# US 4,394,474 A · Product and process for reducing block and increasing slip of linear low density ethylene copolymer films > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,394,474 A - Document ID: US4394474A - Status: Granted - Kind: A - Application number: 06/256,268 - Filed: 1981-04-21 - Granted: 1983-07-19 - Earliest claimed: 1981-04-21 - Assignees: The Dow Chemical Company - Inventors: Osborne K. McKinney; David P. Flores - Web page: https://patentgrep.com/patent/US4394474A ## CPC - C08K 3/36: Silica - B29C 48/022: {characterised by the choice of material} - B29C 48/08: flexible, e.g. films - C08K 5/20: Carboxylic acid amides - B29K 2105/16: Fillers - C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09) - B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00) - B29K: INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS ## Abstract Extrusion-cast films of high molecular weight, linear low density ethylene copolymers which inherently have high block and low slip characteristics are compounded with a minor amount of a secondary fatty acid amide and a finely-divided natural inorganic, e.g., silica, before being extrusion-cast as a thin film, the additives serving to substantially reduce the block and increase the slip characteristics of the film. ## Claims ### Claim 1 A process for reducing block, and increasing slip, of extrusion-cast films of linear low density ethylene copolymers which inherently exhibit high block and low slip, said process comprising incorporating into the said copolymer, prior to extrusion-casting into films, an effective amount in the range of about 0.05 to about 1.5 weight percent of at least one secondary fatty acid amide and about 0.02 to about 2 weight percent of finely-divided natural mineral, and extrusion-casting the mixture into a thin film, wherein the linear low density ethylene copolymer comprises ethylene copolymerized with a sufficient amount of at least one alpha, beta-ethylenically unsaturated alkene having from 3 to 12 carbons, to provide a copolymer having a density in the range of about 0.90 to about 0.94 gms. cc, said copolymers having a melt index in the range of about 0.1 gm./10 min. as measured by ASTM-D-1238(E) to about 20 gms./10 min. as measured by ASTM-D-1238(D). ### Claim 2 (depends on 1) The process of claim 1 wherein the incorporating of the amide and the mineral into the said copolymer comprises the use of a masterbatch of an ethylene polymer with amide and mineral mixed therein and the blending of said masterbatch with said copolymer to attain the desired amount of amide and mineral in the film produced therefrom. ### Claim 3 (depends on 1) The process of claim 1 wherein the alkene is at least one selected from the group consisting of propylene, butene, isobutene, pentene, isopentene, hexene, isohexene, heptene, isoheptene, octene, isooctene, nonene, isononene, decene, and isodecene. ### Claim 4 (depends on 3) The process of claim 3 wherein the alkene is at least one of octene, heptene, hexene, pentene, butene, and propylene. ### Claim 5 (depends on 1) The process of claim 1 wherein the secondary fatty acid amide conforms essentially to the empirical formula R--CO--NH--R', where R and R' each, independently, are saturated or unsaturated alkyl groups having 10 to 26 carbon atoms. ### Claim 6 (depends on 1) The process of claim 1 wherein the finely-divided natural inorganic mineral comprises silica and/or diatomaceous earth having a surface area of about 0.7 to about 100 m.sup.2 /gm., an oil absorption value of about 21 to about 175 lbs. oil per 100 lbs. inorganic, and an average particle size of about 0.02 to about 40 microns. ### Claim 7 (depends on 1) The process of claim 1 wherein the secondary fatty acid amie conforms essentially to the empirical formula R--CO--NH--R', where R and R' represent, independently, moieties selected from the group of fatty acids comprising erucyl, linoleyl, linolenyl, arachidonyl, palmitoleyl, elaidyl, vaccenyl, behenyl, arachidyl, stearyl, palmityl, lignoceryl, and oleyl. ### Claim 8 (depends on 1) The process of claim 1 wherein the secondary fatty acid amide is at least one of stearyl erucylamide, erucyl erucylamide, oleyl palmitamide, stearyl stearamide, and oleyl erucylamide. ### Claim 9 (depends on 1) The process of claim 1 wherein the finely-divided natural mineral comprises talc. ### Claim 10 (depends on 1) The process of claim 1 wherein the finely-divided natural mineral comprises limestone. ### Claim 11 (depends on 1) The process of claim 1 wherein the finely-divided natural mineral comprises clay. ### Claim 12 (depends on 1) The film produced by the process of claim 1. ### Claim 13 (depends on 1) The film produced by the process of claim 1, having an average thickness in the range of about 0.3 to about 8 mils. ### Claim 14 A process for reducing block, and increasing slip, of extrusion-cast films of linear low density ethylene copolymers which inherently exhibit high block and low slip, said process comprising incorporating into the said copolymer, prior to extrusion-casting into films, an effective amount, in the range of about 0.05 to about 1.5 weight percent, of at least one secondary fatty acid amide and about 0.02 to about 2 weight percent of finely-divided natural mineral, and extrusion-casting the mixture into a thin film, wherein said copolymer comprises ethylene copolymerized with a sufficient amount of at least one alpha, beta-ethylenically unsaturated alkene, having from 4 to 8 carbon atoms, to provide a copolymer having a density in the range of about 0.90 to about 0.94 gms/cc, wherein said secondary fatty acid amide comprises at least one conforming essentially to the empirical formula R--CO--NH--R', where R and R' represent, independently, moieties selected from the group of fatty acids comprising erucyl, linoleyl, linolenyl, arachidonyl, palmitoleyl, elaidyl, vaccenyl, behenyl, arachidyl, stearyl, palmityl, lignoceryl, and oleyl, and wherein said finely-divided natural mineral comprises at least one of the group comprising silica, diatomaceous earth, talc, limestone, and clay.