# US 4,394,560 A · Covered electrode containing zirconium for shielded metal arc welding

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- Number: US 4,394,560 A
- Document ID: US4394560A
- Status: Granted
- Kind: A
- Application number: 06/310,283
- Filed: 1981-10-09
- Granted: 1983-07-19
- Earliest claimed: 1980-10-09
- Assignees: Nissan Motor Co., Ltd.
- Inventors: Katsuhiro Kishida; Yutaka Mekuchi; Sumio Hirao; Hirohiko Date
- Web page: https://patentgrep.com/patent/US4394560A

## CPC

- B23K 35/3602: {Carbonates, basic oxides or hydroxides}
- B23K 9/04: Welding for other purposes than joining, e.g. built-up welding
- B23K 35/3033: {Ni as the principal constituent}
- B23K 35/3066: {with Ni as next major constituent}
- B23K: SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM

## Abstract

A covered electrode for shielded metal arc welding, which is particularly suitable for use in build-up welding operation for the purpose of providing hard surface to a metal die. The covered electrode comprises such amounts of Ni, Si, B, Nb, C and Zr as essential alloying elements that the deposited metal contains at least 40% of Ni, 3-8% of Si, 0.1-0.5% of B, 0.3-2.0% of Nb, 0.2-1.5% of C and 0.01-0.20% of Zr, all by weight. In a preferred form, either Ni wire or Fe--Ni wire is used as the core wire, and the covering contains necessary amounts of all the essential alloying elements except Ni. The deposited metal has high wear resistance and good antifrictional property, and the presence of Zr is highly effective for preventing the occurrence of weld cracks.

## Claims

### Claim 1

A covered electrode for shielded metal arc welding, the electrode consisting of a core wire and a covering and comprising such amounts of Ni, Si, B, Nb, C and Zr as essential alloying elements that deposited metal given by the covered electrode contains at least 40% by weight of Ni, 3 to 8% by weight of Si, 0.1 to 0.5% by weight of B, 0.3 to 2.0% by weight of Nb, 0.2 to 1.5% by weight of C and 0.01 to 0.20% by weight of Zr.

### Claim 2 (depends on 1)

A covered electrode according to claim 1, wherein the balance of said deposited metal consists of Fe and inevitable impurities.

### Claim 3 (depends on 1)

A covered electrode according to claim 1, wherein said core wire contains at least 95% by weight of Ni, said covering comprising 5 to 13% by weight of Si, 1 to 5% by weight of B, 0.4 to 4% by weight of Nb, 1 to 6% by weight of C and 0.1 to 2.0% by weight of Zr.

### Claim 4 (depends on 3)

A covered electrode according to claim 3, wherein said covering further comprises Fe as an additional alloying element.

### Claim 5 (depends on 1)

A covered electrode according to claim 1, wherein said core wire consists essentially of 50 to 60% by weight of Ni and the balance of Fe, said covering comprising 5 to 13% by weight of Si, 1 to 5% by weight of B, 0.4 to 4% by weight of Nb, 1 to 6% by weight of C and 0.1 to 2.0% by weight of Zr.

### Claim 6 (depends on 5)

A covered electrode according to claim 5, wherein said covering further comprises Fe as an additional alloying element.

### Claim 7 (depends on 3, 5)

A covered electrode according to claim 3 or 5, wherein said covering further comprises at least one of arc-stabilizing agent, gas-generating agent, slag-forming agent and lubricating agent.

### Claim 8 (depends on 7)

A covered electrode according to claim 7, wherein said covering comprises calcium carbonate, barium carbonate and fluorite.

### Claim 9 (depends on 3, 5)

A covered electrode according to claim 3 or 5, wherein the weight ratio of said covering to said core wire is in the range from about 20:100 to about 50:100.
