# US 4,395,288 A · Liquid recording medium > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,395,288 A - Document ID: US4395288A - Status: Granted - Kind: A - Application number: 06/365,731 - Filed: 1982-04-05 - Granted: 1983-07-26 - Earliest claimed: 1978-07-04 - Assignees: Canon Kabushiki Kaisha - Inventors: Tsuyoshi Eida; Yasuhiro Yano; Masahiro Haruta; Yohji Matsufuji; Tokuya Ohta - Web page: https://patentgrep.com/patent/US4395288A ## CPC - C09D 11/328: characterised by dyes - C09D 11/037: characterised by the pigment - C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D) ## Abstract A liquid recording medium for use in a recording process, wherein said recording medium is discharged from a discharge orifice in a recording head and spattered in the form of droplets for recording, and containing (a) a recording agent for forming recorded images and (b) a carrier liquid capable of dissolving or dispersing the recording agent. The recording agent is a compound having 2-8 sulfo groups per molecule and having the formula (A) ##STR1## where the Q.sub.1 radicals are similar or dissimilar members selected from phenylene and naphthylene, the Q.sub.2 radicals are similar or dissimilar members selected from phenyl and naphthyl, the Q.sub.1 radicals and the Q.sub.2 radicals may be unsubstituted or amino substituted, hydroxyl substituted or sulfo substituted, R.sub.1 -R.sub.6 are similar or dissimilar members selected from hydrogen, amino, hydroxyl and sulfo, and said sulfo groups as mentioned above are all in the form of sodium salt or quaternary ammonium salt. ## Claims ### Claim 1 In an ink jet recording process for discharging a liquid recording medium in the form of droplets for recording from a discharge orifice in a recording head, the improvement which comprises employing a liquid recording medium comprising: (a) a carrier liquid selected from the group consisting of water and a mixture of water and a water-soluble organic solvent; and (b) a recording agent having the formula ##STR15## wherein said recording agent has 2-8 sulfo groups per molecule, each in the form of a sodium salt or quaternary ammonium salt and wherein the Q.sub.1 radicals are similar or dissimilar members selected from the group consisting of phenylene and naphthalene, the Q.sub.2 radicals are similar or dissimilar members selected from the group consisting of phenyl and naphthyl, the Q.sub.1 radicals and the Q.sub.2 radicals may be unsubstituted or amino substituted, hydroxyl substituted or sulfo substituted, and R.sub.1 -R.sub.6 are similar or dissimilar members selected from the group consisting of hydrogen, amino, hydroxyl and sulfo. ### Claim 2 (depends on 1) A liquid recording process according to claim 1 in which the content of the compound (A) is 0.1-15% by weight based on the total weight of the liquid recording medium. ### Claim 3 (depends on 1) A liquid recording process according to claim 1 in which the content of the compound (A) is 0.5-10% by weight based on the total weight of the liquid recording medium. ### Claim 4 (depends on 1) A liquid recording process according to claim 1 in which the content of the compound (A) is 1-5% by weight based on the total weight of the liquid recording medium. ### Claim 5 (depends on 1) A liquid recording process according to claim 1 in which the compound (A) has 3-8 sulfo groups in the form of sodium salt or quaternary ammonium salt. ### Claim 6 (depends on 1) A liquid recording process according to claim 1 in which sulfo groups in the form of sodium salt or quaternary ammonium salt attach to the central naphthalene ring and these sulfo groups attach to symmetrical positions. ### Claim 7 (depends on 1) A liquid recording process according to claim 1 in which the compound (A) has the sulfo groups in the form of sodium salt or quaternary ammonium salt attaching to the central naphthalene ring all at the same side with respect to the long molecular axis. ### Claim 8 (depends on 1) A liquid recording process according to claim 1 in which Q.sub.1 is phenylene having sulfo in the form of sodium salt or quaternary ammonium salt. ### Claim 9 (depends on 1) A liquid recording process according to claim 1 in which the sulfo groups are in the form of a quaternary ammonium salt having a group selected from C.sub.1 -C.sub.5 alkyl, --C.sub.2 H.sub.4 OH and ##STR16## ### Claim 10 In an ink jet recording process for discharging a liquid recording medium in the form of droplets for recording from a discharge orifice in a recording head, the improvement which comprises employing a liquid recording medium comprising: (a) a carrier liquid selected from the group consisting of water and a mixture of water and a water-soluble organic solvent; and (b) a recording agent having the formula ##STR17## wherein said recording agent has 2-8 sulfo groups per molecule, each in the form of a sodium salt or quaternary ammonium salt and wherein the Q.sub.1 radicals are similar or dissimilar members selected from the group consisting of phenylene and naphthalene, the Q.sub.2 radicals are similar or dissimilar members selected from the group consisting of phenyl and naphthyl, the Q.sub.1 radicals and the Q.sub.2 radicals may be unsubstituted or amino substituted, hydroxyl substituted or sulfo substituted, and R.sub.1 -R.sub.4 are similar or dissimilar members selected from the group consisting of hydrogen and sulfo. ### Claim 11 (depends on 10) The liquid recording process according to claim 10 in which the content of said recording agent is 0.1-15% by weight based on the total weight of the liquid recording medium. ### Claim 12 (depends on 10) The liquid recording process according to claim 10 in which the content of said recording agent is 0.5-10% by weight based on the total weight of the liquid recording medium. ### Claim 13 (depends on 10) The liquid recording process according to claim 10 in which the content of said recording agent is 1-5% by weight based on the total weight of the liquid recording medium. ### Claim 14 (depends on 10) The liquid recording process according to claim 10 in which said recording agent has 3-8 sulfo groups in the form of a sodium salt or a quaternary ammonium salt. ### Claim 15 (depends on 10) The liquid recording process according to claim 10 in which sulfo groups in the form of a sodium salt or a quaternary ammonium salt are attached to the central naphthalene ring and these sulfo groups attached to symmetrical positions. ### Claim 16 (depends on 10) The liquid recording process according to claim 10 in which said recording agent has the sulfo groups in the form of a sodium salt or a quaternary ammonium salt attached to the central naphthalene ring at the same side with respect to the long molecular axis. ### Claim 17 (depends on 10) The liquid recording process according to claim 10 in which Q.sub.1 is phenylene having sulfo in the form of a sodium salt or a quaternary ammonium salt. ### Claim 18 (depends on 10) The liquid recording process according to claim 10 in which the sulfo groups are in the form of a quaternary ammonium salt having a group selected from C.sub.1 -C.sub.5 alkyl, --C.sub.2 --H.sub.4 OH and ##STR18## .