# US 4,393,934 A · Conditioning a coal seam prior to in-situ gasification

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- Number: US 4,393,934 A
- Document ID: US4393934A
- Status: Granted
- Kind: A
- Application number: 06/296,039
- Filed: 1981-08-25
- Granted: 1983-07-19
- Earliest claimed: 1981-08-25
- Assignees: Mobil Oil Corporation
- Inventors: Joseph G. Savins; James C. Melrose
- Web page: https://patentgrep.com/patent/US4393934A

## CPC

- E21B 43/295: Gasification of minerals, e.g. for producing mixtures of combustible gases (E21B43/243 takes precedence)
- E21B 43/243: Combustion in situ
- E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS

## Abstract

A method for conditioning a coal seam prior to in-situ gasification to increase the permeability of the coal seam to the flow of combustion-supporting gas therethrough and thus increase the efficiency of gasification wherein a wettability alteration fluid is injected into the coal seam via an injection well and fluids including the wettability alteration fluid are recovered from a spaced apart production well. Injection of the wettability alteration fluid is continued into the coal seam until the permeability thereof to the flow of the combustion-supporting gas therethrough has increased to a maximum extent. Suitable wettability alteration fluids include carbon dioxide, volatile amines, aqueous solutions containing phosphates, phenols, flue gas and alcohols, and mixtures thereof.

## Claims

### Claim 1

A method for conditioning a subsurface wet coal seam prior to in-situ gasification wherein combustion of a portion of the coal in said seam has been initiated and is maintained by injection of a combustion-supporting gas into said seam through an injection well whereby there results an in-situ combustion front containing hot combustion gases which move toward a spaced production well and movement of this front displaces the hot combustion gases into the production well for recovery, the improvement comprising injecting into said coal seam via said injection well a wettability alteration fluid, said wettability alteration fluid capable of decreasing the water content of said coal and altering the wettability of said coal thereby increasing the permeability thereof to the flow of gas therethrough; recovering fluids including the wettability alteration fluid from said coal seam via said production well, and continuing to inject said wettability alteration fluid into said coal seam until the permeability thereof to the flow of said combustion-supporting gas therethrough has increased to a maximum extent.

### Claim 2 (depends on 1)

A method as defined in claim 1, wherein said wettability alteration fluid is a member of the group consisting of carbon dioxide, volatile amines, aqueous solutions containing phosphates, phenols, flue gas and alcohols, and combinations thereof.

### Claim 3 (depends on 2)

A method as defined in claim 2 wherein said member of said group is carbon dioxide.

### Claim 4 (depends on 2)

A method as defined in claim 2 wherein said member of said group is propylamine.

### Claim 5 (depends on 2)

A method as defined in claim 2 wherein said member of said group is ethanolamine.

### Claim 6 (depends on 2)

A method as defined in claim 2 wherein said member of said group is methylamine.

### Claim 7 (depends on 2)

A method as defined in claim 2 wherein said member of said group is an aqueous solution containing ammonium phosphate.

### Claim 8 (depends on 2)

A method as defined in claim 2 wherein said member of said group is methanol.

### Claim 9 (depends on 2)

A method as defined in claim 2 wherein said member of said group is an ethanol.

### Claim 10 (depends on 2)

A method as defined in claim 2 wherein said member of said group is propanol.