# US 4,393,034 A · Energy efficient process for the production of carbon black

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- Number: US 4,393,034 A
- Document ID: US4393034A
- Status: Granted
- Kind: A
- Application number: 06/199,173
- Filed: 1980-10-22
- Granted: 1983-07-12
- Earliest claimed: 1980-10-22
- Assignees: Ashland Oil, Inc.
- Inventors: Norman L. Smith
- Web page: https://patentgrep.com/patent/US4393034A

## CPC

- C09C 1/487: {Separation; Recovery (quenching C09C1/50 - C09C1/54)}
- C09C 1/50: Furnace black {; Preparation thereof (separation or recovery C09C1/487)}
- B01J 19/00: Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- Y02P 20/10: Process efficiency
- C09C: TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES (treatment of materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone C04B14/00, C04B18/00, C04B20/00); PREPARATION OF CARBON BLACK {; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS}
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

Method for the production of carbon black by an oil furnace process whereby an aromatic feedstock is pyrolytically dissociated into carbon black by contact with a turbulent mixture of combustion gases generated in burning a gaseous fuel in the presence of a stoichiometrical excess of oxygen. The gaseous fuel feed to the process being recycled off-gases associated with the pyrolysis reaction effluent from which the condensible gas content thereof is removed prior to recycling.

## Claims

### Claim 1

A method of operating an elongated, generally cylindrical reactor having an upstream and downstream end for the production of carbon black by the furnace process wherein the combustible gases generated a pyrolytically dissociating a carbon black producing feedstock are cyclically utilized as the fuel for effecting the dissociation reaction, which comprises:
introducing a hydrocarbon fuel together with a 25-75% stoichiometrical excess of oxidant gas containing at least 70 volumetric percent oxygen into the upstream end of said reactor and substantially completely burning the fuel to provide a turbulent mixture of combustion gases;
injecting a normally liquid aromatic-rich hydrocarbon feedstock into said turbulent mixture of combustion gases and burning said feedstock to the extent provided by the presence of free oxygen in the combustion gases while essentially simultaneously effecting the pyrolytical dissociation of the unoxidized portion of the feedstock to generate a carbon black aerosol;
quenching the pyrolysis reaction and discharging the aerosol from the downstream end of the reactor whence the carbon black is recovered by filtration;
continuously maintaining the production of carbon black in the manner above defined until steady state conditions are attained; and
thereupon recycling a portion of the filtered reactor gaseous effluent substantially free of condensible gases to the reactor in lieu of the hydrocarbon fuel utilized in attaining steady state conditions, said effluent being introduced at a rate adapted to provide a combustion temperature of about that associated with the burning of the initially introduced hydrocarbon fuel while continuing to introduce a 25-75% stoichiometrical excess of the oxidant gas for burning said filtered gaseous effluent.

### Claim 2 (depends on 1)

The method in accordance with claim 1 in which the residual portion of said filtered reactor gaseous effluent is introduced as the fuel in at least one other carbon black furnace along with a stoichiometrical excess of air and combusted therein to provide a turbulent mixture of resultant combustion gases into which a normally liquid carbon black producing feedstock is injected for effecting the dissociation thereof.