# US 4,394,480 A · Low shrinkage unsaturated polyester resin composition > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,394,480 A - Document ID: US4394480A - Status: Granted - Kind: A - Application number: 06/361,168 - Filed: 1982-03-24 - Granted: 1983-07-19 - Earliest claimed: 1981-04-01 - Assignees: Nippon Oil and Fats Co., Ltd. - Inventors: Norihisa Ujikawa; Kyosuke Fukushi - Web page: https://patentgrep.com/patent/US4394480A ## CPC - C08L 67/06: Unsaturated polyesters - C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06) ## Abstract An unsaturated polyester resin composition comprising an unsaturated polyester resin, a polymerizable monomer and a mixture of block copolymers having acid groups prepared by first copolymerizing in a first copolymerization reaction a polymeric peroxide with a monomer A or B, or with an unsaturated acid together with monomer A or B, thereby obtaining a copolymer having peroxy bonds in the molecule thereof, which copolymer is further copolymerized in the second copolymerization reaction with each of monomers A or B or the unsaturated acid which were excluded in the first copolymerization reaction to give the block copolymer mixture, which composition shows no segregation of the low shrinkage agent on thickening by a thickener and the said composition gives cured moldings of reduced shrinkage which are excellent in many characteristics. Monomer A: a vinyl acetate or a mixture of vinyl acetate and one or more monomers which are copolymerizable with vinyl acetate Monomer B: styrene series monomers, unsaturated organic acids, anhydrides, or acid esters, or mixtures thereof ## Claims ### Claim 1 A low-shrinkage unsaturated polyester resin composition comprising (a) from 20 to 70% by weight of unsaturated polyester resin, (b) from 20 to 70% by weight of a first polymerizable monomer and (c) from 1 to 20% by weight of a block copolymer mixture having acid groups, said block copolymer mixture having been prepared by first copolymerizing (i) a polymeric peroxide having the formula ##STR10## wherein R.sub.1 is alkylene or substituted alkylene having 1 to 18 carbon atoms, cycloalkylene or substituted cycloalkylene having 3 to 15 carbon atoms, phenylene or substituted phenylene; R.sub.2 is alkylene or substituted alkylene having 2 to 10 carbons atoms, ##STR11## wherein R.sub.3 is hydrogen or methyl, R.sub.4 is alkylene or substituted alkylene having 2 to 10 carbon atoms and m is an integer of 1 to 13, ##STR12## and n is an integer of 2 to 20, with (ii) a second monomer component selected from the group consisting of monomer A, monomer B, mixture of monomer A and an unsaturated organic acid, and mixture of monomer B and an unsaturated organic acid, wherein monomer A consists of 70 to 100% by weight of vinyl acetate and up to 30% by weight of fourth monomer copolymerizable with vinyl acetate, and monomer B consists of 0 to 100% by weight of one or more styrene series monomers and 0 to 100% by weight of one or more unsaturated organic acid esters, whereby to obtain a copolymer having peroxy bonds in the molecule, and then block copolymerizing said copolymer having peroxy bonds in the molecule with a third monomer component which is selected from the same group as, but is different from, the said second monomer component that was used in the first copolymerization step, with the provisos that one of said second and third monomer components is a mixture of one of monomer A or monomer B and said unsaturated organic acid and the other of said second and third monomer components is the other of monomer A or monomer B. ### Claim 2 (depends on 1) A composition as claimed in claim 1 wherein the acid value of said mixture of block copolymers having acid groups is 0.5 to 20 and said monomer A is used in an amount of 90 to 10% by weight based on the total amount of said monomers A and B. ### Claim 3 (depends on 1, 2) A composition as claimed in claim 1 or claim 2 in which said first polymerizable monomer is selected from the group consisting of styrene, vinyl toluene, .alpha.-methyl styrene, t-butyl styrene, chlorostyrene, diallyl phthalate, vinyl acetate, acrylic acid esters and methacrylic acid esters; said fourth monomer copolymerizable with vinyl acetate is selected from the group consisting of ethylene, vinyl chloride, vinylidene chloride, vinyl esters and allyl esters; said styrene series monomer is selected from the group consisting of styrene, vinyl toluene, .alpha.-methyl styrene, t-butyl styrene and chlorostyrene; said unsaturated organic acid ester is selected from the group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propylmethacrylate, butyl methacrylate, hexyl methacrylate, 2-ethyl butyl methacrylate, octyl methacrylate, lauryl methacrylate and 2-ethylhexyl methacrylate; and said unsaturated organic acid is selected from the group consisting of acrylic acid, methacrylic acid, maleic anhydride, maleic acid hemiesters and itaconic acid. ### Claim 4 (depends on 1) A composition as claimed in claim 1, wherein said second monomer component consists of monomer A and said third monomer component consists of a mixture of said unsaturated organic acid and monomer B. ### Claim 5 (depends on 1) A composition as claimed in claim 1, wherein said second monomer component consists of a mixture of monomer A and said unsaturated organic acid and said third monomer component consists of monomer B. ### Claim 6 (depends on 1) A composition as claimed in claim 1, wherein said second