# US 4,396,468 A · Three phase graining of aluminum substrates

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- Number: US 4,396,468 A
- Document ID: US4396468A
- Status: Granted
- Kind: A
- Application number: 06/332,392
- Filed: 1981-12-21
- Granted: 1983-08-02
- Earliest claimed: 1981-12-21
- Assignees: American Hoechst Corporation
- Inventors: John E. Walls
- Web page: https://patentgrep.com/patent/US4396468A

## CPC

- C25F 3/04: of light metals
- B41N 3/034: {characterised by the electrochemical treatment of the aluminum support, e.g. anodisation, electro-graining; Sealing of the anodised layer; Treatment of the anodic layer with inorganic compounds; Colouring of the anodic layer}
- Y10S 205/921: Electrolytic coating of printing member, other than selected area coating
- C25F: PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- B41N: PRINTING PLATES OR FOILS (photosensitive material G03); MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

A method for the production of aluminum substrates useful in the production of lithographic printing plates which comprises simultaneously electrochemically graining both sides of an aluminum sheet in an electrolyte employing three phase alternating current.

## Claims

### Claim 1

A method for simultaneously graining both sides of a metal sheet which comprises applying one phase of a three phase alternating current source to each of two electrodes disposed one on each of the opposite sides of said metal sheet and applying the third phase of said alternating current source to said metal sheet while maintaining said sheet and said electrodes in an electrolytic medium.

### Claim 2 (depends on 1)

The method of claim 1 wherein said metal comprises aluminum or the alloys thereof.

### Claim 3 (depends on 1)

The method of claim 1 wherein said medium comprises an aqueous solution containing one or more compounds selected from the group consisting of nitric acid, hydrochloric acid, aluminum salts of mineral acids, chloride ion containing compounds and phosphate ion containing compounds.

### Claim 4 (depends on 3)

The method of claim 3 wherein said electrolyte comprises nitric acid and aluminum nitrate.

### Claim 5 (depends on 3)

The method of claim 3 wherein said electrolyte further comprises one or more compounds selected from the group consisting of gluconic acid, tartaric acid, boric acid and peroxides.

### Claim 6 (depends on 3)

The method of claim 3 wherein the concentration of said compounds in said aqueous solution ranges from about 1% by weight to the saturation point.

### Claim 7 (depends on 1)

The method of claim 1 wherein the current density applied on each side of the sheet ranges from about 30 to about 120 amperes per square decimeter.

### Claim 8 (depends on 1)

The method of claim 1 further comprising the subsequent step of anodizing one or both sides of said sheet.

### Claim 9 (depends on 1, 2, 3, 4, 5, 6, 7, 8)

The metal sheet produced according to the method of claim 1, 2, 3, 4, 5, 6, 7 or 8.

### Claim 10 (depends on 1, 2, 8)

A lithographic printing plate which comprises a lithographically suitable photosensitive composition applied to one or both surfaces of the sheet produced according to the method of claim 1, 2 or 8.

### Claim 11 (depends on 10)

The lithographic printing plate of claim 10 wherein said photosensitive composition comprises a composition selected from the group consisting of diazonium salts, quinone diazides and photopolymerizable compositions.

### Claim 12 (depends on 10)

The lithographic printing plate of claim 10 further comprising a hydrophilizing interlayer composition disposed between said sheet surface and said photosensitive composition.

### Claim 13 (depends on 11)

The lithographic printing plate of claim 11 further comprising a hydrophilizing interlayer composition disposed between said sheet surface and said photosensitive composition.

### Claim 14 (depends on 12)

The lithographic printing plate of claim 12 wherein said hydrophilizing composition comprises one or more compounds selected from the group consisting of alkali metal silicate, silicic acid, the Group IV-B metal fluorides, polyacrylic acid, the alkali zirconium fluorides, and hydrofluozirconic acid.

### Claim 15 (depends on 13)

The lithographic printing plate of claim 13 wherein said hydrophilizing composition comprises one or more compounds selected from the group consisting of alkali metal silicate, silicic acid, the Group IV-B metal fluorides, polyacrylic acid, the alkali zirconium fluorides, and hydrofluozirconic acid.