# US 4,395,501 A · Polymer-carbon black mixing > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,395,501 A - Document ID: US4395501A - Status: Granted - Kind: A - Application number: 06/289,993 - Filed: 1981-08-04 - Granted: 1983-07-26 - Earliest claimed: 1980-10-31 - Assignees: Polysar Limited - Inventors: George J. Briggs; Yung-Kang Wei - Web page: https://patentgrep.com/patent/US4395501A ## CPC - C08J 3/226: {using a polymer as a carrier} - C08J 3/203: {Solid polymers with solid and/or liquid additives} - C08J 2321/00: Characterised by the use of unspecified rubbers - C08J 2421/00: Characterised by the use of unspecified rubbers - C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29) ## Abstract A process is provided for the production of vulcanizates having improved properties wherein polymer (or polymers) is mixed with carbon black in two separate steps such that in one step a major proportion of the carbon black to be used is mixed with polymer and in a second step a zero to minor proportion of the carbon black to be used is mixed with polymer. Such improved vulcanizates may be used, for example, in tires or a variety of mechanical goods. ## Claims ### Claim 1 A process for producing a vulcanizate having improved properties, said process comprising the steps of: (a) mixing in at least two separate steps two or more C.sub.4 or C.sub.5 conjugated diolefin containing polymers with carbon black and other compounding ingredients except cure active agents, followed by resting of the compounds so produced, (b) mixing the compounds from (a) with other compounding ingredients including sulphur and sulphur-containing or peroxidic cure active agents, (c) shaping the mixture from (b), and (d) vulcanizing the shaped mixture by heating at a temperature of from about 145.degree. C. to about 225.degree. C. for a time of from about 3 to about 60 minutes, characterized in that in step (a), the polymers are mixed in at least two separate steps wherein: (i) about 33 to about 60 weight percent of one or more of the polymers is mixed with from about 60 to 100 weight percent of the carbon black and with other compounding ingredients except cure active agents, said polymers being selected from C.sub.4 or C.sub.5 conjugated diolefin containing synthetic polymers, (ii) about 67 to about 40 weight percent of one or more of the polymers is mixed with from 0 to about 40 weight percent of the carbon black and with other compounding ingredients except cure active agents, said polymers being selected from C.sub.4 or C.sub.5 conjugated diolefin containing synthetic polymers and natural rubber, such mixing of polymers, carbon black and other compounding ingredients being in a single mix or in separate mixes containing only a single polymer, (iii) the compounds from (i) and (ii) are supplied to step (b). ### Claim 2 (depends on 1) The process of claim 1 wherein one of the polymers used in step (i) is a masterbatch comprising 100 parts by weight of styrene-butadiene polymer, 0 to about 100 parts by weight of oil and from about 30 to about 150 parts by weight of carbon black. ### Claim 3 (depends on 2) The process of claim 2 wherein said masterbatch comprises 100 parts by weight of styrene-butadiene polymer, from about 25 to about 50 parts by weight of oil and from about 40 to about 80 parts by weight of carbon black. ### Claim 4 (depends on 1) The process of claim 1 wherein one or two of polybutadiene, natural rubber or styrene-butadiene polymer are used as polymer in step (ii). ### Claim 5 (depends on 1) The process of claim 1 wherein the total carbon black to be used is from about 30 to about 80 parts by weight per 100 parts by weight of polymer. ### Claim 6 (depends on 5) The process of claim 5 wherein two polymers are used, the polymer used in step (i) is one of styrene-butadiene polymer or polybutadiene and the polymer used in step (ii) is one of styrene-butadiene polymer, polybutadiene or natural rubber. ### Claim 7 (depends on 5) The process of claim 5 wherein three polymers are used, the polymer used in step (i) is one of styrene-butadiene polymer or polybutadiene and the polymers used in step (ii) are selected from styrene-butadiene polymer, polybutadiene and natural rubber. ### Claim 8 (depends on 7) The process of claim 7 wherein the polymers used in step (ii) are mixed separately and carbon black is mixed with only one of the polymers. ### Claim 9 (depends on 6, 7) The process of claims 6 or 7 wherein the amount of carbon black to be used is from about 30 to about 50 parts by weight per 100 parts by weight of polymers and from about 75 to 100 weight percent of the carbon black is mixed with polymer in step (i). ### Claim 10 (depends on 6, 7) The process of claims 6 or 7 wherein the amount of carbon black to be used is from about 50 to about 80 parts by weight per 100 parts by weight of polymers and from about 60 to about 75 weight percent of the carbon black is mixed with polymer in step (i). ### Claim 11 A process for producing a vulcanizate having improved properties, said process comprising the steps of: (a) mixing in two separate steps one or two C.sub.4 to C.sub.5 conjugated diolefin containing polymers with carbon black and other compounding ingredients except cure active agents, followed by resting of the compounds so produced, (b) mixing the compounds from (a) with other compounding ingredients, including sulphur and sulphur-containing or peroxidic cure active agents, (c) shaping the mixture from (b), and (d) vulcanizing the shaped mixture by heating at a temperature of from about 145.degree. to about 225.degree. C. for a time of from about 3 to about 60 minutes, characterized in that in step (a) the polymer or polymers are mixed in two separate steps wherein: (i) about 40 to about 60 weight percent of the polymer or polymers selected from C.sub.4 or C.sub.5 conjugated diolefin containing synthetic polymers is mixed with from about 60 to 100 weight percent of the carbon black and with other compounding ingredients except cure active agents, (ii) about 60 to about 40 weight percent of the polymer or polymers selected from C.sub.4 or C.sub.5 conjugated diolefin containing synthetic polymers and natural rubber is mixed with from 0 to about 40 weight percent of the carbon black and with other compounding ingredients except cure active agents, and (iii) the compounds from (i) and (ii) are supplied to step (b). ### Claim 12 (depends on 11) The process of claim 11 wherein the polymer used in step (i) is selected from styrene-butadiene polymer, polyisoprene or polybutadiene and the polymer used in step (ii) is selected from styrene-butadiene polymer, polyisoprene, polybutadiene or natural rubber. ### Claim 13 (depends on 11) The process of claim 11 wherein the total carbon black to be used is from about 30 to about 80 parts by weight per 100 parts by weight of polymer. ### Claim 14 (depends on 11) The process of claim 11 wherein the polymer used in step (i) is a masterbatch comprising 100 parts by weight of styrene-butadiene polymer, 0 to about 100 parts by weight of oil and from about 30 to about 150 parts by weight of carbon black. ### Claim 15 (depends on 14) The process of claim 14 wherein said masterbatch comprises 100 parts by weight of styrene-butadiene polymer, from about 25 to about 50 parts by weight of oil and from about 40 to about 80 parts by weight of carbon black. ### Claim 16 (depends on 14) The process of claim 14 wherein the polymer used in step (ii) is one of styrene-butadiene polymer, polybutadiene or natural rubber.