in solution and in a concentrational range of from about 0.1 molar to about 10.sup.-8 molar will effect production of a potential in the range of about 200 mv.

### Claim 6

The method of producing an interface element for use in an ion-selective potentiometric electrode, said method comprising the steps of:
dissolving silver nitrate and cadmium nitrate in water in a ratio to provide a first solution containing two moles of silver ion for each mole of cadmium ion,
dissolving sodium sulfide, and sodium selenide in water to provide a second solution having equimolar concentrations of sulfide ion and selenide ion, the molar concentrations of sulfide ion and of selenide ion being equal to the molar concentration of cadmium ion present in said first solution,
blending said first solution and said second solution to produce an equi-molar co-precipitate of Ag.sub.2 S, Ag.sub.2 Se, CdS and CdSe,
isolating said co-precipitate, and subjecting said co-precipitate to heat and to compression to form a unitary pellet-like element characterized by improved response properties and to cadmium ion concentration in solution.