# US 4,392,974 A · Low-phosphate detergent builder salt mixture and process of washing > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,392,974 A - Document ID: US4392974A - Status: Granted - Kind: A - Application number: 06/097,135 - Filed: 1979-11-26 - Granted: 1983-07-12 - Earliest claimed: 1978-12-02 - Assignees: Henkel Kommanditgesellschaft auf Aktien - Inventors: Klaus Hachmann - Web page: https://patentgrep.com/patent/US4392974A ## CPC - C11D 3/2089: {Ether acids-salts thereof} - C11D 3/06: Phosphates, including polyphosphates - C11D 3/128: {Aluminium silicates, e.g. zeolites (C11D3/1253 takes precedence)} - C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL ## Abstract A low-phosphate detergent builder salt mixture consisting of (a) from 45% to 75% by weight of a water-insoluble, finely-divided, synthetic, crystalline alkali metal aluminosilicate with a calcium binding power of from 50 to 200 mg CaO/gm at 22.degree. C., (b) from 15% to 40% by weight of sodium or potassium carboxymethyloxysuccinate, and (c) from 5% to 15% by weight of sodium or potassium tripolyphosphate; as well as use of the same in detergents in amounts of 25% to 60% by weight with the proviso that the total tripolyphosphate content in the detergent does not exceed 5% by weight. ## Claims ### Claim 1 A builder salt mixture for washing, rinsing and cleansing agent compositions consisting essentially of: (a) from 50% to 75% by weight of at least one water-insoluble, finely-divided, synthetic, crystalline alkali metal aluminosilicate containing at least some combined water and having primary particles in the size range of from 50.mu. to 0.01.mu. and a calcium binding power of from 50 to 200 mg CaO/gm of anhydrous active substance when measured at 22.degree. C. by the Calcium Binding Power Test Method set out in the specification and the formula on the anhydrous basis 0.7-1.5 Me.sub.2 O.Al.sub.2 O.sub.3.1.3-4.0 SiO.sub.2 where Me is an alkali metal, (b) from 20% to 35% by weight of at least one carboxymethyloxysuccinate selected from the group consisting of sodium carboxymethyloxysuccinate and potassium carboxymethyloxysuccinate, and (c) from 8% to 15% by weight, based on the anhydrous salt, of a tripolyphosphate selected from the group consisting of sodium tripolyphosphate and potassium tripolyphosphate. ### Claim 2 (depends on 1) The builder salt mixture of claim 1 wherein the amount of the components in % by weight is the following: component (a), 52% to 70% by weight component (b), 20% to 35% by weight component (c), 8% to 12% by weight ### Claim 3 A washing, rinsing and cleansing agent composition comprising builder salts, tensides, wash alkalies, and optionally other conventional additives for washing, rinsing and cleansing agent compositions wherein (A) said builder salts are present in an amount of from 25% to 60% by weight and consist of a builder salt mixture consisting essentially of: (a) from 50% to 75% by weight of at least one water-insoluble, finely-divided, synthetic, crystalline alkali metal aluminosilicate containing at least some combined water and having primary particles in the size range of from 50.mu. to 0.01.mu. and a calcium binding power of from 50 to 200 mg CaO/gm of anhydrous active substance when measured at 22.degree. C. by the Calcium Binding Power Test Method set out in the specification and the formula on the anhydrous basis 0.7-1.5 Me.sub.2 O.Al.sub.2 O.sub.3.1.3-4.0 SiO.sub.2 where Me is an alkali metal, (b) from 20% to 35% by weight of at least one carboxymethyloxysuccinate selected from the group consisting of sodium carboxymethyloxysuccinate and potassium carboxymethyloxysuccinate, and (c) from 8% to 15% by weight, based on the anhydorus salt, of a tripolyphosphate selected from the group consisting of sodium tripolyphosphate and potassium tripolyphosphate, (B) said tensides are present in an amount of 5% to 20%, (C) said wash alkalies are present in an amount of from 0 to 8% by weight of sodium silicate and from 0 to 10% by weight of other wash alkalies, (D) said other conventional additives include from 0 to 30% by weight of sodium perborate-tetrahydrate, from 0 to 1% of organic nitrogen containing or phosphorus-containing sequestering agent and from 1% to 30% by weight of soil suspension agents, optical brighteners, enzymes, biocides, fabric softeners, dyes and perfumes, sodium sulfate and water, with the proviso that the amount of said tripolyphosphate component (c) in said washing, rinsing and cleansing agent composition does not exceed 5% by weight. ### Claim 4 (depends on 3) The washing, rinsing and cleansing agent composition of claim 3 wherein the amount of the components in said builder salt is the following: component (a), from 52% to 70% by weight, component (b), from 20% to 35% by weight, component (c), from 8% to 12% by weight. ### Claim 5 (depends on 3) The washing, rinsing and cleansing agent composition of claim 3 wherein said builder salts are present in an amount of from 30% to 50% by weight. ### Claim 6 (depends on 1) The builder salt mixture of claim 1 wherein all three components are in the form of the sodium salt and said aluminosilicate has a calcium binding power of from 100 to 200 mg CaO/gm of anhydrous active substance. ### Claim 7 (depends on 3) The washing, rinsing and cleansing agent composition of claim 3 wherein, in said, builder salt mixture, all three components are in the form of the sodium salt and said aluminosilicate has a calcium binding power from 100 to 200 mg CaO/gm of anhydrous active substance. ### Claim 8 (depends on 2) The builder salt mixture of claim 2 wherein all three components are in the form of the sodium salt and said aluminosilicate has a calcium binding power of from 100 to 200 mg CaO/gm of anhydrous active substance. ### Claim 9 (depends on 3) The washing, rinsing and cleansing agent composition of claim 3 wherein, in said builder salt mixture, the amount of component (b) is from 8% to 15% by weight of said total washing, rinsing and cleansing agent composition. ### Claim 10 (depends on 3) The washing, rinsing and cleansing agent composition of claim 3 wherein said builder salts are present in an amount of from 30% to 50% by weight, said tensides are present in an amount of from 7% to 15% by weight, said sodium silicate is present in an amount of from 2% to 5% by weight, and said sodium perborate-tetrahydrate is present in an amount of from 15% to 25% by weight.