# US 4,396,470 A · Lithographic printing plates

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- Number: US 4,396,470 A
- Document ID: US4396470A
- Status: Granted
- Kind: A
- Application number: 06/349,194
- Filed: 1982-02-17
- Granted: 1983-08-02
- Earliest claimed: 1982-02-17
- Assignees: Vickers, Incorporated
- Inventors: Philip A. Atkinson
- Web page: https://patentgrep.com/patent/US4396470A

## CPC

- C25D 11/12: Anodising more than once, e.g. in different baths
- B41N 3/03: Chemical or electrical pretreatment
- B41N 3/034: {characterised by the electrochemical treatment of the aluminum support, e.g. anodisation, electro-graining; Sealing of the anodised layer; Treatment of the anodic layer with inorganic compounds; Colouring of the anodic layer}
- C25D 11/08: containing inorganic acids
- C25D: PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- B41N: PRINTING PLATES OR FOILS (photosensitive material G03); MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM

## Abstract

Aluminium sheets for lithographic printing plate production are anodized firstly in a phosphoric acid electrolyte and secondly in an electrolyte containing a major amount of phosphoric acid and a minor amount of sulphuric acid.

## Claims

### Claim 1

A method of treating aluminium or an alloy thereof for use as a substrate in lithographic printing plate production which comprises firstly anodising it in phosphoric acid electrolyte and secondly anodising it in an electrolyte comprising a mixture containing a major amount of phosphoric acid and a minor amount of sulphuric acid.

### Claim 2 (depends on 1)

A method according to claim 1 wherein the first anodising is carried out for from 0.25 to 4.0 minutes, at a voltage of from 15 to 35 V, at a temperature of from 15.degree. to 46.degree. C., and using an electrolyte containing from 250 to 400 g/l phosphoric acid.

### Claim 3 (depends on 2)

A method according to claim 2 wherein the electrolyte used in the first anodising contains from 328 to 380 g/l phosphoric acid.

### Claim 4 (depends on 1)

A method according to claim 1 wherein the second anodising is carried out for from 0.25 to 4.0 minutes, at a temperature from 15.degree. to 46.degree. C., and using an electrolyte containing from 20 to 150 g/l sulphuric acid and from 250 to 380 g/l phosphoric acid.

### Claim 5 (depends on 4)

A method according to claim 4 wherein the electrolyte used in the second anodising contains at least 40 g/l sulphuric acid.

### Claim 6 (depends on 1)

A method according to claim 1 wherein the voltage used in the second anodising is equal to or greater than the voltage used in the first anodising.

### Claim 7

A method of manufacturing a radiation sensitive plate for lithographic printing plate production which comprises
(i) anodising aluminium or aluminium alloy using an electrolyte consisting essentially of aqueous phosphoric acid solution,
(ii) anodising the aluminium or aluminium alloy using an electrolyte consisting essentially of a major amount of phosphoric acid, a minor amount of sulphuric acid, and water, and
(iii) coating the anodised aluminium or aluminium alloy with a radiation sensitive composition to obtain the desired radiation sensitive plate.