# US 4,396,472 A · Novel apparatus and process for the TiCl.sub.4 feed to electrolysis cells for the preparation of titanium

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- Number: US 4,396,472 A
- Document ID: US4396472A
- Status: Granted
- Kind: A
- Application number: 06/313,230
- Filed: 1981-10-20
- Granted: 1983-08-02
- Earliest claimed: 1980-11-27
- Assignees: Pechine Ugine Kuhlmann
- Inventors: Marcel Armand
- Web page: https://patentgrep.com/patent/US4396472A

## CPC

- C25C 7/06: Operating or servicing
- C25C 3/28: of titanium
- C25C: PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR

## Abstract

The apparatus and the process according to the invention concern the preparation of titanium by electrolysis in a bath of molten halides. The apparatus comprises a porous diaphragm which is disposed around a feed cathode permitting partial reduction of the TiCl.sub.4 introduced into the electrolyte. The intensity of the current which passes through the feed cathode is so regulated as to maintain a low but non-zero voltage drop, across the diaphragm which is insulated with respect to the feed cathode.

## Claims

### Claim 1

An apparatus for the introduction of TiCl.sub.4 into an electrolyte of an electrolytic cell for the preparation of titanium comprising at least one feed cathode including
(a) means for introducing TiCl.sub.4 into said electrolyte,
(b) two metal rods extending into said electrolyte and connected to a negative current source, and
(c) a metal diaphragm surrounding said feed means and said rods and electrically insulated therefrom.

### Claim 2 (depends on 1)

An apparatus according to claim 1 having reference electrodes disposed on respective sides of said diaphragm and means for measuring the potential difference of said reference electrodes.

### Claim 3

A process for the introduction of TiCl.sub.4 into an electrolyte of an electrolytic cell comprising:
(a) providing in an electrolyte cell at least one feed cathode having a metal diaphragm surrounding said feed cathode;
(b) electrically insulating said metal diaphragm from said feed cathode, and
(c) establishing a current flow through said feed cathode such that the intensity of said current passing through said feed cathode is regulated so as to maintain a low but non-zero voltage drop in the electrolyte which impregnates said diaphragm.

### Claim 4 (depends on 3)

A process according to claim 3 wherein the intensity of the current which passes through the TiCl.sub.4 feed cathode is controlled in dependence on the voltage drop in the electrolyte impregnating the diaphragm or a variable linked to said voltage drop.

### Claim 5 (depends on 4)

A process according to claim 4 wherein the intensity of the current which passes through the feed cathode is controlled in dependence on the potential difference as measured between reference electrodes disposed on respective sides of said diaphragm.