# US 4,395,629 A · Solid-state color imager and method of manufacturing the same

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- Number: US 4,395,629 A
- Document ID: US4395629A
- Status: Granted
- Kind: A
- Application number: 06/215,073
- Filed: 1980-12-10
- Granted: 1983-07-26
- Earliest claimed: 1979-12-10
- Assignees: Hitachi, Ltd.
- Inventors: Akira Sasano; Toshio Nakano; Ken Tsutsui; Michiaki Hashimoto; Tadao Kaneko; Yoshio Taniguchi; Haruo Matsumaru; Akiya Izumi
- Web page: https://patentgrep.com/patent/US4395629A

## CPC

- H10F 39/192: {Colour image sensors}
- H10F 39/182: {Colour image sensors}
- H10F 39/8053: {Colour filters}
- H10F: INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION

## Abstract

According to a solid-state imager of this invention, in case where a plurality of color filters are disposed on a semiconductor body for the solid-state imager including a plurality of photosensitive regions and where the color filter of a third color is constructed by the overlapping between filter members of a first color and a second color, that one of the filter members which has a spectral transmittance substantially transmitting light for exposure for use in forming the filter members is arranged as a lower layer closer to a substrate of the semiconductor body. Even when the filter members are formed by the exposure process, a solid-state imager having good characteristics can be manufactured.

## Claims

### Claim 1

A solid-state color imager having at least a semiconductor body which includes a plurality of sets of photosensitive regions therein, and color filter members which are arranged on the semiconductor body in correspondence with the photosensitive regions, said color filter members being formed by exposing desired areas of photosensitive films for color filter members to light and then developing said films into a layer in a desired shape for the colored filter members, the color filter members having at least two sorts of spectral transmittances different from each other, a third spectral transmittance to correspond to one of the photosensitive regions in each set being produced by combining the spectral transmittances of the first and second filter members; characterized in that the first and second filter members with respective first and second spectral transmittances are disposed at different levels above said semiconductor body, and the filter member exhibiting the spectral transmittance which substantially transmits the light to which the photosensitive films are exposed is arranged as a lower layer of the first and second filter members.

### Claim 2 (depends on 1)

A solid-state color imager according to claim 1, wherein said light to which the photosensitive films are exposed is substantially ultraviolet radiation, and said filter member arranged as said lower layer has the spectral transmittance which substantially transmits the ultraviolet radiation.

### Claim 3 (depends on 2)

A solid-state color imager according to claim 2, wherein said filter member arranged as said lower layer is cyanic and has the spectral transmittance which substantially transmits the ultraviolet radiation, while the filter member arranged as an upper layer is yellow.

### Claim 4 (depends on 1, 2, 3)

A solid-state color imager according to any of claims 1 to 3, wherein said plurality of sets of photosensitive regions included in said semiconductor body are constructed as a plurality of sets of impurity regions which are disposed in a semiconductor substrate.

### Claim 5 (depends on 1, 2, 3)

A solid-state color imager according to any of claims 1 to 3, wherein said plurality of sets of photosensitive regions included in said semiconductor body have a photoconductive layer which is disposed on a semiconductor substrate.

### Claim 6 (depends on 1, 2, 3)

A solid-state color imager according to any of claims 1 to 3, wherein a light-transmitting polymer resin layer is disposed on an upper surface of said semiconductor body and is overlaid with at least the color filter members.

### Claim 7 (depends on 1)

A solid-state color imager according to claim 1, wherein said first and second filter members overlap to provide said third spectral transmittance.

### Claim 8 (depends on 1)

A solid-state color imager according to claim 1, wherein said photosensitive films are made of a photosensitive organic material which accepts dyes for forming said color filter members.

### Claim 9 (depends on 8)

A solid-state color imager according to claim 8, wherein said photosensitive organic material includes polyvinyl alcohol or gelatine.

### Claim 10 (depends on 6)

A solid-state color imager according to claim 6, wherein an intermediate layer is formed around and on each of said color filter members.

### Claim 11

A method of manufacturing a solid-state color imager comprising the steps of forming a photosensitive film for a color filter member on a semiconductor body, said semiconductor body including a plurality of sets of photosensitive regions, exposing a desired area of the photosensitive film to light and then developing it into a layer in a desired shape for the color filter member, endowing the layer for the color filter member with a predetermined spectral transmittance to finish the color filter member, and covering the color filter member with a light-transmitting intermediate layer, the operations being repeated to successively form color filter members which have predetermined spectral transmittances respectively, a protective layer being disposed as an uppermost layer, the color filter members having at least two sorts of spectral transmittances different from each other, the color filter member exhibiting the first spectral transmittance being overlaid with the color filter member exhibiting the second spectral transmittance, a third spectral transmittance being produced by combining the first and second spectral transmittances; characterized in that, in forming the first and second filter members with the respective first and second spectral transmittances, the filter member exhibiting the spectral transmittance which substantially transmits said light for exposing the desired area of the photosensitive film is arranged as a lower layer of the first and second filter members.

### Claim 12 (depends on 11)

A method of manufacturing a solid-state imager according to claim 11, wherein said light for exposing the desired area of the photosensitive film is substantially ultraviolet radiation, and said filter member arranged as said lower layer has the spectral transmittance which substantially transmits the ultraviolet radiation.

### Claim 13 (depends on 12)

A method of manufacturing a solid-state color imager according to claim 12, wherein said filter member arranged as said lower layer is cyanic and has the spectral transmittance which substantially transmits the ultraviolet radiation, while the filter member arranged as an upper layer is yellow.

### Claim 14 (depends on 11)

A method of manufacturing a solid-state color imager according to claim 11, wherein said photosensitive film is made of a photosensitive organic material which accepts dyes for forming the color filter member.

### Claim 15 (depends on 14)

A method of manufacturing a solid-state color imager according to claim 14, wherein said photosensitive organic material includes polyvinyl alcohol or gelatine.

### Claim 16 (depends on 11)

A method of manufacturing a solid-state color imager according to claim 11, wherein said color filter members formed with different spectral transmittances are formed in correspondence with photosensitive regions, and wherein the third spectral transmittance produced by combining the first and second spectral transmittances is formed in correspondence with photosensitive regions.

### Claim 17 (depends on 16)

A method of manufacturing a solid-state color imager according to claim 16, wherein said color filter members are formed in correspondence with photosensitive regions by being formed overlying said photosensitive regions.
