# US 4,395,516 A · Thermoplastic resin compositions comprising copolymer of unsaturated dicarboxylic acid anhydride and vinyl aromatic monomer, ABS, and methylmethacrylate polymer

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- Number: US 4,395,516 A
- Document ID: US4395516A
- Status: Granted
- Kind: A
- Application number: 06/332,892
- Filed: 1981-12-21
- Granted: 1983-07-26
- Earliest claimed: 1980-12-26
- Assignees: Daicel Chemical Industries, Ltd.
- Inventors: Tatuhiko Imai; Akira Ohi
- Web page: https://patentgrep.com/patent/US4395516A

## CPC

- C08L 55/02: ABS [Acrylonitrile-Butadiene-Styrene] polymers
- C08L 25/12: with unsaturated nitriles
- C08L 25/14: with unsaturated esters
- C08L 35/06: Copolymers with vinyl aromatic monomers
- C08L 51/003: {grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds (C08L51/04, C08L51/06 take precedence)}
- C08L 51/04: grafted on to rubbers
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)

## Abstract

A thermoplastic resin composition having improved heat resistance, impact resistance and molding properties comprises a resin mixture of: (A) 5-95 wt. % of a polymer containing an unsaturated dicarboxylic anhydride and a vinyl aromatic compound and optionally a vinyl cyanide compound, an alkyl acrylate or methacrylate monomer and/or a rubber, (B) 95-5 wt. % of ABS resin containing 2-70 wt. % of a rubber component, and further containing and (C) 0.1-20 wt. %, per 80-99.9 wt. % of the sum of (A)+(B), of a modified thermoplastic acrylic resin which is a copolymer or a multi-stage polymer containing at least 20 wt. % of methyl methacrylate.

## Claims

### Claim 1

A thermoplastic molding composition which consists essentially of a blend of
(A) from 5 to 95 wt. % of a copolymer consisting essentially of
(1) from 5 to 50 wt. % of an unsaturated dicarboxylic acid anhydride,
(2) from 50 to 95 wt. % of a vinyl aromatic monomer,
(3) from 0 to 30 wt. % of a vinyl cyanide monomer, alkyl acrylate monomer or alkyl methacrylate monomer, and
(4) from 0 to 50 wt. % of a rubber
(B) from 5 to 95 wt. % of an ABS resin containing from 2 to 70 wt. %, based on said ABS resin, of a butadiene rubber, and
(C) from 0.1 to 20 wt. %, per 80 to 99.9 wt. % of the sum of the amounts of (A) plus (B), of thermoplastic acrylic resin different from (A) and (B) and which is a copolymer or multi-stage polymer containing at least 20 wt. % of methyl methacrylate, based on said acrylic resin.

### Claim 2 (depends on 1)

A composition as claimed in claim 1, wherein said ABS resin (B) has been polymerized by bulk-suspension polymerization.

### Claim 3 (depends on 1)

A composition as claimed in claim 1, wherein said copolymer (A) is a copolymer of styrene and maleic anhydride.

### Claim 4 (depends on 1)

A composition according to claim 1, wherein said unsaturated dicarboxylic acid anhydride is maleic anhydride.

### Claim 5 (depends on 1)

A composition according to claim 1, wherein said vinyl aromatic monomer is selected from the group consisting of styrene and .alpha.-methylstyrene.

### Claim 6 (depends on 1)

A composition according to claim 1, wherein said vinyl cyanide monomer is acrylonitrile or methacrylonitrile, said alkyl acrylate monomer is methyl acrylate or ethyl acrylate, and said alkyl methacrylate monomer is methyl methacrylate or ethyl methacrylate.

### Claim 7 (depends on 1)

A composition according to claim 1, wherein said resin (C) consists essentially of units of said methyl methacrylate, units of one or more members selected from the group consisting of alkyl acrylates, wherein the alkyl group has 1 to 18 carbon atoms, and a rubber.

### Claim 8 (depends on 7)

A composition according to claim 7, wherein the alkyl group of said alkyl acrylates is selected from ethyl, butyl, octyl and stearyl.

### Claim 9 (depends on 1)

A composition according to claim 1, wherein said copolymer (A) contains 2 to 50 wt. % of said rubber.

### Claim 10 (depends on 1)

A resin composition as claimed in claim 1, wherein said resin (C) consists of units of said methyl methacrylate and units of one or more members selected from the group consisting of alkyl acrylates, wherein the alkyl group has 1 to 18 carbon atoms.