# US 4,395,360 A · Catalyst components and catalysts for the polymerization of alpha-olefins

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- Number: US 4,395,360 A
- Document ID: US4395360A
- Status: Granted
- Kind: A
- Application number: 06/256,235
- Filed: 1981-04-21
- Granted: 1983-07-26
- Earliest claimed: 1980-04-22
- Assignees: Montedison S.p.A.
- Inventors: Enrico Albizatti; Enzo Giannetti; Umberto Scata
- Web page: https://patentgrep.com/patent/US4395360A

## CPC

- C08F 10/00: Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

## Abstract

Catalyst components for the polymerization of olefins are disclosed. Said components comprise the solid product of the reaction of a halogenated Ti compound and of an electron-donor compound not containing active H atoms with the solid product of the reaction between an electron-donor compound containing active H atoms and a Mg dihalide obtained by decomposition, with halogenating agents other than the above halogenated Ti compound, of product (d) obtained from the reaction between an organometallic Mg compound of formula R.sub.m MgX.sub.n is which R is a hydrocarbon or --OR group, X is halogen or a group R, OR, or COX' (X' being halogen), 0<m=2, 0<n<2 and m+n is 2; and a Si compound selected from polysiloxanes, hydropolysiloxanes, silanols and polysilanols.

## Claims

### Claim 1

Components of catalysts for polymerizing olefins comprising the solid product of the reaction of:
(a) a halogenated Ti compound containing at least a Ti-halogen bond, and
(b) an electron-donor compound not containing active hydrogen atoms (ED) reacted as such or as a complex with product (c), said complex being obtained without cogrinding, and employing in such amount, that from 0.2 to 4 moles of compound (ED) per gram atom of Ti of component (a) are present in the catalytic component with
(c) the solid product, prepared without cogrinding, of the reaction between at least an electron-donor compound containing active hydrogen atoms (HED), selected from aliphatic, cycloaliphatic and aromatic alcohols and thioalcohols having 1 to 20 C, phenols and thiophenols having 6 to 20 C and the silanols having 1 to 20 C, and a Mg dihalide, or complexes thereof with an (ED) compound, said Mg dihalide being obtained by decomposition, with halogenating agents other than the Ti compounds of (a), of reaction product (d) of an organometallic Mg compound of general formula R.sub.m MgX.sub.n, in which R is an alkyl, aryl, cycloalkyl or alkenyl radical having 1 to 20 C, or a group OR, and X is a halogen, R, OR in which R has the meaning as specified or COX' in which X' is a halogen, m is 0<m.ltoreq.2, n is 0<n<2 and M+n=2; with a silicium compound selected from polysiloxanes, hydropolysiloxanes, silanols and polysilanols, product (c) being reacted as such without any intermediate pretreatment with an Al-alkyl compound.

### Claim 2 (depends on 1)

Catalytic components according to claim 1, in which compound (a) is a Ti tetrahalide, compound (ED) employed in (b) is an alkyl, aryl or cycloalkyl ester of benzoic acid or derivatives thereof, product (c) is obtained by reacting 0.1 to 6 moles of an aliphatic alcohol or of a phenol with 1 mole of Mg dichloride or dibromide or complexes thereof with ethers, obtained by decomposition, with halogenating agents selected from the group consisting of halogenated compounds of Si, SOCl.sub.2, AlR.sub.3 or AlR.sub.2 X in which R is an alkyl radical and X is halogen of reaction product (d).

### Claim 3 (depends on 1, 2)

Catalysts for polymerizing olefins, prepared by reacting the catalyst components of claims 1 or 2, with organometallic Al compounds.

### Claim 4 (depends on 3)

Catalysts according to claim 3 in which the organometallic Al compound is an Al trialkyl compound.

### Claim 5 (depends on 4)

Catalysts according to claim 4, in which the Al-trialkyl compound is complexed by reaction with 0.1 to 1 mole of electron-donor compound (ED).

### Claim 6 (depends on 1)

The components of claim 1 in which, in the formula R.sub.m MgX.sub.n, X is chlorine, bromine or iodine.