# US 4,395,445 A · Coating and primer formulation on the basis of a copolymer of tetrafluoroethylene and a perfluoro-(alkylvinyl) ether, and use thereof

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- Number: US 4,395,445 A
- Document ID: US4395445A
- Status: Granted
- Kind: A
- Application number: 06/300,900
- Filed: 1981-09-10
- Granted: 1983-07-26
- Earliest claimed: 1980-02-19
- Assignees: Hoechst Aktiengesellschaft
- Inventors: Gerhard Gebauer; Franz Mayer
- Web page: https://patentgrep.com/patent/US4395445A

## CPC

- B05D 5/083: {involving the use of fluoropolymers}
- C09D 127/18: Homopolymers or copolymers of tetrafluoroethene
- B05D 2401/20: Aqueous dispersion or solution
- C08L 27/18: Homopolymers or copolymers or tetrafluoroethene
- C08L 2205/02: containing two or more polymers of the same C08L -group
- Y10T 428/31544: Addition polymer is perhalogenated
- B05D: PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL (conveying articles or workpieces through baths of liquid B65G, e.g. B65G49/02)
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

Coating formulations having improved adhesion are described which are especially suitable as primer for top coats of fluorocarbon polymers, which comprise (a) a copolymer of tetrafluoroethylene units, units of a perfluoroalkylvinyl ether and optionally units of hexafluoropropylene or vinylidene fluoride, (b) optionally dispersed polytetrafluoroethylene particles in addition, (c) a mixture of lithium hydroxide and suspended fine-particle pyrogenic SiO.sub.2, and (d) water as liquid carrier. The coating formulations are applied according to known methods to substrates such as metals, glass or ceramic surfaces. They may be used as single-layer systems without top coat, or as primer, the top coat being applicable immediately after a short-time drying only. Application fields are the coating of household equipment or technical apparatus, where a high-grade adhesion onto the substrate, combined with anti-adhesive properties and a smooth surface are obtained.

## Claims

### Claim 1

A method for improving the coating of a substrate with a fluoropolymer which comprises applying a primer composition and subsequently without an intermediate heat treatment for sintering applying a topcoat of a tetrafluoroethylene homopolymer or copolymer wherein the improvement comprises applying a primer composition consisting essentially of
(a) from 100 to 20 weight %, relative to the total polymer solids of the components (a) and (b), of a copolymer of copolymerized tetrafluoroethylene units; from 0.5 to 11 weight % of copolymerized units of a perfluoro(alkylvinyl) ether of the formula CF.sub.2 .dbd.CF--OR, in which R is a perfluoroalkyl radical having from 1 to 10 carbon atoms; and from 0 to 12 weight % of copolymerized units of hexafluoropropylene or vinylidene fluoride, each relative to the total weight of the copolymer;
(b) from 0 to 80 weight %, relative to the total polymer solids of components (a) and (b), of dispersed polytetrafluoroethylene particles having a mean grain size of from 0.05 to 30 .mu.m;
(c) from 10 to 70 weight % of the weight sum of (a) plus (b) plus (c) of lithium hydroxide and suspended, fine-particle SiO.sub.2 produced by thermal treatment; the molar ratio LiOH: SiO.sub.2 being from 1:0.5 to 1:30; and
(d) water as liquid carrier.

### Claim 2 (depends on 1)

The method of claim 1, wherein the component (a) of the primer composition in the copolymer contains from 0.4 to 6.5 weight % of copolymerized units of hexafluoropropylene and 1.5 to 6.0 weight % of copolymerized units of perfluoro(n-propylvinyl) ether and copolymerized tetrafluoroethylene units.

### Claim 3 (depends on 1)

The method of claim 1, wherein the weight sum of components (a), (b) and (c) of the primer composition is from 12 to 60 weight percent.

### Claim 4 (depends on 1)

The method of claim 1, wherein the primer composition contains in addition pigments and fillers.