# US 4,395,428 A · Process for preparing cooked meat having reduced levels of N-nitrosamines > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,395,428 A - Document ID: US4395428A - Status: Granted - Kind: A - Application number: 06/286,743 - Filed: 1981-07-27 - Granted: 1983-07-26 - Earliest claimed: 1981-07-27 - Assignees: Armour and Company - Inventors: Richard F. Theiler - Web page: https://patentgrep.com/patent/US4395428A ## CPC - A23B 4/20: Organic compounds; Microorganisms; Enzymes - A23B 4/0235: {with organic compounds or biochemical products} - A23B 4/0526: {Smoke generators or smoking apparatus using liquid smoke in gaseous or liquid form} - A23B: PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES ## Abstract A process for preparing cured meat which, when cooked for consumption, contains substantially reduced levels of N-nitrosamines. The process comprises the steps of introducing into uncured meat a nitrite-containing curing composition, a tocopherol and an additional nitrosamine-inhibiting substance which may be liqid smoke, a reducing sugar, or a combination thereof, and thereafter processing the meat to effect curing. The invention is applicable either to ground meat, such as sausage, or to intact cuts of meat, such as ham or bacon bellies. ## Claims ### Claim 1 A process for preparing a cured meat product which, when cooked for comsumption, contains substantially reduced levels of N-nitrosamines, comprising the steps of introducing into uncured meat a nitrite-containing curing composition, a tocopherol, and an inhibitor substance selected from the group consisting of preneutralized liquid smoke, buffered liquid smoke, reducing sugar, and mixtures thereof, and processing said meat to effect curing. ### Claim 2 (depends on 1) The process of claim 1 wherein the uncured meat is first ground and subsequently mixed with the nitrite-containing curing composition, the tocopherol and the inhibitor substance. ### Claim 3 (depends on 2) The process of claim 2 wherein the concentration of said tocopherol is 10-1,000 ppm, the liquid smoke is in concentration to provide 5-800 ppm phenols and 10-4,000 ppm carbonyl compounds, and the concentration of said reducing sugar is 10 ppm to 40,000 ppm, all said ppm concentrations being based on the weight of the uncured meat. ### Claim 4 (depends on 2) The process of claim 2 wherein the concentration of said tocopherol is 100-800 ppm, the liquid smoke is in concentration to provide 40-240 ppm phenols and 30-720 ppm carbonyl compounds, and the concentration of said reducing sugar is 1,000-9,000 ppm all said ppm concentrations being based on the weight of the uncured meat. ### Claim 5 (depends on 2) The process of claim 2 wherein the meat is ground pork. ### Claim 6 (depends on 2) The process of claim 2 wherein the meat is ground beef. ### Claim 7 (depends on 2) The process of claim 2 wherein the meat is ground poultry. ### Claim 8 (depends on 2) The process of claim 2 wherein said reducing sugar is glucose. ### Claim 9 A process for preparing cured, unground meat which, when cooked for consumption, contains substantially reduced levels of N-nitrosamines, said process comprising the steps of Preparing a nitrite-stable injectable curing solution comprising a nitrite-containing pickle, a tocopherol, and an inhibitor substance selected from the group consisting of preneutralized liquid smoke, buffered liquid smoke, reducing sugar, and mixtures thereof; Injecting said curing solution into uncured, unground meat; and Processing said meat to effect curing. ### Claim 10 (depends on 9) The process of claim 9 wherein the pickle is buffered to stabilize the nitrite. ### Claim 11 (depends on 10) The process of claim 10 wherein the buffer is sodium tripolyphosphate. ### Claim 12 (depends on 9) The process of claim 9 wherein the said pickle is unbuffered and said liquid smoke is preneutralized to avoid depletion in the unbuffered pickle. ### Claim 13 (depends on 9) The process of claim 9 wherein the concentration of said tocopherol is 10-1000 ppm, the liquid smoke is in concentration to provide 5-400 ppm of phenols and 10-2000 ppm carbonyl compounds, and the concentration of the said reducing sugar is 150-30,000 ppm, all said ppm concentrations being based on the weight of the uncured meat. ### Claim 14 (depends on 9) The process of claim 9 wherein the concentration of said tocopherol is 100-500 ppm, the liquid smoke is in concentration to provide 40-120 ppm of phenols and 30-360 ppm carbonyl compounds, and the concentration of the said reducing sugar is 1,000-20,000 ppm, all said ppm concentrations being based on the weight of the uncured meat. ### Claim 15 A process for preparing cured bacon which, when cooked for consumption, contains substantially reduced levels of N-nitrosamines, said process comprising the steps of Preparing a nitrite-stable injectable curing solution comprising A nitrite-containing pickle From 10 to 1000 ppm of tocopherol, based upon the green weight of the bacon belly to be injected A preneutralized or buffered liquid smoke in concentration to provide 5 to 400 ppm phenols and 10 to 2000 ppm carbonyl compounds, based upon the green weight of the bacon belly, the ratio of carbonyls to phenols being within the range of 0.5-5 to 1, An effective amount of a food grade emulsifier which does not substantially increase N-nitrosamine formation; Injecting said curing solution into a green bacon belly; and Processing said bacon belly to effect curing. ### Claim 16 A process for preparing cured bacon which, when cooked for consumption, contains substantially reduced levels of N-nitrosamines, said process comprising the steps of Preparing a nitrite-stable injectable curing solution comprising A nitrite-containing pickle From 10 to 1000 ppm of tocopherol, based upon the green weight of the bacon belly to be injected, From 150 to 10,000 ppm of reducing sugar, based upon the green weight of the bacon belly, and An effective amount of a food grade emulsifier which does not substantially increase N-nitrosamine formation; Injecting said curing solution into a green bacon belly; and Processing said bacon belly to effect curing. ### Claim 17 A process for preparing cured bacon which, when cooked for consumption, contains substantially reduced levels of N-nitrosamines, said process comprising the steps of Preparing a nitrite-stable injectable curing solution comprising A nitrite-containing pickle From 10 to 1000 ppm of tocopherol, based upon the green weight of the bacon belly to be injected A preneutralized or buffered liquid smoke in concentration to provide 5 to 400 ppm phenols and 10 to 2000 ppm carbonyl compounds, based on the green weight of the bacon belly, the ratio of carbonyls to phenols being within the range of 0.5 to 1, From 150 to 10,000 ppm of reducing sugar, based upon the green weight of the bacon belly, and An effective amount of a food grade emulsifier which does not substantially increase N-nitrosamine formation; Injecting said curing solution into a green bacon belly; and Processing said bacon belly to effect curing.