# US 4,394,239 A · Electro-chemical sensor for the detection of reducing gases, in particular carbon monoxide, hydrazine and hydrogen in air

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- Number: US 4,394,239 A
- Document ID: US4394239A
- Status: Granted
- Kind: A
- Application number: 06/295,277
- Filed: 1981-08-24
- Granted: 1983-07-19
- Earliest claimed: 1980-09-09
- Assignees: Bayer Aktiengesellschaft
- Inventors: Dieter Kitzelmann; Jacques Deprez
- Web page: https://patentgrep.com/patent/US4394239A

## CPC

- G01N 27/4045: {for gases other than oxygen}
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

A sensor consists of a catalytically active measuring electrode communicating with a non-polarizable atmospheric oxygen electrode by way of an aqueous acid electrolyte. The electrolyte used is an aqueous gelatinous polymeric adhesive in which ionogenic substances are dissolved. Due to the adhesive properties of the electrolyte, a 3-phase boundary of air-catalyst-electrolyte is formed at the transition to the measuring electrode and substantially determines the measuring process.

## Claims

### Claim 1

In an electro-chemical sensor for the measurement of carbon monoxide, hydrogen or hydrazine in ambient air, comprising a catalyst containing measuring electrode exposed to ambient air and communicating through an aqueous acid electrolyte with a non-polarizable counter electrode, the improvement comprising:
(a) a body of an aqueous hygroscopic polymer gel in which ionogenic substances are dissolved, the gel body having sticky surfaces,
(b) the measuring electrode comprising a porous sheet-like matrix, coated with catalyst particles,
(c) the matrix being firmly anchored at the surface of the polymer gel in a self-supporting manner and the catalyst particles being embedded with part of their surfaces in the gel and with the remaining surface portions protruding from the gel.

### Claim 2 (depends on 1)

The sensor according to claim 1, wherein the matrix consists of a meshed electrically conductive grid, which is applied to the gel electrolyte by pressure.

### Claim 3 (depends on 1, 2)

The sensor according to claim 1 or 2, for the measurement of carbon monoxide and hydrogen, wherein the matrix and the counter electrode consists of a graphite fleece and the catalyst is platinum.

### Claim 4 (depends on 1, 2)

The sensor according to claim 1 or 2, for the measurement of hydrazine, wherein the matrix consists of a carbon fleece coated with gold and the counter electrode consists of a carbon fleece coated with platinum black.