# US 4,393,938 A · Treating wells with ion-exchange-precipitated scale inhibitor

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- Number: US 4,393,938 A
- Document ID: US4393938A
- Status: Granted
- Kind: A
- Application number: 06/252,566
- Filed: 1981-04-09
- Granted: 1983-07-19
- Earliest claimed: 1981-04-09
- Assignees: Shell Oil Company
- Inventors: Jimmie B. Lawson; Edwin A. Richardson
- Web page: https://patentgrep.com/patent/US4393938A

## CPC

- C09K 8/528: inorganic depositions, e.g. sulfates or carbonates
- Y10S 166/902: for inhibiting corrosion or coating
- Y10S 507/927: Well cleaning fluid
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

The scaling of a production well in a clay-containing reservoir is inhibited by injecting a scale inhibitor dissolved in an aqueous solution having a pH and ratio of monovalent-to-multivalent cations such that multivalent cation salts of the inhibitor are precipitated as a result of a cation-exchange within the reservoir.

## Claims

### Claim 1

A well treating process for inhibiting scaling by fluid which is produced from a clay-containing subterranean reservoir which tends to exchange cations with those contained within an injected aqueous solution, comprising:
dissolving within an aqueous solution of relatively neutral pH (a) at least one nitrogen-containing phosphonate scale inhibiting compound which contains scale-inhibiting anions that form multivalent cation salts which are only slightly soluble at the pH of the solution and (b) enough of at least one substantially neutral salt to both provide a ratio of monovalent-to-multivalent cations of at least about 100 and to substantially saturate the solution with respect to multivalent cation salts of the scale-inhibiting anions;
injecting said solution into a portion of said reservoir which (a) has a significant tendency to exchange cations with those contained within an injected aqueous solution and (b) contains a significant proportion of adsorbed multivalent cations; and,
controlling the rate at which said solution is injected so that at least some portions of that solution remain relatively near the well long enough to induce a significant precipitation of scale inhibitor salt due to the ion-exchange-induced addition of multivalent cations to the solution.

### Claim 2 (depends on 1)

The process of claim 1 in which the reservoir is pretreated, to the extent required in order to ensure the presence of a significant proportion of multivalent cations on the ion-exchange sites of the reservoir rock, by injecting a saline aqueous liquid containing a significant preponderance of multivalent cations.

### Claim 3 (depends on 1, 2)

The process of claim 1 or 2 in which the reservoir rock has a clay content of at least about 3% by weight.

### Claim 4 (depends on 1, 2)

The process of claim 1 or 2 in which the ion-exchange capacity of the reservoir rock is relatively low and the scale inhibitor solution is injected or displaced in a manner causing it to contact and undergo an ion-exchange with the reservoir rocks within a relatively large zone around the well.

### Claim 5 (depends on 1, 2)

The process of claim 1 or 2 in which the scale-inhibiting anions are members of the group consisting of phosphate and phosphonate scale-inhibiting anions.