# US 4,394,766 A · Graphitization system method and apparatus > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,394,766 A - Document ID: US4394766A - Status: Granted - Kind: A - Application number: 06/289,249 - Filed: 1981-08-03 - Granted: 1983-07-19 - Earliest claimed: 1981-08-03 - Assignees: Great Lakes Carbon Corporation - Inventors: Berch Y. Karagoz - Web page: https://patentgrep.com/patent/US4394766A ## CPC - F27D 11/04: with direct passage of current through the material being heated - C04B 35/52: based on carbon, e.g. graphite - H05B 3/0004: {Devices wherein the heating current flows through the material to be heated (Circuit arrangements for heating by passing the current directly across the material to be heated H05B3/0023; granular, powdered or fluid material H05B3/60)} - Y02P 10/25: Process efficiency - F27D: DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE - C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE - H05B: ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL - Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS ## Abstract Amorphous carbon bodies forming a lengthwise series horizontal string or column 26 are converted to graphite by the Joule effect in a semi-cylindrical metal shell 20 with a refractory lining 22 and containing particulate thermal insulation medium 28. When the conversion to graphite is complete the insulation medium is dumped through the bottom of the metal shell into a hopper 50 and transferred for re-use while hot. Air pollution control is facilitated and energy and capital costs are lowered by specialization of equipment, retention of sensible heat and shorter cycle times, allowing operation with less equipment and higher production rates. ## Claims ### Claim 1 An apparatus for the production of graphite from carbon bodies comprising a refractory lined open-topped metal and generally U-shaped shell furnace supported by structural support means, a column of carbon bodies within said furnace which are in end abutting relationship surrounded by particulate thermal insulation medium and held in place by and in electrical contact with two electrical power heads located at the ends of said furnace at least one of which is movable by means effective to apply pressure to said column, said power heads being adapted to conduct a current of electricity through said column of bodies to convert the carbon bodies to graphite by the Joule effect, and means to remove said thermal insulation medium by gravity dumping through the bottom of said furnace. ### Claim 2 (depends on 1) The apparatus of claim 1 wherein the means for dumping the insulation medium comprise valve means connecting with duct means leading to at least one hopper situated below the furnace. ### Claim 3 (depends on 1) The apparatus of claim 1 wherein conveying means are provided effective to move the furnace and structural support means therefor from a firing station to at least one other process station, and thence back to said firing station. ### Claim 4 (depends on 1) The apparatus of claim 1 wherein chute means are provided effective to connect the dumping means of the furnace with one or more hoppers. ### Claim 5 (depends on 1) The apparatus of claim 1 wherein the metal furnace comprises a plurality of shell assemblies, each of which is electrically isolated from each other and from ground. ### Claim 6 (depends on 5) The apparatus of claim 5 wherein each shell assembly is isolated from another adjacent shell assembly by a gap across which an insulating seal arrangement comprising a refractory lined metal member conforming in shape to the interior of the segment is installed provided with a flexible ceramic fiber seal gasket on the exterior of said member, the whole effective to maintain a sealing action against loss of particulate insulation and to act as an electrical isolator between said assemblies, while providing for relative movement between said adjacent segments. ### Claim 7 (depends on 5) The apparatus of claim 5 wherein each shell assembly is supported by flexible support means effective to allow relative differential thermal expansion and thermal movement of said assembly with respect to structural support frame. ### Claim 8 (depends on 5) The apparatus of claim 5 wherein each shell assembly is supported by flexible web support means effective to allow relative differential thermal expansion and thermal movement of said segment with respect to structural support frame comprising a plurality of I-beams placed vertically, one flange attached to said shell assembly and one flange attached to said structural support frame, the web flexing to allow said thermal movement. ### Claim 9 (depends on 5) The apparatus of claim 5 wherein each shell assembly is supported at its base by slidable support means effective to allow differential thermal expansion of said shell with respect to the structural support frame. ### Claim 10 (depends on 1) The apparatus of claim 1 wherein the particulate thermal insulation medium is a calcined petroleum coke recovered from the settling chamber in a rotary kiln installation and having a particle size range such that the particles pass a screen having 3.9 mesh/cm and are retained on a screen having 39 mesh/cm. ### Claim 11 (depends on 1) The apparatus of claim 1 wherein the metal furnace is lined with a high alumina castable refractory. ### Claim 12 (depends on 1) The apparatus of claim 1 wherein one or both electrical power heads are movable and pressurized by hydraulic cylinder means. ### Claim 13 (depends on 1) The apparatus of claim 1 wherein the gravity dumping means comprise a plurality of dump ports and gate valves in the bottom of the furnace. ### Claim 14 (depends on 1) The apparatus of claim 1 wherein the furnace is equipped to be reloaded with particulate insulation from an overhead hopper to place said insulation medium on both sides of the column of carbon bodies. ### Claim 15 An apparatus for the production of carbon bodies from baked cylindrical carbon bodies comprising an open-topped metal shell furnace having an approximately U-shaped cross-section and closed ends, mounted on structural support means, and lined with a cast-in-place refractory compound held in place by anchors, said furnace comprising a plurality of shell assemblies electrically isolated from each other by a gap sealed against loss of particulate insulation contained therein by a metal insert and gasket conforming to the shape of the interior of said assemblies and on its interior by said cast-in-place refractory compound, said assemblies being isolated from ground by means of insulation pads and anchoring brackets between said support