monomer component consists of monomer B and said third monomer component consists of a mixture of said unsaturated organic acid and monomer A. ### Claim 7 (depends on 1) A composition as claimed in claim 1, wherein said second monomer component consists of a mixture of monomer B and said unsaturated organic acid and said third monomer component consists of monomer A. ### Claim 8 (depends on 1) A composition as claimed in claim 1, wherein said polymeric peroxide is used in an amount of from 0.1 to 10 parts by weight per 100 parts by weight of the monomer A or monomer B contained in said second monomer component. ### Claim 9 (depends on 8) A composition as claimed in claim 8, wherein said first copolymerization is conducted at a temperature in the range of 40.degree. C. to 90.degree. C. for a reaction time of 2 to 15 hours. ### Claim 10 (depends on 1) A composition as claimed in claim 1, wherein said mixture of block copolymers having acid groups is dispersed in said polymerizable monomer (b), and said dispersion is subsequently added to said unsaturated polyester resin (a) to form said composition. ### Claim 11 A low-shrinkage unsaturated polyester resin composition comprising (a) from 20 to 70% by weight of unsaturated polyester resin, (b) from 20 to 70% by weight of a first polymerizable monomer and (c) from 1 to 20% by weight of a block copolymer mixture having acid groups and having an acid value of from 0.5 to 20, said block copolymer mixture having been prepared by first copolymerizing, at a reaction temperature of from 40.degree. to 90.degree. C. and for a reaction time of from 2 to 15 hours, (i) a polymeric peroxide having the formula ##STR13## wherein R.sub.1 is alkylene or substituted alkylene having 1 to 18 carbon atoms, cycloalkylene or substituted cycloalkylene having 3 to 15 carbon atoms, phenylene or substituted phenylene; R.sub.2 is alkylene or substituted alkylene having 2 to 10 carbon atoms, ##STR14## wherein R.sub.3 is hydrogen or methyl, R.sub.4 is alkylene or substituted alkylene having 2 to 10 carbon atoms and m is an integer of 1 to 13, ##STR15## and n is an integer of 2 to 20, with (ii) a second monomer component selected from the group consisting of monomer A, monomer B, mixture of monomer A and an unsaturated organic acid, and mixture of monomer B and an unsaturated organic acid, wherein monomer A consists of 70 to 100% by weight of vinyl acetate and up to 30% by weight of fourth monomer copolymerizable with vinyl acetate, and monomer B consists of 0 to 100% by weight of one or more styrene series monomers and 0 to 100% by weight of one or more unsaturated organic acid esters, the amount of said polymeric peroxide being from 0.1 to 10 parts by weight per 100 parts by weight of the monomer A or monomer B contained in said second monomer component, whereby to obtain a copolymer having peroxy bonds in the molecule, and then block copolymerizing said copolymer having peroxy bonds in the molecule with a third monomer component which is selected from the same group as, but is different from, the said second monomer component that was used in the first copolymerization step, with the provisos that one of said second and third monomer components is a mixture of one of monomer A or monomer B and said unsaturated organic acid, the other of said second and third monomer components is the other of monomer A or monomer B, and the amount of monomer A is from 10 to 90% by weight based on the sum of the amounts of monomer A plus monomer B. ### Claim 12 (depends on 11) A composition as claimed in claim 11 in which said first polymerizable monomer is selected from the group consisting of styrene, vinyl toluene, .alpha.-methyl styrene, t-butyl styrene, chlorostyrene, diallyl phthalate, vinyl acetate, acrylic acid esters and methacrylic acid esters; said fourth monomer copolymerizable with vinyl acetate is selected from the group consisting of ethylene, vinyl chloride, vinylidene chloride, vinyl esters and allyl esters; said styrene series monomer is selected from the group consisting of styrene, vinyl toluene, .alpha.-methyl styrene, t-butyl styrene and chlorostyrene; said unsaturated organic acid ester is selected from the group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propylmethacrylate, butyl methacrylate, hexyl methacrylate, 2-ethyl butyl methacrylate, octyl methacrylate, lauryl methacrylate and 2-ethylhexyl methacrylate; and said unsaturated organic acid is selected from the group consisting of acrylic acid, methacrylic acid, maleic anhydride, maleic acid hemiesters and itaconic acid. ### Claim 13 (depends on 11) A composition as claimed in claim 11, wherein said second monomer component consists of monomer A and said third monomer component consists of a mixture of said unsaturated organic acid and monomer B. ### Claim 14 (depends on 11) A composition as claimed in claim 11, wherein said second monomer component consists of a mixture of monomer A and said unsaturated organic acid and said third monomer component consists of monomer B. ### Claim 15 (depends on 11) A composition as claimed in claim 11, wherein said second monomer component consists of monomer B and said third monomer component consists of a mixture of said unsaturated organic acid and monomer A. ### Claim 16 (depends on 11) A composition as claimed in claim 11, wherein said second monomer component consists of a mixture of monomer B and said unsaturated organic acid and said third monomer component consists of monomer A.