# US 4,396,400 A · Process for improving the combustion of gas oils > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,396,400 A - Document ID: US4396400A - Status: Granted - Kind: A - Application number: 06/254,048 - Filed: 1981-04-14 - Granted: 1983-08-02 - Earliest claimed: 1980-04-16 - Assignees: Societe Elf France - Inventors: Henri Grangette; Jean Bouvier - Web page: https://patentgrep.com/patent/US4396400A ## CPC - C10L 1/10: containing additives - C10L 1/125: {water} - C10L 1/2222: {(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates (C10L1/221 takes precedence)} - C10L 1/224: Amides; Imides {carboxylic acid amides, imides (C10L1/221, C10L1/2227 take precedence)} - C10L 1/2437: {Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters} - C10L: FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS ## Abstract This process consists in adding to gas oil from 100 to 5000 ppm of water in the form of a micellar clear and limped solution, which is stable for long times, obtained by the addition of one or more surfactants, associated with one or more auxiliary surface-active agents (co-surfactants). This invention substantially improves the combustion of gas oils. ## Claims ### Claim 1 Process for improving the combustion of a gas oil comprising incorporating into said fuel from 100 to 5000 ppm of water in conjunction with at least one surfactant of the formula: ##STR6## wherein Z represents CO or SO.sub.2, n is an integral number from 1 to 6, R is an alkyl group or a hydrogen atom, R' is an alkyl or alkenyl group, a hydrogen atom or an acyl group, while R" is methyl or is absent, or a salt thereof. ### Claim 2 (depends on 1) Process according to claim 1, characterized in that R is a C.sub.1 to C.sub.30 alkyl group. ### Claim 3 (depends on 1, 2) Process according to claim 1 or 2, characterized in that R' is a C.sub.1 to C.sub.30 alkyl or alkenyl group. ### Claim 4 (depends on 1, 2) Process according to claim 1 or 2, characterized in that R' is an aliphatic acyl group containing 2 to 18 carbon atoms. ### Claim 5 (depends on 3) Process according to claim 3, characterized in that R and R" are methyl groups, while R' is a C.sub.6 to C.sub.18 aliphatic chain, the compound being an N-alkyl (or N-alkenyl) dimethyl-glycine. ### Claim 6 (depends on 4) Process according to claim 4, characterized in that R is a methyl group, R" is absent and the group --ZOH is an alkali metal carboxylate the compound thus being an N-acyl sarcosinate of the alkali metal. ### Claim 7 (depends on 1, 2) Process according to claim 1 or 2 characterized in that the surfactant is accompanied by an amine, an amide or an alcohol co-surfactant. ### Claim 8 (depends on 1, 2) Process according to claim 1 or 2 characterized in that the water dispersed in the gas oil is in particles of dimensions below 0.4 micron. ### Claim 9 (depends on 7) Process according to claim 7, characterized in that the water incorporated into the gas ol is accompanied by the surfactant in the proportion of 10 to 5000 ppm with respect to the gas oil, and 0.1 to 1 part by weight of co-surfactant being present per part of surfactant. ### Claim 10 (depends on 9) Process according to claim 9, characterized in that the proportion of water incorporated into the gas oil is from 100 to 1000 ppm in conjunction with 25 to 2000 ppm of surfactant accompanied by 0.5 to 1 part by weight of co-surfactant. ### Claim 11 (depends on 1, 2) Process according to claim 1 or 2, characterized in that the surfactant is an alkali metal sulphonate in which the group: ##STR7## is an aliphatic or alkyl-aryl hydrocarbon chain. ### Claim 12 (depends on 11) Process according to claim 11, characterized in that the surfactant is an alkali metal sulphosuccinate. ### Claim 13 A gas oil composition comprising hydrocarbons boiling between 200.degree. and 425.degree. C., having improved combustion properties, which contains 100 to 5000 ppm of emusified water and 10 to 5000 ppm of at least one surfactant of the formula ##STR8## wherein Z represents CO or SO.sub.2, n is an integral number from 1 to 6, R is an alkyl group or a hydrogen atom, R' is an alkyl or alkenyl group, a hydrogen atom or an acyl group, while R" is methyl or is absent or a salt thereof. ### Claim 14 (depends on 13) Composition according to claim 13, characterized in that the water it contains is in the form of particles having dimensions less than 0.4 micron. ### Claim 15 (depends on 2) Process according to claim 2 characterized in that R is a C.sub.1 to C.sub.4 alkyl group. ### Claim 16 (depends on 3) Process according to claim 3 characterized in that R' is a C.sub.1 to C.sub.18 alkyl or alkenyl group. ### Claim 17 (depends on 7) Process according to claim 7 characterized in that said cosurfactant is a C.sub.1 to C.sub.5 alcohol. ### Claim 18 (depends on 17) The process according to claim 17 characterized in that said co-surfactant is butanol and characterized in that said surfactant is sodium coco-sarcosinate.