# US 4,396,469 A · Process and apparatus for continuously coating a solid electrolyte with a catalytically active metal

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- Number: US 4,396,469 A
- Document ID: US4396469A
- Status: Granted
- Kind: A
- Application number: 06/302,986
- Filed: 1981-09-17
- Granted: 1983-08-02
- Earliest claimed: 1980-09-19
- Assignees: BBC Brown, Boveri & Company, Limited
- Inventors: Robert Banziger; Hans-Jorg Christen; Samuel Stucki
- Web page: https://patentgrep.com/patent/US4396469A

## CPC

- C25D 7/0614: {Strips or foils}
- C25D 5/56: of plastics
- C25D: PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR

## Abstract

A process and apparatus for continuously coating a solid electrolyte with a catalytically active metal, whereby large-area sheets of the solid electrolyte are continuously coated in a uniform manner with the catalytically active metals, by first being impregnated with an aqueous solution of the particular metal and subsequently being passed through, in a water bath, between two rolls acting as electrodes, wherein a felt of carbon is arranged on the cathode side interposed between the electrolyte and the cathode roll, and thus being subjected to an electrolysis process.

## Claims

### Claim 1

A process for continuously coating a solid electrolyte with a catalytically active metal, wherein a solid electrolyte in the form of a sheet having opposite sides is dried, treated in a solution which contains the metal as a salt, then rinsed in distilled water and finally subjected to an electrolysis step in a cell which is fed with distilled water of constant temperature and to which a constant current density is applied, comprising:
providing a pair of opposed cathode and anode rolls respectively serving as cathode and anode electrodes;
interposing a felt of cabon between said cathode and anode rolls; and
passing the solid electrolyte through, in a water bath, between said cathode and anode rolls with the felt of carbon interposed between said cathode roll and said electrolyte and the opposite sides of said electrolyte contacting the felt of carbon and the anode roll, respectively.

### Claim 2 (depends on 1)

A process according to claim 1, comprising:
forming the felt of carbon as a coaxial unit with the roll formed as the cathode; and
rotating the felt synchronously with the cathode.

### Claim 3 (depends on 1)

A process according to claim 1, comprising:
maintaining the felt of carbon in a loose state; and
passing the felt in an electrolysis zone of the rolls between the rolls plane-parallel with the solid electrolyte, said solid electrolyte disposed on the cathode side between the rolls.

### Claim 4

An apparatus for continuously coating a solid electrolyte having opposite sides with a catalytically active metal, comprising:
a trough containing a water bath consisting of distilled water;
a first roll serving as an anode;
a second roll disposed opposite said anode roll and serving as a cathode; and
a felt of carbon arranged on the cathode side, said felt being maintained between said solid electrolyte and said cathode roll with said electrolyte disposed with the opposite sides of said electrolyte in contact with said felt of carbon and said anode roll.

### Claim 5 (depends on 4)

An apparatus according to claim 4, comprising:
the felt of carbon coaxially enclosing the roll and rigidly bonded to the latter by means of a synthetic resin.

### Claim 6 (depends on 4)

An apparatus according to claim 4, wherein the felt of carbon is in a loose state and, in an electrolysis zone between the rolls, assumes a position which is plane-parallel to the solid electrolyte.

### Claim 7 (depends on 4)

An apparatus according to claim 4, comprising:
the roll serving as the anode arranged beneath the roll serving as the cathode and completely submerged in the water bath; and
the roll serving as the cathode arranged above said anode roll and partially or completely immersed in the water bath.

### Claim 8 (depends on 4)

An apparatus according to claim 4, wherein the anode roll consists of platinized titanium and the cathode roll consists of corrosion-resistant steel.

### Claim 9 (depends on 4)

An apparatus according to claim 4, comprising:
the trough consisting of polypropylene and having rectangular shape defining an interior;
a rectangular frame serving as a roll support located in the interior of said trough;
said anode roll mounted on a stationary mounting;
a drive motor for driving said cathode;
said cathode roll being vertically movable and arranged in the rectangular frame by means of insulated bearing and adjustable springs; and
current leads coupled to said rolls for making electrical connection to respective of said rolls.