# US 4,392,931 A · Reactive deposition method and apparatus > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,392,931 A - Document ID: US4392931A - Status: Granted - Kind: A - Application number: 06/249,402 - Filed: 1981-03-31 - Granted: 1983-07-12 - Earliest claimed: 1981-03-31 - Assignees: Northern Telecom Limited - Inventors: Shmuel Maniv; William D. Westwood - Web page: https://patentgrep.com/patent/US4392931A ## CPC - C23C 14/345: {using substrate bias} - C23C 14/0068: {characterised by means for confinement of gases or sputtered material, e.g. screens, baffles} - C23C 14/228: {Gas flow assisted PVD deposition} - C23C 14/34: Sputtering - C23C 14/505: {for rotation of the substrates} - H01J 37/34: operating with cathodic sputtering (H01J37/36 takes precedence {; methods of cathodic sputtering C23C14/34}) - H01J 37/3447: {Collimators, shutters, apertures} - C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04) - H01J: ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS (spark-gaps H01T; electric arc lamps H05B31/00; particle accelerators H05H) ## Abstract Using a sputter deposition system to reactively deposit a material such as an oxide, it is relatively easy to achieve either an oxygen-doped film with appreciable metallic content or an oxide film. However it is difficult with known systems to obtain an intermediate film having an accurately controlled resistivity, transparency, and composition, such films being of much use in semiconductor applications, in displays and in photovoltaic cells. It is now proposed that an apertured barrier be used to accurately fix the flow rate of target material to the substrate and in addition, that reactive gas flow be regulated and directed only to the immediate vicinity of the substrate. In this way the composition of the film can be accurately fixed. By establishing an r.f. field at the substrate, increased dissociation of the reactive gas can be achieved to render the gas more reactive and so enhance certain film properties such as transparency. ## Claims ### Claim 1 Thin film deposition apparatus for reactively sputter depositing a film, the apparatus comprising a substrate, a target, means for directing sputtered target material towards the substrate, means for directing reactive gas at a present flow rate to the substrate, an apertured barrier containing a series of vertical slots intermediate the target and the substrate to limit passage of the reactive gas to the target and to control the rate at which target material reaches the substrate, whereby at said preset reactive gas flow rate to fix the composition of a film reactively deposited from the target material and the reactive gas; and a mounting arrangement comprising a carousel having a control axis extending in the same direction as the longitudinal extent of said slots, said substrate being contained on said mounting arrangement whereby rotation of said mounting arrangement causes a deposition area of said substrate to move past said slots to ensure uniform deposition over said deposition area. ### Claim 2 (depends on 1) Apparatus as claimed in claim 1, in which said barrier is a box housing the target. ### Claim 3 Thin film deposition apparatus for reactively sputter depositing a film, the apparatus comprising a substrate; a target; means for directing sputtered target material towards the substrate; means comprising a conduit extending around the deposition area to direct reactive gas at a preset flow rate to the substrate; an apertured barrier intermediate the target and the substrate to limit passage of the reactive gas to the target and to control the rate at which target material reaches the substrate; means for applying an inert atmosphere around the target; and means for applying a sputtering voltage to the target. ### Claim 4 (depends on 3) Apparatus as claimed in claim 3, in which the conduit is a tube having apertures positioned to direct the reactive gas at the substrate. ### Claim 5 (depends on 1) Apparatus as claimed in claim 1, further comprising means for applying r.f. power to the substrate during deposition of a film. ### Claim 6 A method for reactively sputter depositing a film, the method comprising generating and directing sputtered target material towards a substrate, applying an inert atmosphere around the target, directing reactive gas at a preset flow rate to a deposition area of the substrate, and, using an apertured barrier intermediate the target and the substrate, limiting passage of reactive gas to the substrate and controlling the rate at which target material reaches the deposition area of the substrate whereby at said preset reactive gas flow rate to fix the composition of a film reactively deposited from the sputtered target material and the reactive gas. ### Claim 7 (depends on 6) A method as claimed in claim 6, in which r.f. energization is applied at said substrate to cause enhancement of gas reactivity. ### Claim 8 (depends on 6) A method as claimed in claim 6, in which said substrate is periodically moved in order to equalize deposition rate over the deposition area of the substrate. ### Claim 9 (depends on 6) A method as claimed in claim 6, in which the film is sputter deposited in a magnetron sputtering chamber. ### Claim 10 (depends on 6) A method as claimed in claim 6, in which the reactive gas is one of the group consisting of O.sub.2, H.sub.2 S, CO.sub.2, N.sub.2, F.sub.2 and H.sub.2. ### Claim 11 (depends on 6) A method as claimed in claim 6, in which the target material is one of a group consisting of cadmium-tin, zinc, and indium-tin.