means and ground, said structural support means comprising a metal support structure, said furnace being specially adapted to hold and maintain a series of said carbon bodies in aligned horizontal end-abutting relationship by hydrostatic pressure applied from movable power heads placed at each end of the furnace, to convert said bodies to graphite by the Joule effect with application of electrical current through said power heads, said bodies being held in position by placement within a bed of said particulate insulation medium within said furnace, said furnace and said support means being movable, means effective to connect said furnace power heads to a current source, means to transport said furnace and said structural support means to a plurality of working stations including a firing station, a cooling station and a dump and re-load station, means on said support means to maintain hydrostatic pressure while moving said furnace, gravity dumping means on said furnace comprising a plurality of dump ports and valves situated at the bottom and adapted to dump said insulation medium through chute means movable under said furnace, a plurality of receiving hoppers situated under said furnace to receive said insulation medium at said dump and re-load station, said hoppers adapted to be moved to a storage area and back to the said dump and re-load station, chute means connectible to said hoppers in the shape of an inverted Y, said chute means especially adapted to re-load said furnace with said insulation medium by traversing said furnace longitudinally while discharging said medium on each side of said carbon bodies, and insulation compactor means comprising a vibrator. ### Claim 16 A process for operating a furnace for converting amorphous carbon bodies to graphite wherein said bodies are held firmly in end-abutting relationship forming a horizontal column and while held in a bed of particulate insulation medium in a metal shell furnace by two electrical power heads at least one of which is movable and effective to apply hydrostatic pressure to said column while simultaneously conducting a current of electricity through said column until it reaches a peak temperature from 2500.degree. to 3000.degree. C., and cooling the column to 1500.degree. to 1700.degree. C. before removal of stock, and gravity dumping said insulation medium at the end of each operating cycle through the bottom of said furnace. ### Claim 17 (depends on 16) The process of claim 16 wherein the furnace is moved during the operating cycle from a firing station at which the carbon bodies are converted to graphite to a cooling station where said furnace is allowed to cool, said bodies cooling to approximately 1500.degree. to 1700.degree. C., then to a dump and re-load station at which the said bodies are removed from the furnace, the insulation medium is dumped into hoppers by gravity, the furnace is re-loaded with a new charge of said insulation medium and a new load of said carbon bodies, then moved to a firing station. ### Claim 18 (depends on 16) The process of claim 16 wherein the hot insulation medium when dumped, is at a weighted average temperature of from 700.degree. C. to 1100.degree. C., dumped by gravity from the furnace into at least one hopper, said hopper transferred to a position above said furnace and said medium reloaded into said furnace by gravity. ### Claim 19 (depends on 16) The process of claim 16 wherein the hot insulation medium is dumped at a weighted average temperature of from 700.degree. C. to 1100.degree. C., by gravity from a first furnace into at least one hopper, the furnace removed, said hopper moved to a storage area, then back to the dump and re-load station at which said insulation medium is recharged into a second said furnace. ### Claim 20 (depends on 16) The process of claim 16 wherein the hot insulation medium is dumped at a weighted average temperature of from 700.degree. to 1100.degree. C., by gravity from the furnace into one or more hoppers, then said hopper is removed from beneath said furnace to a position above said furnace, and said medium is used to reload said furnace with said medium for the next operating cycle of graphitization. ### Claim 21 (depends on 16) The process of claim 16 wherein the furnace is stationary, the insulation medium being dumped into at least one hopper beneath the furnace, said hopper being then removed to a position above said furnace and said insulation medium then recharged into said furnace. ### Claim 22 An apparatus for the production of graphite from carbon bodies comprising a plurality of refractory lined open-topped metal and generally U-shaped shell furnace segments supported by structural support means, a column of carbon bodies within said furnace which are in end abutting relationship surrounded by particulate thermal insulation medium and held in place by, and in electrical contact with two electrical power heads located at the ends of said furnace at least one of which is movable by means effective to apply pressure to said column, said power heads being adapted to conduct a current of electricity through said column of bodies to convert the carbon bodies to graphite by the Joule effect, each of said shell segments being electrically isolated from each other and from ground. ### Claim 23 An apparatus for the production of graphite from carbon bodies comprising a refractory lined open-topped metal and generally U-shaped shell furnace supported by structural support means, a column of carbon bodies within said furnace which are in end abutting relationship surrounded by particulate thermal insulation medium and in electrical contact with two electrical power heads located at the ends of said furnace at least one of which is movable by means effective to apply pressure to said column, said power heads being adapted to conduct a current of electricity through said column of bodies to convert the carbon bodies to graphite by the Joule effect, wherein the metal furnace comprises a plurality of shell segments, each of said segments being electrically isolated from each other and from ground, and wherein each shell segment is isolated from another adjacent shell segment by a gap across which an insulating seal arrangement comprising a refractory lined metal member conforming in shape to the interior of the segment is installed and provided with a flexible ceramic fiber seal gasket on the exterior of said member, the whole effective to maintain a sealing action against loss of particulate insulation and to act as an electrical isolator between said segments, while providing for relative movement between said adjacent shell segments.