# US 4,395,309 A · Fractional distillation of hydrocarbons from coal > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,395,309 A - Document ID: US4395309A - Status: Granted - Kind: A - Application number: 06/203,255 - Filed: 1980-11-03 - Granted: 1983-07-26 - Earliest claimed: 1980-11-03 - Inventors: Ernest P. Esztergar - Web page: https://patentgrep.com/patent/US4395309A ## CPC - C10G 1/02: by distillation - C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES ## Abstract Process and apparatus for recovering volatile distillates from coal, and other solid carbonaceous fuel sources, by heating the top surface of a bilayer of coal formed of an upper layer of recycled coal and a lower layer of green coal, maintaining the lower level of green coal at a temperature cool enough to condense constituents distilled from the upper layer of recycle coal, and recycling the once passed green coal as recycle coal is disclosed. ## Claims ### Claim 1 The process for recovering liquid fuel from coal comprising continuously forming a bilayer coal bed on a foraminous conveyor, passing the coal bed through a substantially oxygen free processing zone, heating the bed in said zone to a temperature of higher than about 550.degree. F., while maintaining the bottom of the bed at a temperature of not higher than about 450.degree. F., removing the top of the coal bed bilayer from the processing zone as product char, recycling the bottom of the coal bed bilayer to the processing zone to form the top of a coal bed bilayer in another pass through the processing zone, and removing liquid through the foraminous conveyor as product liquid fuel. ### Claim 2 (depends on 1) The process of claim 1 wherein the process is carried out continuously by continuous removal of char and liquid product, continuous recycle of the botton of the bed to the top of the bed and continuous feeding green coal as the bottom of the coal bilayer bed. ### Claim 3 (depends on 2) The process of claim 2 further including the step of passing substantially oxygen free gas downwardly through the bed to carry volatile materials released from the top of the bed through the bottom of the bed for condensing at least some of said volatile materials on the coal forming the bottom of the bed. ### Claim 4 (depends on 1) The process of claim 1 further comprising the steps of maintaining a gas pressure differential through the bed, the high temperature side being maintained at a higher pressure than the low temperature side of the bed, thereby causing gas to flow from the high temperature side of the bed through the bed to the low temperature side of the bed for carrying volatilized constituents of coal into contact with the low temperature side of the bed for condensing at least some of said volatilized constituents. ### Claim 5 (depends on 4) The process of claim 4 wherein forming of the bed comprises placing a layer of primary green coal on a horizontal foraminous conveyor surface, and placing a layer of recycle coal on top of the green coal. ### Claim 6 (depends on 5) The process of claim 5 wherein the heating of the bed comprises directing radiant heat to the upper surface of said bed of coal to thereby preferentially heat the recycle coal without directly heating the green coal, the green coal being maintained at the lower temperature. ### Claim 7 (depends on 1) The process of claim 1 further comprising the steps of controlling the heating of the one side of the bed such that approximately one-half the bed comprises a high temperature side of the bed at a maximum temperature of greater than 550.degree. F. and the other approximately one-half the bed comprises a low temperature side of the bed at a temperature less than 450.degree. F. ### Claim 8 (depends on 7) The process of claim 7 wherein forming the coal bed comprises placing a layer of primary green coal on a horizontal foraminous conveyer surface, and placing a layer of recycle coal on top of the green coal. ### Claim 9 (depends on 8) The process of claim 8 wherein the heating of the bed comprises directing radiant heat to an upper surface of said bed of coal to thereby preferentially heat the recycle coal without directly heating the green coal, the green coal being maintained at the lower temperature. ### Claim 10 (depends on 9) The process of claim 9 wherein the maintaining of the other side of the bed at said lower temperature comprises the step of cooling the other, green coal side of the bed. ### Claim 11 (depends on 10) The process of claim 10 wherein the lower temperature is from about 300.degree. F. to about 400.degree. F. and the higher temperature is from about 550.degree. F. to about 1000.degree. F. ### Claim 12 (depends on 10) The process of claim 10 further comprising the steps of removing gas from the process, recovering at least some gaseous constituents from the gas removed, and recycling at least a portion of said gas as a substantially oxygen free process cover gas. ### Claim 13 (depends on 12) The process of claim 12 comprising the steps of collecting the product liquid fuel in at least two fractions including a fraction having boiling points of from about 225.degree. F. to about 425.degree. F. and a fraction having boiling points of higher than about 425.degree. F. ### Claim 14 (depends on 1) The process of claim 1 wherein forming of the bed comprises placing a layer of primary green coal on a horizontal foraminous conveyor surface, and placing a layer of recycle coal on top of the green coal. ### Claim 15 (depends on 14) The process of claim 14 wherein the heating of the bed comprises directing radiant heat to the upper surface of said bed of coal to thereby preferentially heat the recycle coal without directly heating the green coal, the green coal being maintained at the lower temperature. ### Claim 16 (depends on 15) The process of claim 15 comprising the steps of collecting the product liquid fuel in at least two fractions including a fraction having a weighted average boiling point of from about 225.degree. F. to about 425.degree. F. and a fraction having a weighted average boiling point of higher than about 425.degree. F.